Tabla 4.

5 Propiedades críticas y parámetros de Lennard-Jones

Sustancia Peso Parámetros de Constantes críticas

molecular Lennard Jones
M σ Ɛ/K TC PC VC μC
3
(A°) (K) (K) (atm) (cm /gmol)
H2 2.016 2.915 38.0 33.3 12.8 65.0 34.7
He 4.003 2.576 10.2 5.26 2.26 25.4 25.4
Ne 20.183 2.789 35.7 44.5 26.9 41.7 156.0
Ar 39.944 3.418 124.0 151.0 48.0 75.2 264.0
Kr 83.80 3.498 225.0 209.4 54.3 92.2 396.0
Xe 131.30 4.055 229.0 289.8 58.0 118.8 490.0
Aire 28.97 3.617 97.0 132.0 36.4 86.6 193.0
N2 28.02 3.681 91.5 126.2 33.5 90.1 180.0
O2 32.00 3.433 113.0 154.4 49.7 74.4 250.0
O3 48.00 268 67.0 89.4
H2O 18.01 2.649 356.0 647.3 57.1
CO 28.01 3.590 110.0 133.0 34.5 93.1 190.0
CO2 44.01 3.996 190.0 304.2 72.9 94.0 343.0
NO 30.01 3.470 119.0 180.0 64.0 57.0 258.0
N2O 44.02 3.879 220.0 309.7 71.7 96.3 332.0
SO2 64.07 4.290 252.0 430.7 77.8 122.0 411.0
F2 38.00 3.653 112.0
Cl2 70.91 4.115 357.0 417.0 76.1 124.0 420.0
Br2 159.83 4.268 520.0 584.0 102.0 144.0
I2 253.82 4.982 550.0 800.0
CH4 16.04 3.822 137.0 190.7 45.8 99.3 159.0
C2H2 26.04 4.221 185.0 309.5 61.6 113.0 237.0
C2H4 28.05 4.232 205.0 282.4 50.0 124.0 215.0
C2H6 30.07 4.418 230.0 305.4 48.2 148.0 210.0
C3H6 42.08 365.0 45.5 181.0 233.0
C3H8 44.09 5.016 254.0 370.0 42.0 200.0 228.0
n-C4H10 58.12 425.2 37.5 255.0 239.0
I-C4H10 58.12 5.341 313.0 408.1 36.0 263.0 239.0
n-C5H12 72.15 5.769 345.0 469.8 33.3 311.0 238.0
n-C6H14 86.17 5.909 413.0 507.9 29.9 368.0 248.0
n-C7H16 100.20 54.2 27.0 426.0 254.0
n-C8H18 114.22 7.451 320.0 569.4 24.6 485.0 259.0
n-C9H20 128.25 595.0 22.5 543.0 265.0
Ciclohexano 84.16 6.093 324.0 553.0 40.0 308.0 284.0
C6H6 78.11 5.270 440.0 562.6 48.6 260.0 312.0
CH3Cl 50.49 3.375 855.0 416.3 68.9 143.0 338.0
CH2Cl2 84.94 4.759 406.0 510.0 60.0
CHCl3 119.39 5.430 327.0 536.6 54.0 240.0 410.0
CCl4 153.84 5.881 327.0 556.4 45.0 276.0 413.0
C2N2 52.04 4.380 339.0 400.0 59.0
COS 60.08 4.130 335.0 378.0 61.0
CS2 76.14 4.438 448.0 552.0 78.0 170.0 404.0
Nh3 17.31 2.900 558.3 405.5 72.5
HF 20.006 3.149 330.0 461.0 69.2
HCL 36.461 3.339 343.7 324.3 80.9
HBR 80.912 3..353 419.0 363.2
HI 127.912 4.211 288.7 424.0
HCN 27.026 3.630 569.1 456.3 133.8

MIQ. Norma A. Vallejo Cantú 3.15