Practica 1

tubo 1 Tubo 2 Tubo 3 Tubo 4

Tiempo/s Temp/°C Tiempo/s Temp/ °C Tiempo/s Temp/°C Tiempo/s
0 0 42.2 0 35.8 0 54.6 0
0.25 15 39.7 15 34.6 15 52.1 15
0.5 30 37.1 30 31.9 30 46.8 30
0.75 45 35.8 45 29.9 45 41.4 45
1 60 35.1 60 28.3 60 36.9 60
1.25 75 34.7 75 27.1 75 33.1 75
1.5 90 34.4 90 26.2 90 30.3 90
1.75 105 34.2 105 25.6 105 28.2 105
2 120 33.9 120 25.1 120 26.5 120
2.25 135 33.6 135 24.8 135 25.3 135
2.5 150 33.2 150 24.6 150 24.2 150
2.75 165 32.9 165 24.3 165 23.6 165
3 180 32.6 180 24.2 180 23.1 180
3.25 195 32.7 195 24.1 195 22.6 195
3.5 210 32.6 210 24 210 22.3 210
3.75 225 31.8 225 23.9 225 22 225
4 240 31.3 240 23.8 240 21.9 240
4.25 255 30.8 255 23.8 255 21.8 255
4.5 270 30.2 270 23.7 270 21.6 270
4.75 285 29.6 285 23.6 285 21.5 285
5 300 28.8 300 23.5 300 21.4 300
5.25 315 28.2 315 23.3 315 21.3 315
5.5 330 27.6 330 23.3 330 21.3 330
5.75 345 27.1 345 23.2 345 21.3 345
6 360 26.3 360 23.2 360 21.3 360
6.25 375 25.9 375 23.1 375 21.3 375
6.5 390 25.6 390 23.1
6.75 405 23.1
7 420 22.9
7.25 435 22.9
7.5
7.75

Tub
tubo 1 40

35
45
40 30
35
25
30
Temp °C

25 20
20
15 15
10
5 10
0
0 50 100 150 200 250 300 350 400 450 5
 40
35
25
30

Temp °C
25 20
20
15 15
10
5 10
0
0 50 100 150 200 250 300 350 400 450 5
Tiempo
0
0 50 100 150 2
Column C

Tub
Tubo 2 45
40
40
35
30 35
Temp/ °C

25 30
20 25
15
20
10
5 15
0 10
0 50 100 150 200 250 300 350 400 450 500
Tiempo /s 5

0
0 50 100 150 2

Tubo 3
T
60
40
50
35
40 30
Temp/°C

30 25

20 20

10 15

10
0
0 50 100 150 200 250 300 350 400
5
Tiempo/s
0
0 50 100 150 200

Tubo 4
50
45
40
35
30
25
20
45
40
35
30
25
20
15
10
5
0
0 50 100 150 200 250 300 350 400
 Tubo 5 Tubo 6 Tubo 7 Tubo 8
Temp/°C Tiempo/s Temp/°C Tiempo/s Temp/°C Tiemp Temperatura/Tiempo/s
45.8 0 34.7 0 39.7 0 36.4 0
43.2 15 33.9 15 35.6 15 34.4 15
40.2 30 31 30 31.8 30 33.1 30
36.8 45 29 45 29.6 45 31.6 45
33.9 60 27.8 60 27.4 60 29.8 60
31.3 75 27.3 75 25.8 75 28.4 75
29.7 90 27 90 24.7 90 27.3 90
28.3 105 26.8 105 23.8 105 26.5 105
27.4 120 26.4 120 23.1 120 26 120
26.3 135 26.3 135 22.6 135 25.6 135
25.6 150 26.2 150 22.2 150 25.2 150
25.2 165 26.2 165 22 165 24.9 165
24.9 180 26.1 180 21.8 180 24.6 180
24.6 195 26.1 195 21.6 195 24.3 195
24.3 210 25.9 210 21.5 210 24.1 210
24.2 225 25.8 225 21.3 225 23.8 225
24 240 25.7 240 21.2 240 23.6 240
23.9 255 25.6 255 21.2 255 23.3 255
23.8 270 25.6 270 21.1 270 23.1 270
23.7 285 25.3 285 21.1 285 22.9 285
23.6 300 25.2 300 21.1 300 22.8 300
23.5 315 25.1 315 21.1 315 22.6 315
23.4 330 24.9 330 21 330 22.4 330
23.3 345 24.7 345 21 345 22.2 345
23.2 360 24.6 360 21 360 22.1 360
23.2 375 24.3 375 21 375 22 375
390 24.2 390 21.9
405 24.1 405 21.8
420 23.9 420 21.7
435 23.8 435 21.6
450 21.6
465 21.6

Tubo 8 Tubo 9
70

60

50

40

30

20

10
 40

30

20

10

0
0 50 100 150 200 250 300 350 400
50 100 150 200 250 300 350 400

Tubo 6 Tubo 7
40

35

30

25

20

15

10

50 100 150 200 250 300 350 400 0

0 50 100 150 200 250 300 350 400

Tubo 5

50 100 150 200 250 300 350 400 450 500

 Tubo 9
Temp/°C Tiempo/s Temp/°C
35.5 0 57.2
32.2 15 54.2
30.5 30 48.5
29.8 45 44.3
29.2 60 41.8
28.9 75 40.8
28.8 90 39.7
28.6 105 36.7
28.3 120 35.2
28.1 135 34.1
27.7 150 33.2
27.3 165 31.6
27 180 30.8
26.8 195 29.9
26.5 210 29.2
26.1 225 28.6
25.9 240 27.8
25.7 255 27.2
25.3 270 26.7
25.2 285 26.2
25 300 25.6
24.8 315 25.1
24.6 330 24.3
24.4 345 24.2
24.2 360 23.3
375 23.6
390 22.3
405 23.1
420 22.9
435 22.9
450

Tubo 9
 250 300 350 400 450 500

ubo 7

250 300 350 400 450 500

 Tubo 4
50
45
40
35
30

Temp/°C
25
20
15
10
5
0
0 50 100 150 200 250 300 35
Tiempo/s

Tubo 5
40
35
30
25
Temp/°C

20
15
10
5
0
0 50 100 150 200 250 300 350 400
Tiempo/s

Tubo 6
45

40

35

30

25
Temp/°C

20
 45

40

35

30

25

Temp/°C
20

15

10

0
0 50 100 150 200 250 300

Tiempo/s
bo 4 Tubo 7
40
35
30
25

Temp/°C
20
15
10
5
0
200 250 300 350 400 0 50 100 150 200 250 300 350 400 450 500
Tiempo/s Tiempo/s

ubo 5
Tubo 8
40
35
30
25
Temp/°C

20
15
10
0 250 300 350 400 450 500 5
Tiempo/s 0
0 50 100 150 200 250 300 350 400
Tiempo/s

Tubo 6
Tubo 9
70

60

50

40
p/°C
 70

60

50

40

Temp/°C
30

20

10

0 200 250 300 350 400 0

0 50 100 150 200 250 300 350 400 450
Tiempo/s
Tiempo/s
0 400 450 500

50 300 350 400

 300 350 400 450 500

s
 tubo 1

45 50
40 45
35 40
30 35
Temp °C

25 30

Temp/°C
20
25
15
10 20
5 15
0 10
0 50 100 150 200 250 300
5
Tiempo 0
0 50 100

Column C

Tubo 2
40 40
35 35
30 30
Temp/ °C

25 25

Temp/°C
20 20
15 15
10
10
5
5
0
0 50 100 150 200 250 300 350 400 450 500 0
0 50
Tiempo /s

Tubo 3
60 45
40
50
35
40 30
Temp/°C

25
Temp/°C

30
20
20
15
10 10
5
0
0 50 100 150 200 250 300 0
0 50 10
Tiempo/s
10 10
5
0
0 50 100 150 200 250 300 0
0 50 10
Tiempo/s
 Tubo 4 Tubo 7
50 40
45 35
40
30
35
30 25

Temp/°C
25 20
20 15
15
10
10
5 5
0 0
0 50 100 150 200 250 300 0 50 100 150 2
Tiempo/s Tiempo/s

Tubo 5
40 Tubo 8
35 40
30 35
25 30
Temp/°C

20
25
Temp/°C
15
20
10
15
5
10
0
0 50 100 150 200 250 5
Tiempo/s 0
0 50 100 150
Tiempo/s

Tubo 6
45 Tubo
40 70
35
30 60

25
50
20
15 40
Temp/°C

10
30
5
0 20
0 50 100 150 200 250 300
Tiempo/s 10

0
0 50 100 150 200 2
Tiem
 Temp
10
30
5
0 20
0 50 100 150 200 250 300
Tiempo/s 10

0
0 50 100 150 200 2
Tiem
 Tubo 7

50 100 150 200 250 300

Tiempo/s

Tubo 8

50 100 150 200 250 300

Tiempo/s

Tubo 9

50 100 150 200 250 300 350 400 450 500

Tiempo/s
50 100 150 200 250 300 350 400 450 500
Tiempo/s
Tubo g/fenol g/p-toluidina t punto eutetico T punto eutetico
1 2 0 4.6843 40.7206
2 1.75 0.25 83.1078 26.0323
3 1.5 0.5 137.3506 23.868
4 1.25 0.75 120.878 23.0044
5 1 1 78.7064 27.0002
6 0.75 1.25 71.3953 24.3753
7 0.5 1.5 110.0128 25.5688
8 0.25 1.75 32.9012 29.7483
9 0 2 88.61 35.79

p-toluidina vs tiempo f
160 160

140 140

120 120

100 100

80 80

60 60

40 40

20 20

0 0
0 0.5 1 1.5 2 2.5 0 0.5

p-toluidina vs Temperatura feno

45 45

40 40

35 35

30 30

25
25
20
20
15
15
10
10
5
5
0
0 0.5
0
0 0.5 1 1.5 2 2.5
 fenol vs tiempo

0.5 1 1.5 2 2.5

fenol vs Temperatura

0.5 1 1.5 2 2.5

 p-toluidina fenol Temperatura de
TUBO
fusión (°C)
(%n) (%n)
1 0 100 42.2
2 12.5 87.5 35.8
3 25 75 54.6
4 37.5 62.5 45.8
5 50 50 34.7
6 62.5 37.5 39.7
7 75 25 36.4
8 87.5 12.5 35.5
9 100 0 57.2

g/p- n xp
Tubo g/fenol t punto eutetico n fenol total x fenol
toluidina ptoluidina toluidina
1 2 0 4.6843 0.02125072 0 0.0212507 1 0
2 1.75 0.25 83.1078 0.01859438 0.002333 0.0209274 0.8885174 0.1114826
3 1.5 0.5 137.3506 0.01593804 0.0046661 0.0206041 0.7735363 0.2264637
4 1.25 0.75 120.878 0.0132817 0.0069991 0.0202808 0.6548894 0.3451106
5 1 1 78.7064 0.01062536 0.0093322 0.0199575 0.5323985 0.4676015
6 0.75 1.25 71.3953 0.00796902 0.0116652 0.0196342 0.4058737 0.5941263
7 0.5 1.5 110.0128 0.00531268 0.0139983 0.0193109 0.2751125 0.7248875
8 0.25 1.75 32.9012 0.00265634 0.0163313 0.0189876 0.1398984 0.8601016
9 0 2 88.61 0 0.0186643 0.0186643 0 1

DIAGRAMA DE FASES FENOL EN FUNCION DE P-TOLUIDINA

%(m/m) T Fenol T p-Tol

0 40.7206 35.79
12.5 26.0323 29.7483
25 23.868 25.5688
37.5 23.044 24.3753
50 27.002 27.002

Diagrama eut
40
35
30
 Diagrama eut
%(m/m) T Fenol T p-Tol 40
35
0 33.9554 33.9554
30
12.5 24.71 29.683 25
25 22.972 26.0332

T (°C)
20
37.5 26.377 23.03 15
50 27.416 27.416 10
5
0
0 10 20 30
Composicion

T Fenol

%(m/m) T T e
0 33.9554 24.59
12.5 29.683 24.59 Diagrama de
25 26.033 24.59 40
30.96 24.59 24.59 35
37.5 26.377 24.59 30
50 27.416 24.59 25

T /(°C)
20
15
10
5
0
0 10 20
Com

T
 Diagrama de fases eutectico
45

40

35

30
T punto
eutetico
Temperatura (C)

25
40.7206 35.79
26.0323 29.7483
20
23.868 25.5688
23.0044 24.3753 15
27.0002 27.0002
24.3753 23.0044 10
25.5688 23.868
29.7483 26.0323 5
35.79 40.7206
0
0 10 20 30 40 50 60

Composicion porcentual expresada en masa

LUIDINA
T Fenol T p-Tol

Diagrama eutectico
 Diagrama eutectico

10 20 30 40 50 60
Composicion molar (%)

T Fenol T p-Tol

Diagrama de fases eutectico

10 20 30 40 50 60
Composicion molar

T Te
50 60
t T
25 26.03321
37.5 23.03

-0.2402568
32.03963
-1