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Tinh Toan SD, LOQ, LOD
Tinh Toan SD, LOQ, LOD
50
50
50
50
50
50
50
50
50
50
50
24.9
23.7
23.65
23.6
23.7
23.7
23.65
23.7
23.65
23.6
23.7
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
X Tbinhf SD
4.8
5
5.2
4.8
4.8
5
4.8
5
5.2
4.8
50
50
50
50
50
50
50
50
50
50
50
24.9
18.45
18.6
18.9
18.7
18.95
18.75
18.7
18.4
18.8
18.8
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
25.8
25.2
24
24.8
23.8
24.6
24.8
26
24.4
24.4
50
50
50
50
50
50
50
50
50
50
50
24.9
12.45
12
12.2
12.15
12.55
12.65
12.8
12.35
12.15
12.4
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
KHNG M BO O M RNG
96
100
104
COD
103
101
96
100
103
102
49.8
51.6
50.8
51
49.4
49
48.4
50.2
51
50
LOD
LOQ
CV%
6.25
4.94
0.16465
X Tbinhf SD
24.78
LOD
0.71461
X Tbinhf SD
50.12
96
99
102
0.49396 1.646545
2.14383 7.146095
LOD
1.00311
96
95
99
LOQ
LOQ
3.00932 10.03106
100
98
98
96
99
97
3.33309
CV%
2.88382
CV%
2.00141
100
104
100
BOD
N
Ntb
4.29
4.32
4.36
4.32
4.40
4.27
4.32
4.36
4.24
4.40
4.328
4.321
4.321
4.321
4.321
4.321
4.321
4.321
4.321
4.321
4.321
Ntb
1.07
1.01
0.96
0.99
1.04
1.07
1.04
1.014
1.014
1.014
1.014
1.014
1.014
1.014
N-Ntb
( N-Ntb)2
-0.031
0.000961
-0.001
1E-06
0.039
0.001521
-0.001
1E-06
0.079
0.006241
-0.051
0.002601
-0.001
1E-06
0.039
0.001521
-0.081
0.006561
0.079
0.006241
0.02565
N-Ntb
( N-Ntb)2
0.056
0.003136
-0.004
0.000016
-0.054
0.002916
-0.024
0.000576
0.026
0.000676
0.056
0.003136
0.026
0.000676
SD
LOD
LOQ
CV%
0.00285 0.05339 0.16016 0.533854 1.23349
0.96
1.01
0.99
1.014
1.014
1.014
1.014
-0.054
-0.004
-0.024
0.002916
0.000016
0.000576
0.01464
0.00163
SD
LOD
LOQ
CV%
0.04033
0.121 0.40332 3.97751
N-Ntb
( N-Ntb)2
-0.045
0.002025
-0.025
0.000625
0.005
2.5E-05
0.035
0.001225
0.055
0.003025
0.005
2.5E-05
-0.045
0.002025
-0.025
0.000625
0.005
2.5E-05
0.035
0.001225
0.01085
0.00121
SD
LOD
LOQ
CV%
0.03472 0.10416 0.347211
0.6896
DO
N
Ntb
4.99
5.01
5.04
5.07
5.09
5.04
4.99
5.01
5.04
5.07
5.035
5.035
5.035
5.035
5.035
5.035
5.035
5.035
5.035
5.035
5.035
KiM
N
0.671
0.61
0.671
0.61
0.671
0.61
0.671
0.61
0.671
0.61
0.6405
Ntb
N-Ntb
0.6405
0.031
0.6405
-0.031
0.6405
0.031
0.6405
-0.031
0.6405
0.031
0.6405
-0.031
0.6405
0.031
0.6405
-0.031
0.6405
0.031
0.6405
-0.031
( N-Ntb)2
0.00093025
0.00093025
0.00093025
0.00093025
0.00093025
0.00093025
0.00093025
0.00093025
0.00093025
0.00093025
0.0093025
Nt t
N
0.011
0.012
0.01
0.012
Ntb
N-Ntb
( N-Ntb)2
0.0112
0.000
4E-08
0.0112
0.001
6.4E-07
0.0112
-0.001 0.00000144
0.0112
0.001
6.4E-07
SD
LOD
LOQ
CV%
0.00103 0.03215 0.09645 0.321498 5.01949
0.01
0.011
0.012
0.011
0.01
0.01
0.0109
V1
0.0112
0.0112
0.0112
0.0112
0.0112
0.0112
V0
0.5
-0.001 0.00000144
0.000
4E-08
0.001
6.4E-07
0.000
4E-08
-0.001 0.00000144
-0.001 0.00000144
0.0000078
N
0
Mn
0.002
SD
LOD
LOQ
CV%
8.7E-07 0.00093 0.00279 0.009309 8.54082
m(g)
14
KQ1
0.2
0.07
100 Wh20
100
30
100
100
R%
18.65
96
100
104
96
96
100
96
100
104
96
10.0007
R
R%
11.5588
103
101
96
99
95
98
99
104
98
98
16.6549
100
103
102
102
99
98
97
100
102
100
TB R%
104
98
102
96
98
100
99
SD
CV
3
2.75
U%
4.68
N
10
10
10
11
11
10
10
11
11
11
11
Ntb
N-Ntb
( N-Ntb)2
10.515
-0.085 0.00723
10.515
-0.045 0.00202
10.515
-0.025 0.00063
10.515
0.005 2.5E-05
10.515
0.065 0.00422
10.515
-0.115 0.01323
10.515
-0.085 0.00723
10.515
0.095 0.00902
10.515
0.065 0.00422
10.515
0.125 0.01563
0.06345
SD
LOD
LOQ
0.00705 0.08396 0.25189 0.83964
R
8.380451
Ntb
1
1
1
1
1
1
1
1
1
1
1
R
48.33755
R
6.640783
1.039
1.039
1.039
1.039
1.039
1.039
1.039
1.039
1.039
1.039
N-Ntb
( N-Ntb)2
0.031 0.00096
-0.029 0.00084
-0.049
0.0024
-0.049
0.0024
0.001
1E-06
0.031 0.00096
0.001
1E-06
-0.029 0.00084
0.061 0.00372
0.031 0.00096
0.01309
2
3
3
3
2
2
2
3
3
3
2
Ntb
N-Ntb
( N-Ntb)2
2.4898
-0.049 0.00238
2.4898
0.012 0.00015
2.4898
0.012 0.00015
2.4898
0.012 0.00015
2.4898
-0.049 0.00238
2.4898
-0.049 0.00238
2.4898
-0.049 0.00238
2.4898
0.012 0.00015
2.4898
0.073 0.00536
2.4898
0.073 0.00536
0.02084
2
3
3
3
Ntb
N-Ntb
( N-Ntb)2
2.4898
-0.049 0.00238
2.4898
0.012 0.00015
2.4898
0.012 0.00015
2.4898
0.012 0.00015
0.00145
SD
LOD
LOQ
0.03814 0.11441 0.38137
SD
LOD
LOQ
0.00232 0.04812 0.14435 0.48117
2
2
2
3
3
3
2
R
3.902826
KQ2
KQUA
1.3
2.4898
2.4898
2.4898
2.4898
2.4898
2.4898
-0.049
-0.049
-0.049
0.012
0.073
0.073
0.00238
0.00238
0.00238
0.00015
0.00536
0.00536
0.02084
SD
LOD
LOQ
0.00232 0.04812 0.14435 0.48117
CV%
0.79852
CV%
R
3.67057 9.081252
CV%
R
1.93258 17.24807
CV%
R
1.93258 17.24807
DO
V mu(ml V Na2S2O3(ml) C Na2S2O3 (N)DO mg/l
300
300
300
300
300
300
300
300
300
300
2.3
2.15
2.25
2.35
2.2
2.25
2.15
2.35
2.25
2.15
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
1.53
1.43
1.50
1.57
1.47
1.50
1.43
1.57
1.50
1.43
300
300
300
300
300
300
300
300
300
300
7.55
7.6
7.8
7.65
7.45
7.4
7.35
7.3
7.55
7.45
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
5.03
5.07
5.20
5.10
4.97
4.93
4.90
4.87
5.03
4.97
300
300
300
300
300
300
300
300
300
300
12.2
12
11.9
11.6
12.05
11.85
11.95
12.25
11.75
12.45
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
KHNG M BO O M RNG
8.13
8.00
7.93
7.73
8.03
7.90
7.97
8.17
7.83
8.30
X Tbinhf SD
1.49333
0.05164
X Tbinhf SD
5.00667
0.10037
X Tbinhf SD
0.16704
LOD
0.15492
LOD
0.30111
LOD
0.50111
LOQ
0.5164
LOQ
1.0037
LOQ
1.67037
DO
100
101
102
96
101
100
100
104
99
104
102
97
98
99
100
100
99
99
96
98
100
CV%
3.45802
CV%
2.08796
102
96
100
104
98
100
96
104
100
96
9.63943
R
2.00472
CV%
R%
R%
101
101
104
102
99
99
98
97
101
99
16.6274
R%
15.9646
102
100
99
97
100
99
100
102
98
104
TB R%
SD
CV
U%
104
97
102
100
101
98
96
99
104
100
2.35
4.00
BOD5
V mu(ml V 1Na2S2O3(ml) C Na2S2O3 (N)DO1 mg/l
300
300
300
300
300
300
300
300
300
300
12.2
12
11.9
11.6
12.05
11.85
11.95
12.25
11.75
12.3
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
8.13
8.00
7.93
7.73
8.03
7.90
7.97
8.17
7.83
8.20
300
300
300
300
300
300
300
300
300
300
12.25
11.8
11.95
11.75
12.15
11.65
11.9
11.95
12.2
12.15
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
8.17
7.87
7.97
7.83
8.10
7.77
7.93
7.97
8.13
8.10
300
300
300
300
300
300
300
300
300
300
12.1
12.15
11.85
11.8
12.35
11.95
12.3
12.15
12.1
11.95
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
KHNG M BO O M RNG
8.07
8.10
7.90
7.87
8.23
7.97
8.20
8.10
8.07
7.97
X Tbinhf SD
7.99
LOD
0.14911
X Tbinhf SD
7.98333
LOD
0.13721
X Tbinhf SD
8.04667
0.44734
0.41164
LOD
0.1209
0.36271
LOQ
1.49113
LOQ
1.37212
LOQ
1.20902
BOD
105
102
100
100
88
98
100
103
93
92
88
93
98
103
102
90
87
97
92
93
98
CV%
1.86624
CV%
1.50251
V5Na2S2O3(ml) DO5(mg/l)
R%
R%
22.1851
9.2
9.15
8.85
9.1
9.05
9.05
9.1
8.95
9.15
8.95
9.1
9.2
9.05
9
9.3
9.05
9.35
9.05
9.2
9.05
TB R%
1
1
1
1
1
1
1
1
1
1
2.10
2.00
2.00
1.83
1.97
1.80
1.83
2.13
2.00
2.17
10
10
10
10
10
10
10
10
10
10
20.33
17.67
20.67
17.67
20.67
17.33
18.67
20.00
20.33
21.33
6.07
6.13
6.03
6.00
6.20
6.03
6.23
6.03
6.13
6.03
SD
X Tbinh
6.13
6.10
5.90
6.07
6.03
6.03
6.07
5.97
6.10
5.97
V5Na2S2O3(ml) DO5(mg/l)
101
101
99
98
103
100
103
101
101
100
6.03
6.00
5.93
5.90
6.07
6.10
6.13
6.03
5.83
6.03
V5Na2S2O3(ml) DO5(mg/l)
102
98
100
98
101
97
99
100
102
101
19.3941
9.05
9
8.9
8.85
9.1
9.15
9.2
9.05
8.75
9.05
102
100
99
97
100
99
100
102
98
103
17.8612
1.71873
CV%
R%
25
25
25
25
25
25
25
25
25
25
CV
50.00
49.17
46.67
46.67
50.83
48.33
49.17
51.67
48.33
48.33
U%
1.98
X Tbinh
19.47
X Tbinh
48.92
107
100
103
100
102
97
108
107
97
98
5.96
10.13
SD
LOD
LOQ
CV%
R%
105
100
100
92
98
90
92
107
100
108
SD
LOD
LOQ
CV%
R%
102
88
103
88
103
87
93
100
102
107
SD
LOD
LOQ
CV%
R%
100
98
93
93
102
97
98
103
97
97
KiM
V mu(ml
100
100
100
100
100
100
100
100
100
100
V mu(ml
1.00
1.05
0.95
0.95
0.95
1.05
1.00
1.05
1.05
0.95
V mu(ml
3.40
3.30
3.15
3.25
3.10
3.25
3.20
3.45
3.15
3.30
6.70
6.75
6.65
6.60
6.50
6.40
6.55
6.70
6.40
6.65
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
3.05
3.20
2.90
2.90
2.90
3.20
3.05
3.20
3.20
2.90
0.17
0.17
0.16
0.16
0.16
0.16
0.16
0.17
0.16
0.17
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
kim(me/l) PTLng
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
KHNG M BO O M RNG
102
107
Kim
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
kim(me/l) PTLng
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
100
100
100
100
100
100
100
100
100
100
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
0.005
100
100
100
100
100
100
100
100
100
100
kim(me/l) PTLng
0.34
0.34
0.33
0.33
0.33
0.32
0.33
0.34
0.32
0.33
97
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
61.02
97
3.05
10.37
10.07
9.61
9.92
9.46
9.92
9.76
10.53
9.61
10.07
9.93
20.44
20.59
20.29
20.14
19.83
19.53
19.98
20.44
19.53
20.29
97
20.11
107
Kim
104
102
101
103
96
101
99
101
95
99
99
98
SD
LOD
0.14383
SD
0.43148
LOD
0.34073
SD
1.0222
LOD
0.37917
1.1375
LOQ
1.43826
LOQ
3.40733
LOQ
3.79165
CV%
4.71405
CV%
1.88582
R%
107
107
104
101
96
99
95
99
98
105
96
101
9.71534
R
R%
102
103
101
101
99
98
100
102
98
101
17.6758
TB R%
102
102
107
97
97
97
107
102
107
107
97
7.07107
3.431
CV%
R%
SD
CV
U%
97
101
3.52
5.97
98
100
105
102
96
98
101
101
101
3.52
5.97
Phenol
Vmchit Peak chun Peak mu C chun(mg/l) V lm giu mu
500
0.8
0.28
0.005
500
0.8
0.34
0.005
500
0.8
0.33
0.005
500
0.8
0.31
0.005
500
0.8
0.37
0.005
500
0.8
0.3
0.005
500
0.8
0.31
0.005
500
0.8
0.33
0.005
500
0.8
0.34
0.005
500
0.8
0.29
0.005
KHNG M BO O M RNG
70
85
83
phenol
83
93
90
96
91
94
78
86
101
1
1
1
1
1
1
1
1
1
1
H lng (mg/l)
X Tbnh(mg/l)
0.004
0.004
0.004
0.004
0.005
0.004
0.004
0.004
0.004
0.004
0.0040
1
1
1
1
1
1
1
1
1
1
H lng (mg/l)
X Tbnh(mg/l)
0.414
0.466
0.448
0.431
0.466
0.500
0.517
0.534
0.500
0.483
0.476
1
1
1
1
1
1
1
1
1
1
H lng (mg/l)
X Tbnh(mg/l)
1.917
1.818
1.884
2.017
1.719
1.851
1.818
1.752
1.785
1.884
1.845
93
93
86
75
100
93
SD
LOD
LOQ
SD
LOD
0.038295 0.114885
SD
LOD
LOQ
CV%
R%
70
85
83
78
93
75
78
83
85
73
8.46254 3.938928
CV%
R%
83
93
90
86
93
100
103
107
100
97
LOQ
CV%
R%
96
91
94
101
86
93
91
88
89
94
TB R%
78
103
91
83
107
88
85
100
89
73
97
94
89
SD
CV
9
10.09
U%
17.15
Cr6+
Cr6
0.0052
104
0.022
88
0.049
98
0.005
100
0.023
92
0.051
102
0.005
100
0.025
100
0.049
98
0.0053
106
0.025
100
0.052
104
0.0051
102
0.024
96
0.047
94
0.0055
110
0.023
92
0.051
102
0.0049
98
0.027
108
0.053
106
0.0051
102
0.026
104
0.047
94
KHNG M BO O M RNG
Cr6+
104
100
88
92
98
102
100
100
98
106
100
104
102
96
94
110
92
102
98
108
106
102
104
94
0.0052
104
0.025
100
0.046
92
104
100
92
STDEV LOD
LOQ
0.005 0.000177 0.00053 0.001767
100
98
110
0.026 0.001578 0.004733 0.015776
104
88
108
0.048 0.002359 0.007078 0.023594
96
92
106
CV%
TB ga tr
3.444408 0.00513
6.413095
0.0246
4.785758
0.0493
TB R%
SD
CV
U%
100 99.86667 5.197701 5.20464 8.842684
104
96
Phenol
0.0017
85
0.093
93
0.504
100.8
0.0015
75
0.087
87
0.486
97.2
0.0015
75
0.097
97
0.459
91.8
0.0016
80
0.092
92
0.437
87.4
KHNG M BO O M RNG
Phenol
85
75
75
80
93
87
97
92
101
97
92
87
STDEV
0.0015 0.0014 0.0017 0.0019 0.0018 0.0016 0.00015
75
70
85
95
90
80
70
0.104 0.088 0.105 0.079 0.084 0.092 0.00825
104
88
105
79
84
92
79
0.489 0.459 0.472 0.428 0.435 0.451 0.02543
97.8
91.8
94.4
85.6
87
90.2
85.6
75
104
98
70
88
92
85
105
94
95
79
86
90
84
87
80
92
90
TB R%
88.5
LOD
0.00046
95
0.02476
105
0.07628
100.8
LOQ
CV%
0.00155 9.563
0.08252 8.96
0.25425 5.503
SD
CV
U%
8.77202 9.91188 16.84
TB ga tr R
0.00162 3.48569
0.0921
0.462