V pH Vm dpH/dV

pH
0 2.842 0.25 1.684 0.5 -2.08
0.5 3.684 0.75 0.644 1 -0.44 14

1 4.006 1.25 0.424 1.5 -0.368 12

1.5 4.218 1.75 0.24 2 0.32
2 4.338 2.25 0.4 2.5 -0.228 10
2.5 4.538 2.75 0.286 3 0 8
3 4.681 3.25 0.286 3.5 0.04
3.5 4.824 3.75 0.306 4 0.084 6
4 4.977 4.25 0.348 4.5 0.184
4
4.5 5.151 4.75 0.44 5 0.484
5 5.371 5.25 0.682 5.5 10.416 2
5.5 5.712 5.75 5.89 6 -0.224
0
6 8.657 6.25 5.778 6.5 -10.432 0 2 4 6
6.5 11.546 6.75 0.562 7 -0.492
7 11.827 7.25 0.316 7.5 -0.204
7.5 11.985 7.75 0.214 8 -0.108 dpH/dV
8 12.092 8.25 0.16 8.5 -0.072 7
8.5 12.172 8.75 0.124 9 -0.044
6
9 12.234 9.25 0.102 9.5 0.023008
9.5 12.285 9.75 -0.00441 4.875 -0.000905 5

10 12.328 4

0
0 2 4 6
-1
 pH Chart Title
15

10

0
0 1 2 3 4 5 6 7 8 9 10

-5

-10

6 8 10 12 -15

dpH/dV

6 8 10 12
9 10
V E Vm dE/dV
0 241 0.25 -26 0.5 0
0.5 228 0.75 -26 1 8 300
1 215 1.25 -22 1.5 8
200
1.5 204 1.75 -18 2 -8
2 195 2.25 -22 2.5 8 100
2.5 184 2.75 -18 3 -4
0
3 175 3.25 -20 3.5 -12 0 2 4
3.5 165 3.75 -26 4 -16 -100
4 152 4.25 -34 4.5 -56
4.5 135 4.75 -62 5 -2395 -200
5 104 5.25 -1020 5.4 4200
-300
5.5 -202 5.55 -180 5.6 400
5.6 -220 5.65 -140 5.7 700 -400
5.7 -234 5.75 -70 5.8 400
5.8 -241 5.85 -30 5.9 200 d
5.9 -244 5.95 -10 6 -200
0
6 -245 6.05 -30 6.1 100 0 2 4
6.1 -248 6.15 -20 6.2 -100 -200
6.2 -250 6.25 -30 6.3 100
6.3 -253 6.35 -20 6.4 33.33333 -400
6.4 -255 6.45 -13.33333 6.6 -26.66667
6.5 -259 6.75 -24 7 8 -600
7 -271 7.25 -20 7.5 12
7.5 -281 7.75 -14 8 4 -800
8 -288 8.25 -12 8.5 12
-1000
8.5 -294 8.75 -6 9 -120
9 -297 9.25 -66 9.5 -13.69369
-1200
9.5 -330 9.75 -2.666667 4.875 -0.547009
10 -304
 E Chart Titl
5000

4000

3000

2 4 6 8 10 12
2000

1000

0
0 1 2 3 4 5

-1000

-2000
dE/dV
-3000
2 4 6 8 10 12
 Chart Title

3 4 5 6 7 8 9 10
V E Vm dE/dV
E
0 241 0.25 -24 0.5 -4
0.5 229 0.75 -26 1 8 300

1 216 1.25 -22 1.5 0

200
1.5 205 1.75 -22 2 4
2 194 2.25 -20 2.5 4 100
2.5 184 2.75 -18 3 0
0
3 175 3.25 -18 3.5 -12 0 2 4 6
3.5 166 3.75 -24 4 -73.33333 -100
4 154 4.25 -53.33333 4.4 66.66667
4.5 138 4.55 -40 4.6 -200 -200

4.6 134 4.65 -60 4.7 100 -300

4.7 128 4.75 -50 4.8 -300
4.8 123 4.85 -80 4.9 300 -400
4.9 115 4.95 -50 5 -700
5 110 5.05 -120 5.1 -900
5.1 98 5.15 -210 5.2 -2100 dE/dV
5.2 77 5.25 -420 5.3 1500 200
5.3 35 5.35 -270 5.4 -9475.556 0
5.4 8 5.45 -1336 5.5125 7697.778 0 2 4 6
-200
5.5 -159 5.575 -470 5.625 4000
5.65 -206 5.675 -120 5.7125 342.8571 -400

5.7 -215 5.75 -90 5.8 300 -600

5.8 -224 5.85 -60 5.9 133.3333 -800
5.9 -230 5.95 -33.33333 6.1 8.333333
-1000
6 -240 6.25 -30 6.5 -20
-1200
6.5 -255 6.75 -40 7 44
7 -275 7.25 -18 7.5 20 -1400
7.5 -284 7.75 -8 8 -8 -1600
8 -288 8.25 -12 8.5 8
8.5 -294 8.75 -8 9 8
9 -298 9.25 -4 9.5 -0.931393
9.5 -300 9.75 0.307692 4.875 0.063116
10 -303
 E Chart Title
10000

5000

0
6 8 10 12 0 1 2 3 4 5 6 7 8 9 10

-5000

-10000

-15000

dE/dV

4 6 8 10 12
9 10
V E Vm dE/dV
0 240 0.25 -28 0.5 8
E
0.5 226 0.75 -24 1 4
300
1 214 1.25 -22 1.5 -4
1.5 203 1.75 -24 2 20 200
2 191 2.25 -14 2.5 -8
2.5 184 2.75 -18 3 -8 100
3 175 3.25 -22 3.5 4
0
3.5 164 3.75 -20 4 -125 0 2 4 6
4 154 4.25 -70 4.4 200 -100
4.5 133 4.55 -30 4.6 -200
-200
4.6 130 4.65 -50 4.7 -200
4.7 125 4.75 -70 4.8 -100 -300
4.8 118 4.85 -80 4.9 -400
4.9 110 4.95 -120 5 -700 -400
5 98 5.05 -190 5.1 408.8889
5.1 79 5.15 -144 5.2125 -9031.111
5.2 61 5.275 -1160 5.325 1219.048 dE/dV
5.35 -55 5.375 -1053.333 5.4125 6895.238 200
5.4 -134 5.45 -450 5.5 1300
0
5.5 -179 5.55 -320 5.6 1300 0 2 4 6
5.6 -211 5.65 -190 5.7 1000 -200
5.7 -230 5.75 -90 5.8 8.1E-12 -400
5.8 -239 5.85 -90 5.9 416.6667
5.9 -248 5.95 -6.666667 6.1 -83.33333 -600

6 -250 6.25 -40 6.5 36 -800

6.5 -270 6.75 -22 7 24.58874
-1000
7 -281 7.25 -9.090909 7.525 -13.16017
7.5 -286 7.8 -16 8.05 14.97076 -1200
8.1 -294 8.3 -8.888889 8.525 6.081871 -1400
8.5 -298 8.75 -6 9 4
9 -301 9.25 -4 9.5 -0.931393
9.5 -303 9.75 0.307692 4.875 0.063116
10 -306
 E
Chart Title
8000

6000

4000

2000
6 8 10 12
0
0 1 2 3 4 5 6 7 8 9 10
-2000

-4000

-6000

-8000

-10000

dE/dV

80167.119006 -5.320479
6 8 10 12 -426527.4579
8 9 10
 Prática 2

titulação potenciométrica do h3po4 com naoh

V(mL) pH Vm dph/dv Gráfico 1:
0 2.16 0.125 -0.08 0.25 0.48
0.25 2.18 0.375 -0.2 0.5 -0.48
0.5 2.23 0.625 -0.08 0.75 0.16
0.75 2.25 0.875 -0.12 1 0.32
1 2.28 1.125 -0.2 1.25 0.16
1.25 2.33 1.375 -0.24 1.5 -0.16
1.5 2.39 1.625 -0.2 1.75 0.32
1.75 2.44 1.875 -0.28 2 7.105427E-15
2 2.51 2.125 -0.28 2.25 0.48
2.25 2.58 2.375 -0.4 2.5 0.16
2.5 2.68 2.625 -0.44 2.75 0.96
2.75 2.79 2.875 -0.68 3 1.92
3 2.96 3.125 -1.16 3.2 1.6
3.25 3.25 3.275 -1.4 3.3125 13.333333333
3.3 3.32 3.35 -2.4 3.4 18
3.4 3.56 3.45 -4.2 3.5125 37.333333333
3.5 3.98 3.575 -8.866666667 3.625 -42.66666667
3.65 5.31 3.675 -4.6 3.7125 -32
3.7 5.54 3.75 -2.2 3.8 -13
3.8 5.76 3.85 -0.9 3.925 3.6666666667
3.9 5.85 4 -1.45 4.0875 -3.714285714
4.1 6.14 4.175 -0.8 4.275 -0.8
4.25 6.26 4.375 -0.64 4.5 0
4.5 6.42 4.625 -0.64 4.75 -0.8
4.75 6.58 4.875 -0.44 5 -1.42109E-14
5 6.69 5.125 -0.44 5.25 -0.32
5.25 6.8 5.375 -0.36 5.5 0.48
5.5 6.89 5.625 -0.48 5.75 0
5.75 7.01 5.875 -0.48 6 0
6 7.13 6.125 -0.48 6.25 0.48
6.25 7.25 6.375 -0.6 6.5 0.8
6.5 7.4 6.625 -0.8 6.725 0.3333333333
6.75 7.6 6.825 -0.866666667 6.8875 1.8666666667
6.9 7.73 6.95 -1.1 7 2
7 7.84 7.05 -1.3 7.1 18
7.1 7.97 7.15 -3.1 7.2 7
7.2 8.28 7.25 -3.8 7.3 22 2796
7.3 8.66 7.35 -6 7.4 -16 -380
7.4 9.26 7.45 -4.4 7.5 -9 7.3578947368
7.5 9.7 7.55 -3.5 7.6 -9
7.6 10.05 7.65 -2.6 7.7 -12
7.7 10.31 7.75 -1.4 7.825 -2
7.8 10.45 7.9 -1.1 8.0125 -1.866666667
8 10.67 8.125 -0.68 8.25 -0.48
8.25 10.84 8.375 -0.56 8.5 -0.64
8.5 10.98 8.625 -0.4 8.75 -0.16
8.75 11.08 8.875 -0.36 9 0
9 11.17 9.125 -0.36 9.25 -0.48
9.25 11.26 9.375 -0.24 9.5 -0.48
9.5 11.32 9.625 -0.12 9.75 1.28
9.75 11.35 9.875 -0.44 4.9375 0.044556962
10 11.46

Página 13
Prática 2

V(PE) 3.5650040078 d(dph/vm)

3.565
-0.00140625

Página 14
 Prática 2

Título do Gráfico Título do Grá

50 14
40
12
30
10
20
10 8
0
0 2 4 6 8 10 12 6
-10
-20 4

-30 2
-40
0
-50 0 2 4 6

50

40
f(x) = − 711.111111111116 x + 2535.11111111113 0
30 0
-1
20 -2
-3
10
-4
Column H
0 -5
3.5 3.52 3.54 3.56 3.58 3.6 3.62 3.64 Linear (Column H)
-10 -6
-7
-20
-8
-30 -9
-10
-40

-50

Página 15
 Prática 2

dvm

Página 16
 Prática 2

áfico

8 10 12

Título do Gráfico
2 4 6 8 10 12

Página 17
V(mL) L (uS) L corrigido Volume Inicial (mL)
0 76.48 76.48 100
Titulação pote
1 122.9 124.129 470
2 193 196.86 420
3 215.7 222.171 370
4 234.2 243.568
320
5 253.7 266.385
condutância (uS) 270
6 269.4 285.564
220
7 287.7 307.839
170
8 306.4 330.912
120
9 320.9 349.781
70
10 337.2 370.92 0 2

V(mL) L (uS) L corrigido Volume Inicial (mL) Titulação pote

0 139.6 139.6 100
1 192 193.92 520
2 253.2 258.264 470
3 316.8 326.304 420
370
4 370.8 385.632
320
5 398.6 418.53 Condutância (uS) f(x) = 62.4456 x +
270
6 414.9 439.794
220
7 432.3 462.561
170
8 448.6 484.488
120
9 462.5 504.125
70
10 477.7 525.47 0 2

V(mL) L (uS) L corrigido Volume Inicial (mL)

0 130.8 130.8 100 Titulação pote
1 187.6 189.476 470
2 251.7 256.734
420
3 314.6 324.038
370
4 347.2 361.088
320
5 364.8 383.04 f(x) = 64.6972 x +
condutância (uS) 270
6 382.6 405.556
220
7 397.6 425.432
170
8 413.7 446.796
9 429.7 468.373 120
70
0 2
 condutância (uS) 270
220
170
120

10 446.5 491.15 70
0 2
 Titulação potenciométrica do captopril
470
420
370
320
270
220
170
120
70
0 2 4 6 8 10 12
Volume (mL)

VPE Ccu Massa Molar

Titulação potenciométrica do captopril
4.2899971 0.0117 217.29
520
f(x) = 21.4177142857143 x + 311.86180952381
470
420
370
320
f(x) = 62.4456 x + 135.8536
270
220
Média
170
9.7937078439
120
70
0 2 4 6 8 10 12
Volume (mL)

Titulação potenciométrica do captopril

VPE Ccu Massa Molar
470 f(x) = 21.439 x + 275.932
3.4146285 0.0117 217.29
420
370
320
f(x) = 64.6972 x + 128.2162
270
220
170
120
70
0 2 4 6 8 10 12
Volume (mL)
270
220
170
120
70
0 2 4 6 8 10 12
Volume (mL)
 ncap (mmol) mcap m/comprimido
0.1003859316 21.81286 10.90642953422

ncap (mmol) mcap m/comprimido

0.0799023071 17.36197 8.680986153544
 Valores de Absorbância em função da concentração de Fe (II)
Balão (50mL) C Fe(II) (mg/L) V Fe (II) (L) V tampão (mL) V o-fen (mL)
1 0 0 2.5 5
2 0.501006762103 0.0005 2.5 5
3 1.002013524207 0.001 2.5 5
4 1.202416229048 0.0012 2.5 5
5 2.004027048414 0.002 2.5 5
6 2.505033810517 0.0025 2.5 5
7 3.006040572621 0.003 2.5 5
8 4.008054096828 0.004 2.5 5
9 5.010067621034 0.005 2.5 5

Valores de absorbância das soluções diluídas da amostra

Balão (50mL) C Fe (II) (mg/L) V amostra (mL) V tampão (mL) V o-fen (mL)
10 1 2.5 0
11 1 2.5 5
12 1 2.5 5
13 1 2.5 5

Chart Title
0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
370 420 470 520 570 620

A7 A10 A11 A11-A10

(II) Valores de absorbância em função do comprimento de onda
A l (nm) A7 A10 A11 A11-A10
0 400 0.246 0.064 0.156 0.092
0.104 410 0.303 0.054 0.197 0.143
0.174 420 0.354 0.044 0.233 0.189
0.286 430 0.399 0.037 0.266 0.229
0.343 440 0.434 0.033 0.291 0.258
0.382 450 0.469 0.029 0.312 0.283
0.589 460 0.483 0.022 0.324 0.302
0.652 470 0.518 0.012 0.348 0.336
0.935 480 0.541 0.014 0.368 0.354
490 0.541 0.01 0.368 0.358
500 0.573 0.008 0.391 0.383
a 510 0.587 0.006 0.401 0.395
A a CORR 520 0.54 0.004 0.363 0.359
0.005 530 0.399 0.005 0.244 0.239
0.409 0.404 540 0.296 0.006 0.134 0.128
0.547 0.542 550 0.162 0.007 0.043 0.036
0.514 0.509 560 0.093 0.006 0.018 0.012
570 0.055 0.005 0.049 0.044
580 0.0037 0.007 0.066 0.059
590 0.023 0.005 0.078 0.073
600 0
610 0
620 0
630 0
640 0
650 0
660 0
670 0
680 0
690 0
620
700 0
massa pesada de FeSO4.7H2O(g) balão (mL) Solução massa molar do composto (g/mol)
0.1247 500 0.2494 278.02
massa pesada de ferro (g/L) Massa molar do Ferro (g/mol)
0.0250503381051723 1L (mL) 55.85
1000
Concentração de Ferro (g/L) mg/L
0.0501006762103446 50.1006762
1
0.9
Volume do Balão (L) Ml f(x) = 0.175
0.8 R² = 0.9743
0.05 50 0.7
0.6
0.5
0.4
0.3
Y A X B
0.2
0.404 0.1756 2.2460137 0.0096
0.1
0.542 0.1756 3.0318907 0.0096
0
0.509 0.1756 2.8439636 0.0096 0

MEDIA
2.70728929384966 VALOR TOTAL
135.364464692483

FABRICANTE
5,0MG/30Ml
166MG/L
 Chart Title
1
0.9
f(x) = 0.175633618603894 x + 0.00956050955414006
0.8 R² = 0.974334570274599
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 1 2 3 4 5 6
Balão (50mL) C Vit.C (mg/L) V Vit.C (mL) VFe(III) V SCN(mL) A
1 0 0 2.5 0 0
2 0 0 2.5 20 0.588
3 0.9888 0.1 2.5 20 0.479
4 1.9776 0.2 2.5 20 0.438
5 2.9664 0.3 2.5 20 0.347
6 3.9552 0.4 2.5 20 0.275
7 4.944 0.5 2.5 20 0.159

Balão (50mL) C Vit.C (mg/L) V amostra (mL) VFe(III) V SCN(mL) A

9 Branco da amostra 0.2 2.5 0 0
10 replicata 1 0.2 2.5 20 0.319
11 replicata 2 0.2 2.5 20 0.332
12 replicata 3 0.2 2.5 20 0.320

l (nm) A
400 0.265 lambda máximo
410 0.324 0.7
420 0.381
0.6
430 0.433
0.5
440 0.489
450 0.537 0.4
460 0.573 l 0.3
470 0.590
0.2
480 0.595
0.1
490 0.586
500 0.559 0
350 400 450 500 550 600 650
510 0.512
A
520
530
540
550
560
570
580
590
600
610
620
630
640
650
660
670
680
690
700
 Vit. C padrão (mg/L)
494.4 Curva
Volume do Balão (mL) 0.7
50
0.6
f(x) = − 0.082293111419325 x + 0.584428571428571
0.5 R² = 0.987177446248141
0.4

A
0.3

0.2

0.1

0
0 1 2 3 4 5
C

y a x
0.319 -0.0823 3.2247874
bda máximo 0.332 -0.0823 3.0668287
0.32 -0.0823 3.2126367

3.1680842

550 600 650 700 750

A
4 5 6

b C C desvpada
0.5844 3.2247874 806.19684 21.975025
0.5844 3.0668287 766.70717
0.5844 3.2126367 803.15917

C amostra +
792.02106 22
mg/L/tablete -