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4
80. Ans ( 1 ) 9
500 × 10 −
9
NCERT Pg # 295 = 125 × 10
−
= s3
4
81. Ans ( 3 ) s = 5 × 10–3 = s
NCERT Pg # 294
[OH–] = 2s
82. Ans ( 1 )
NCET-Pg : 287-288 [OH–] = 2 × 5 × 10–3 = 10–2
83. Ans ( 3 ) pOH = 2
NCERT-Pg : 278,279
pH = 12
84. Ans ( 4 )
NCERT–XI, Pg#288 104. Ans ( 1 )
−−−−−
kw
SECTION-B
↓ h=√
kb c ↑
87. Ans ( 1 ) 106. Ans ( 1 )
NCERT XI Pg # 56 BiOCl ⇒ BiO+ Cl–
1016CMD303122081 HS-3/11
TARGET:PRE-MEDICAL 2023/27-03-2023
108. Ans ( 3 ) 115. Ans ( 2 )
2 2
E4 1 6 36 9
= ( ) ×( ) = =
E6 4 1 16 4
116. Ans ( 1 )
h 6.636 × 10 34
−
Δx = =
4πmΔν 4 × 3.14 × 0.1 × 3 × 10 − 8
117. Ans ( 3 )
C H O
26.67 2.22 71.11
26.67 2.22 71.11
109. Ans ( 2 ) Relative mole
12 1 16
1
X O2 = Simplest Ratio of
3 2.22 2.22 4.44
2 moles 2.22 2.22 2.22
X H2 =
3
K p = (P H 2 )2 (P O2 ) 1 1 2
2
2 1 1 1
Kp = ( X ) ( X )
3 3 HCO2 is empirical formula
4
Kp =
H2C2O4 molecular formula
27
110. Ans ( 3 ) 118. Ans ( 3 )
nR D−d Urea used to stabilize H2O2 from
α= ( )
Δn g d decomposition.
1 D
0.7 = ( − 1) 119. Ans ( 3 )
2 d
D
e– rich hydride = 8e– + ℓ.p.
1.4 = −1
d 120. Ans ( 4 )
D As per E.N.
= 2.4
d
d 1 121. Ans ( 3 )
=
D 2.4 AgF > AgCl > AgI
d 5
D
=
12
123. Ans ( 2 )
sp hybridisation is known as diagonal
111. Ans ( 3 )
h
hybridisation
λ=
√
−−−−−−
2mKE 124. Ans ( 2 )
112. Ans ( 2 ) Concept
Circumference = 2πr3 125. Ans ( 3 )
32
( ) In sp3d hybridisation lone pair at equatorial
= 2 × 3.14 × 0.529 ×
3 127. Ans ( 1 )
= 9.96 A°≈10 (1) 111 → Roentgenium
114. Ans ( 2 ) (2) 107 → Bohrium
Radial node = n – ℓ – 1 (3) 103 → Lawrencium
Angular node = ℓ (4) 112 → Copernicium
HS-4/11 1016CMD303122081
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128. Ans ( 2 ) 138. Ans ( 3 )
I.E. → Ne < Ne+ P(Vm – b) = RT
Pb
+ve Z = 1+ = 1.25
Diff. ions of same element I . E. ∝ RT
−ve
Pb
= 0.25
129. Ans ( 1 ) RT
RT b
Li+ ≥ Mg+2 (Ionic radius) ⇒ = = 4b
P 0.25
SOH < SeOH < TeOH (Basic nature) RT
Vm − b = = 4b
P
Li < Na ≃ K ≃ Rb ≃ Cs (Zeff accn to slater) Vm = 5b = xb
x=5
130. Ans ( 3 )
139. Ans ( 3 )
For n = 7
for any adiabatic process ΔSsurr = 0
7s2 6d2 5f0 → Thorium for rev. adiabatic process ΔSuniv = 0
7 period, f-block, 3 group ΔSsurr = 0
∴ ΔSsys = 0
131. Ans ( 3 )
for irrev. adiabatic process ΔSuniv > 0
I.E. → B > Tℓ > Ga > Aℓ > In
ΔSsurr = 0
due to Lanthanoid contraction & Transition contraction
∴ ΔSsys > 0
132. Ans ( 2 )
NCERT XI, Page # 298 140. Ans ( 1 )
4NH3 + 5O2 → 4NO + 6H2O
133. Ans ( 3 ) 2 mol 2 mol
NCERT XI, Page # 304 2 2
134. Ans ( 1 ) 4 5
Smallest s-block, element is Be having high density. 0.5 0.4
O2 is L.R.
135. Ans ( 3 )
NCERT XI, Part-2 Page # 300 5mol of O2 formed 4 mole of NO
2 mol of O2 with 75% yield
SECTION-B 4 3
× 2× = 1.2mol
5 4
136. Ans ( 3 )
141. Ans ( 1 )
ΔG = ΔH – TΔS mass of 1 electron = 9.1 × 10–31 g
1
no. of electron in 1 kg =
ΔG > 0 9.1 × 10 − 31
1
mole of electron =
ΔH > TΔS 9.1 × 10 31
−
× 6.02 × 1023
1
–1 = × 108
ΔH > 70 × 450 J mol 9.1 × 6.02
142. Ans ( 2 )
–1
ΔH > 31.5 KJ mol 1 1
E3 – E1 = − 54 [ 2
− ]
3 12
137. Ans ( 4 ) −8
It is an endothermic reaction. = − 54 ( ) = 48 KJ
9
1016CMD303122081 HS-5/11
TARGET:PRE-MEDICAL 2023/27-03-2023
143. Ans ( 2 ) 152. Ans ( 2 )
32 mass of X combine with 72 mass of Y 1
r2 2
−
P=4 [ 4+ ]
8 mass of X combine with 'a' mass of Y 2
1
32 mass of X combine with 4a mass of Y 2 −
r 2
P = 4 × (4)–1/2 [1+ ]
Ratio of Y in B and C is 3 : 5 8
72 3 1
= 2 −
4a 5 r 2
P=2 [ 1+ ]
a = 30 8
145. Ans ( 2 ) r2
P=2–
Fact 8
3R Pf = 60 × (8 – v) – 180 × v = 0
=
4
⇒ 240 v = 60 × 8
163. Ans ( 4 )
v = 2 m/sec
168. Ans ( 2 )
To cross the river in shortest path,
V sin θ = VR
v = v1 + v2 + v3 + v4 –
– – – – 2 sin θ = √3
−√ 2Gm √ 2Gm √ 2Gm √ 2Gm
= − − − –
ℓ ℓ ℓ ℓ √3
– sin θ = ⇒ θ = 60°
√ 2Gm 2
= − 4
ℓ So, direction from river flow = (90 + 60) = 150°
1016CMD303122081 HS-7/11
TARGET:PRE-MEDICAL 2023/27-03-2023
169. Ans ( 1 ) 174. Ans ( 1 )
aP = apulley = 2 m/s2,
acp = 1 m/s2 ↑ , a c ⃗ = a cp
⃗ + ap
⃗ = 3m/s 2 ↑
175. Ans ( 2 )
T1sin30° + T2sin60° = 50 ......(1)
T1cos30° = T2cos60° ......(2)
VAB = VA –VB –
T1 = 25 N, T2 = 25 3 N √
VAB = √
−−
2−−−−
+32
4 = 5 km/hr 176. Ans ( 4 )
–1 vA
α = tan ( )
vB
170. Ans ( 4 ) –
N = 5√3
fℓ = μN
– = 6.9
= 4√3
T=0
177. Ans ( 1 )
Moment of inertia of solid sphere of mass M
1 2
h = – (u sin θ) t + gt and radius R about an axis passing through the
2
1 2
40 = – (20 sin 30°) t + × 10 × t 2 centre of mass is : I = M R 2. Let the radius
2 5
t = 4 sec of the disc is r.
171. Ans ( 1 ) Moment of inertia of circular disc of radius r
and mass M about an axis passing through the
s+s+s 3s 3s centre of mass and perpendicular to its plane
vavg =
s s s = = × 6
3s+2s+s 6s
2
+
3
+
6 6 1
= M r 2.
= 3 m/sec 2
Using theorem of parallel axes, moment of
172. Ans ( 4 )
ΔP = Area of F–t graph
inertia of disc about its edge is:
1 3
M(v2 – v1) = 50 × 5 + 75 × 5 I′ = Mr 2 + Mr 2 = Mr 2
2 2
16(v – 0) = 250 + 375 = 625
Given : I = I'
625
v= ≈ 39 m/sec 2 3
16 or MR 2 = Mr 2
5 2
173. Ans ( 2 ) 4
or r2 = R2
dm 15
Minimum rate of burning fuel is 2R
dt
dm
or r = −−
√ 15
∴ mg = u
dt
dm mg 1000 × 10 178. Ans ( 2 )
or, = = = 100 kg/s. FNet = 0; τNet ≠ 0
dt u 100
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179. Ans ( 1 ) SECTION-B
186. Ans ( 3 )
1 1 2
M1 L1 T
−
n2 = n1( ) ( ) ( )
M2 L2 T2
gm 1 cm 1 sec −2
= 100 ( ) ( ) ( )
kg m min
F(0.5) = 10g(0.5) ⇒ F = 100 N 1 1
gm cm sec − 2
180. Ans ( 2 ) = 100 ( ) ( ) ( )
103 gm 102 cm 60 sec
3600
n2 = = 3.6
103
187. Ans ( 4 )
KE ∝ t
1 2
mv ∝ t
2
181. Ans ( 4 ) v∝ t √
A = 10–6m2 dv 1
T 100 a= ∝
(
A
) (
10 6 −
)
100 100 dt 2√t
Y = = = × m
Δl (
0.1
) 10− 6 0.1 F = ma ∝
l 100 2√t
4
10 1
= = 1011 N /m 2 ∴F∝
7
10
−
√t
1016CMD303122081 HS-9/11
TARGET:PRE-MEDICAL 2023/27-03-2023
189. Ans ( 2 ) 192. Ans ( 1 )
(a) Vy = u sinθ – gt 2 −
−−− −
−−
v1 =
– √5gR = 2√gR
(b) Vx = u cosθ √ 5
Vx = constant v2 = v21 − 2gR ⇒ v2 = 4gR − 2gR
(c) x = u cosθ t
x∝t
1
(d) y = u sinθ t – gt2
2
190. Ans ( 3 )
x = αt2 – βt3
dx
v= = 2αt − 3βt 2
dt
dv ⇒ v = √−−−
2gR
−
a= = 2α − 6βt
dt v2
(a) When it reaches starting point x = 0 ac = = 2g
R
2 3 g
αt – βt = 0 at 1 1 1
tan α = = = ⇒ α = tan −
( )
α ac 2g 2 2
t=
β
193. Ans ( 3 )
(b) v = 0
By COLM
2αt – 3βt3 = 0
2α
t= mu + 0 = (m + nm)Vc
3β
(c) at t = 0 u
Vc =
v=0 (1 + n)
a = 2α By COME
(d) at t α
=
1 1 u2
3β mu 2 + 0 = m(1 + n) + mgh
α 2 2 (1 + n)
2
a = 2α − 6β ×
3β 1 1
a=0 mu 2 [1 − ] = mgh
2 1+n
−−−−−−−−−−−
191. Ans ( 2 ) 1
u = √2gh (1 + )
1 n
FCA = F CB
3 194. Ans ( 1 )
gx 2
y = xtanθ – (1 + tan2θ)
2u 2
10 × 20
10 = 20tanθ – (1 + tan2θ)
GM A M 1 GM B M 2 × 20
=
x2 3 (1 − x) 2 10 = 20tanθ – 5(1 + tan2θ)
4 1 1 2 tan2θ – 4tanθ + 3 = 0
= (1 − x)
3 x2 3
(tanθ – 1) (tanθ – 3) = 0
2 1 2
⇒ = ⇒ x= m tanθ = 1 ⇒ θ = 45°
x 1−x 3
HS-10/11 1016CMD303122081
ENTHUSIAST, LEADER & ACHIEVER COURSE/PHASE-ALL ENTHUSE, MLA, MLB, MLC, MLD, MLE, MLF, MLG, MLH, MLI, MLJ,
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195. Ans ( 1 ) 198. Ans ( 2 )
Let the angular velocity be ω, when the insect
5
−− −−−−−−−
11 3
−−−−−−
10
−−
3
−
2 −
10
− −−
rA ( × )−( × ) 9 3
7 = = √ = √
h= R rB ⎷ ( × 83
) −( ×10 3
)2 10 6 2
5
1016CMD303122081 HS-11/11