volumen de E(milivolts) E(volteos) metodo 1 derivada

0 439.4 0.4394 XV DpH/ Dv #M

0.5 439.1 0.4391 0.25 -0.6 M1
1 438.3 0.4383 0.75 -1.6 M2
1.5 437.4 0.4374 1.25 -1.8 M3
2 436.7 0.4367 1.75 -1.4 M4
2.5 435.9 0.4359 2.25 -1.6 M5
3 435.1 0.4351 2.75 -1.6 M6
3.5 434.4 0.4344 3.25 -1.4 M7
4 433.5 0.4335 3.75 -1.8 M8
4.5 432.7 0.4327 4.25 -1.6 M9
5 431.8 0.4318 4.75 -1.8 M10
5.5 430.8 0.4308 5.25 -2 M11
6 429.9 0.4299 5.75 -1.8 M12
6.5 429.2 0.4292 6.25 -1.4 M13
7 428.3 0.4283 6.75 -1.8 M14
7.5 427.3 0.4273 7.25 -2 M15
8 426.5 0.4265 7.75 -1.6 M16
8.5 425.4 0.4254 8.25 -2.2 M17
9 424.4 0.4244 8.75 -2 M18
9.5 423.1 0.4231 9.25 -2.6 M19
10 421.9 0.4219 9.75 -2.4 M20
10.5 420.9 0.4209 10.25 -2 M21
11 419.6 0.4196 10.75 -2.6 M22
11.5 418.4 0.4184 11.25 -2.4 M23
12 416.9 0.4169 11.75 -3 M24
12.5 415.6 0.4156 12.25 -2.6 M25
13 413.4 0.4134 12.75 -4.4 M26
13.5 412.2 0.4122 13.25 -2.4 M27
14 410.5 0.4105 13.75 -3.4 M28
14.5 408.2 0.4082 14.25 -4.6 M29
15 406 0.406 14.75 -4.4 M30
15.5 403 0.403 15.25 -6 M31
16 399.6 0.3996 15.75 -6.8 M32
16.5 395.2 0.3952 16.25 -8.8 M33
17 388.8 0.3888 16.75 -12.8 M34
17.5 369.8 0.3698 17.25 -38 M35
18 295.5 0.2955 17.75 -148.6 M36
18.5 276.8 0.2768 18.25 -37.4 M37
19 265.8 0.2658 18.75 -22 M38
19.5 258.2 0.2582 19.25 -15.2 M39
20 252.8 0.2528 19.75 -10.8 M40
20.5 247.3 0.2473 20.25 -11 M41
 21 243.6 0.2436 20.75 -7.4 M42
21.5 240 0.24 21.25 -7.2 M43
22 236.8 0.2368 21.75 -6.4 M44
22.5 233.7 0.2337 22.25 -6.2 M45
23 231.1 0.2311 22.75 -5.2 M46
23.5 228.2 0.2282 23.25 -5.8 M47
24 225.8 0.2258 23.75 -4.8 M48
24.5 223.6 0.2236 24.25 -4.4 M49
25 221.2 0.2212 24.75 -4.8 M50

Chart Title
500
400
300
200
100
0
0 5 10 15 20 25 30
 Chart Title
0
0 5 10 15 20 25 30

-20

-40

-60

-80

-100

-120

-140

-160
25 30
 Método de la 2da derivada

Err:509 E(milivolts) E(volteos) metodo 1 derivada

0 439.4 0.4394 XV DpH/ Dv #M
0.5 439.1 0.4391 0.25 -0.6 M1
1 438.3 0.4383 0.75 -1.6 M2
1.5 437.4 0.4374 1.25 -1.8 M3
2 436.7 0.4367 1.75 -1.4 M4
2.5 435.9 0.4359 2.25 -1.6 M5
3 435.1 0.4351 2.75 -1.6 M6
3.5 434.4 0.4344 3.25 -1.4 M7
4 433.5 0.4335 3.75 -1.8 M8
4.5 432.7 0.4327 4.25 -1.6 M9
5 431.8 0.4318 4.75 -1.8 M10
5.5 430.8 0.4308 5.25 -2 M11
6 429.9 0.4299 5.75 -1.8 M12
6.5 429.2 0.4292 6.25 -1.4 M13
7 428.3 0.4283 6.75 -1.8 M14
7.5 427.3 0.4273 7.25 -2 M15
8 426.5 0.4265 7.75 -1.6 M16
8.5 425.4 0.4254 8.25 -2.2 M17
9 424.4 0.4244 8.75 -2 M18
9.5 423.1 0.4231 9.25 -2.6 M19
10 421.9 0.4219 9.75 -2.4 M20
10.5 420.9 0.4209 10.25 -2 M21
11 419.6 0.4196 10.75 -2.6 M22
11.5 418.4 0.4184 11.25 -2.4 M23
12 416.9 0.4169 11.75 -3 M24
12.5 415.6 0.4156 12.25 -2.6 M25
13 413.4 0.4134 12.75 -4.4 M26
13.5 412.2 0.4122 13.25 -2.4 M27
14 410.5 0.4105 13.75 -3.4 M28
14.5 408.2 0.4082 14.25 -4.6 M29
15 406 0.406 14.75 -4.4 M30
15.5 403 0.403 15.25 -6 M31
16 399.6 0.3996 15.75 -6.8 M32
16.5 395.2 0.3952 16.25 -8.8 M33
17 388.8 0.3888 16.75 -12.8 M34
17.5 369.8 0.3698 17.25 -38 M35
18 295.5 0.2955 17.75 -148.6 M36
18.5 276.8 0.2768 18.25 -37.4 M37
19 265.8 0.2658 18.75 -22 M38
19.5 258.2 0.2582 19.25 -15.2 M39
20 252.8 0.2528 19.75 -10.8 M40
20.5 247.3 0.2473 20.25 -11 M41
21 243.6 0.2436 20.75 -7.4 M42
21.5 240 0.24 21.25 -7.2 M43
22 236.8 0.2368 21.75 -6.4 M44
22.5 233.7 0.2337 22.25 -6.2 M45
23 231.1 0.2311 22.75 -5.2 M46
23.5 228.2 0.2282 23.25 -5.8 M47
24 225.8 0.2258 23.75 -4.8 M48
24.5 223.6 0.2236 24.25 -4.4 M49
25 221.2 0.2212 24.75 -4.8 M50
 Método 2da derivada
xv Δ(ΔpH/Δv)=s
0.5 -2
1 -0.4
1.5 0.8
2 -0.4
2.5 2.27373675E-13
3 0.4
3.5 -0.8
4 0.4
4.5 -0.4
5 -0.4
5.5 0.4
6 0.8
6.5 -0.8
7 -0.4
7.5 0.8
8 -1.2
8.5 0.4
9 -1.2
9.5 0.4
10 0.8
10.5 -1.2
11 0.4
11.5 -1.2
12 0.8
12.5 -3.6
13 4
13.5 -2
14 -2.4
14.5 0.4
15 -3.2
15.5 -1.6
16 -4
16.5 -8 250
17 -50.4
200
17.5 -221.2
18 222.4 150

18.5 30.8 100

19 13.6
50
Δ(ΔpH/Δv)

19.5 8.8
20 -0.4 0
0 2 4 6 8 10 12 14 16 18 20 22
-50

-100

-150
 100

50

Δ(ΔpH/Δv)
0
0 2 4 6 8 10 12 14 16 18 20 22
20.5 7.2 -50
21 0.4
-100
21.5 1.6
22 0.4 -150
22.5 2 -200
23 -1.2
-250
23.5 2
24 0.8 Volumen de Na2S2O3
24.5 -0.8
4 16 18 20 22 24 26
4 16 18 20 22 24 26

2S2O3
 xv m 2da derivada
v 0.25 62 -4
0 0.75 60 -64
0.5 1.25 28 -16 Valoración p
1 1.75 20 -8 250
1.5 2.25 16 -8
200
2 2.75 12 4
2.5 3.25 14 -12 150

3 3.75 8 0 100
3.5 4.25 8 0

Δ(ΔpH/Δv)
50
4 4.75 8 0
0
4.5 5.25 8 0 0 3 6
5 5.75 8 0 -50
5.5 6.25 8 -4 -100
6 6.75 6 0
-150
6.5 7.25 6 -4
7 7.75 4 0 -200
7.5 8.25 4 0
8 8.75 4 4
8.5 9.25 6 4
9 9.75 8 -12
9.5 10.25 2 4
10 10.75 4 0
10.5 11.25 4 0
11 11.75 4 0
11.5 12.25 4 0
12 12.75 4 0
12.5 13.25 4 0
13 13.75 4 0
13.5 14.25 4 0
14 14.75 4 4
14.5 15.25 6 -4
15 15.75 4 4
15.5 16.25 6 -4
16 16.75 4 8
16.5 17.25 8 0
17 17.75 8 0
17.5 18.25 8 -8
18 18.75 4 12
18.5 19.25 10 0
19 19.75 10 12
19.5 20.25 16 28
20 20.75 30 216
20.5 21.25 138 -44
 21 21.75 116 -176
21.5 22.25 28 -44
22 22.75 6 -4
22.5 23.25 4 -16
23 23.75 -4 8
23.5 24.25 0 -4
24 24.75 -2 -0.08080808
24.5
25
 Valoración potenciométrica de KCl con AgNO3
250

200

150

100
Δ(ΔpH/Δv)

50

0
0 3 6 9 12 15 18 21 24 27
-50

-100

-150

-200
xV de AgNO3