:   

( "!  #$ )731 *( 1
:, . /$, 1 2 -1-1
C+ D

2 A+ B

67 3.,  B ; ., 7 6,  <:2-1

.!  /$, . > @, ,A <. 2 : 3-1
! /$, !DE #@,< >; . 2 :4-1
!/$, !DE #@, >; H.,  :5-1

---------------------------------------------------------------------------------------------------------Qr =
--------------------------------------------------------------

. Qr =

K=

[C ]q [D]q
[A]q 2

[C ] [D]
[A]2 [B]

[C ] [D] :!  ;7 3.,  

[A]2

:IJ
:/$, 1 :1-1

B ; ., 7 6,  :2-1

--------------------------------------------------------------

:>K L "! K =

[C ]q [D]q
[A]q 2 [B]q

:MN L "! , ,A :3-1

--------------------------------------------------------------

xf

: ! ! /$, !DE #@, >; :4-1

x max
.O  ;QE # 2RS H.,  !$, 2 L I# #; 3$,    H., !

( "!  #$ )732 *( 2

: , 3$, V. ;,.>

HCO2 H + C 6 H 5 CO2
HCO2 + C 6 H 5 CO2 H (1
( aq )

( aq )

( aq )

C 2 H 5 CO2 + H 3O +

C 2 H 5 CO2 H + H 2 O
( aq )

( )

( aq )

(2

( aq )

NH 4 + HO

NH 3 + H 2 O
( aq )

( aq )

( )

(3

( aq )

( aq )

. /$, 1 . /  ;E 2

---------------------------------------------------------------------------------------------------------

[HCO ] [C H CO H ]
[HCO H ] [C H CO ]
[C H CO ] [H O ]
=

:IJ

Qr =

(1

-------------------------------------------------------------

Qr

[C 2 H 5CO2 H ]

(2

--------------------------------------------------------------

[NH ] [HO ]
=
+

Qr

[NH 3 ]

(3

( "!  #$ )733 *( 3

. Ag 3 PO4 : S$ $"  . AgC 2 S$ ,; AgC S$  6 . 6,( 1
. /$, 1  / "! 2( 2
1

---------------------------------------------------------------------------------------------------------:IJ
(1


Ag + C AgC
+

( aq)

( aq)

(s)


Ag + + 2 C AgC 2
( aq )

( aq )

(s)


3
Ag 3 PO 4 3 Ag + + PO 4
( aq )

(s)

( aq )

--------------------------------------------------------------

Qr =

1
C
1

[Ag ] [
+

Qr =

:MN L

[Ag ] [C ]
= [Ag ] [PO ]

(2

:>K L

+
Qr
:KK L( 2
4

( "!  #$ )73 4 *( 4

:!, /$,; ,.>

CH 3CO2 H + H 2 O
CH 3CO2 + H 3 O +

( aq )

[CH

( )

CO 2

( aq )

. /$, 7D , ,A ;. 2( 1

: , "!  #> (2
+
4
= H 3 O q = 1, 2 10 mol /

] [
q

( aq )

[CH 3CO2 H ]q = 9,6 10 4 mol /

. /$, 7D > @, ,A 6

--------------------------------------------------------------------------------------------------------:IJ
, ,A ;. (1

[CH CO ] [H O ]
K=

[CH 3CO2 H ]q

--------------------------------------------------------------

[CH CO ] [H O ]

K=

(2

[CH 3 CO 2 H ]q

(1,2 10 4 ) 2
= 1,5 10 5
9,6 10 4

( "!  #$ )73 5 *( 5

3
+

c1 = 0,32mo / W X ( K + I )   ;50cm M ,L S1 VL "! [6\> l

( aq )

. 8m.mol

( aq )

(2 K + S 2 O8 )   ,;>! A ;10m.mol ]< S> A

( aq )

2m.mol

( aq )

V  2_  .# ! EA   ,> E > 71[ A $\ 2_^ 3>
./$, . 6, -1
0m.mol :@ /$, #@ 71[ #E   #@, #I `  #-2
/$, #@, #@, / /$, 1 * 3K VL "! 6( 3

--------------------------------------------------------------------------------------------------------:IJ
:/$, . (1
2I +

S 2 O8
2

2SO4

I2

.#; S 2 O8

 n2  #; I  n1  ,(2

: I S 2 O8 2  /$, #@ #I

(aq )
( aq )

2I

n1
n1 2 x

S 2 O8
2SO4
 
0
n2
2x
n2 x

. [I 2 ] =
. [SO4 2 ] =

/$, .

I2

m.mol : #@,
0
x

0
x

x
V

[I ] = n V 2 x

L
#; L
t eL #E

n x
2x
2

S 2 O8 = 2
V
V
3
3
3
n1 = c1 V1 = 0,32mol / 50 10 = 5 10 mol = 16 10 m.mol = 16m.mol : E#
V = V1 + V2 = 50 + 100 = 150ml : L !  L
2
2
/$, .
2I
+
S 2 O8
2 SO4
+
I2
 
L
m.mol : #@,
0
0
16
10
0
#; L
x
x
16 2 x
10 x
2x
t eL #E

n( S 2 O8

2m.mol :@ /$, #@ 71[ #E 

2
) = 8m.mol n( I ) = 1m.mol n( SO4 ) = 4m.mol
n( I 2 ) = 2m.mol

8m.mol :@ /$, #@ 71[ #E 

2

. n( S 2 O8 ) = 2m.mol n( I ) = 0 n( SO4 2 ) = 16m.mol

n( I 2 ) = 8m.mol

--------------------------------------------------------------

:/$, 1 (3
x
2
x
( )2
2 2
[
I 2 ] SO4
4x3
V
V
Qr =
=
=
2
2
n 2 x 2 n2 x (n1 2 x) 2 (n2 x)
I S 2 O8
( 1
)
V
V
./$, #@, H., /$, 1

( "!  #$ )73 6 *( 6

: WX gXE; hL ! L ii ( * S = 1cm 2 ; l = 1cm) 1 ` j@>

[ ] [

. G = 2,03 10 4 S : #E" c = 5 10 3 mol / l

./iL /$, . 6,( 1
./$, 7 "! 1#,> N> N X # (2
. /$, 7D !DE #@, >; 6( 3
./$, 7 . > @K , ,A 6( 4
H O + = 3,5 10 2 S .m 2 / mol :!`.>
3

C H COO = 3,23 10 3 S .m 2 / mol

:IJ
./iL /$, . (1

+
C 6 H 5 COOH + H 2 O
C 6 H 5 COO + H 3O
( aq )

(l )

( aq )

( aq )

--------------------------------------------------------------

C 6 H 5 COOH + H 2 O
( aq )

(l )

C 6 H 5 COO + H 3O
( aq )

( aq )

:/$, #@ #I (2

/$, .

 
"
"

n1
n1 xq

m.mol : #@,
0

xq

xq

xq

L
#; L
, #E

:2_ i ;.

n( H 3 O + ) = n(C 6 H 5 COO ) : E# #@, #I 31 

: ! * @ 3. l;\ g7

=G

[C H COO ]

= H 3O +

[C 6 H 5 COOH ] =

n1 x q
V

S
: G = :  .> 1 DI 
S

: !  l;\ @* 3.

10 2 m
10 4 m 2
= 0,53mol / m 3 = 0,53 10 3 mol /
+ 3,23 10 3 ) S .m 2 .mol 1
: E#

2,03 10 4 S
(3,5 10 2
=

n1 x q

= c 0 ,53 mol / = 5 .10 3 0,53 .10 3 = 4 , 47 10 3 mol /

V
V
--------------------------------------------------------------

:!DE #@,( >; 3

. #L
  /$,  gXE; h #@, #I 31 
x max = n1 :

xq
x max

xq
n1

[H O ]
+

c.V

[H O ] = 0,53 10
+

5 10

[C H COO ] [H O ] = (0,53 10

= 0,106 = 10,6 o o
:, ,A (4
3 2

)
= 6,28 10 5
[C 6 H 5COOH ]
(4,47 10 )

( "!  #$ )737 *( 7

K=

. p >N /$ . 6,( 1
# "! D /\L Q,E p> 7> r $,_ c X, ;E >N L i j@> (2
: !,
3
3
2
c(mol )l )
10
5.10
10
33,3
100,4
70
( .S .cm 1 )
. L / "! #I,> N> r !.$ ! X, #I
/., 7 X, H., /. !DE #@, @ >; Q,E  Q,E,( 3
4

 HO = 19,9mS .m 2 .mol 1 :!`.>

NH = 7,34mS .m 2 .mol 1
+

(1:IJ
+

NH 3 + H 2 O
NH 4 + HO
( aq )

(l )

( aq )

( aq )

-------------------------------------------------------------+

NH 3 + H 2 O
( aq )

NH 4 + HO

(l )

:/$, #@ #I (2

/$, .

( aq )

( aq )

 
"
"

n1
n1 xq

m.mol : #@,
0

xq

xq

xq

L
#; L
, #E

:2_ i ;.

n( NH 4 ) = n( HO ) : E# #@, #I 31 
: ! * @ 3. l;\ g7

:# H;`
3

10
33,3

5.10
70

,4 10 S 10 m
[NH ] = [HO ] = (19,9.100
10 + 7,34.10 ) S .m .mol
[NH ] = c [NH ] = 10 0,37.10 = 9,63 10
+

3 q

3 q

= 0,37 mol / m 3 = 0,37 10 3 mol / l

mol / l
:!>K L ;E

= 0,257 mol / m 3 = 0,257 10 3 mol / l

mol / l

S 10 m
[NH ] = [HO ] = (19,9.1033,3+ 10
= 0,122mol / m
7,34.10 ) S .m .mol
[NH ] = c [NH ] = 10 0,122.10 = 8,78 10 mol / l
+

3 q

( .S .cm 1 )
: N L ;E

[NH ] = [HO ] = (19,9.1070 +107,34S.10 10)Sm.m .mol

[NH ] = c [NH ] = 5.10 0,257.10 = 4,74 10
4

c(mol )l )

10
100,4

:sK L ;E

1
2

= 0,122 10 3 mol / l

--------------------------------------------------------------

:!DE #@,( >; 3

. #L
  /$,>  N #@, #I 31 
5

xf
x max

xq
xmax

[NH ]
+

xq

n1

[NH ]

c.V

x max = n1

: V L ;E

[NH ] = 0,37 10
=
+

10 2

= 0,037 = 3,7 o o

:!>K L ;E

[NH ] = 0,257 .10

=
+

5.10 3

0,05 = 5 o o

:sK L ;E

[NH ] = 0,122 .10

+

10 3

0,12 = 12 o o

.L X t*E  X ^ 3>. /., 7 X, H., !DE #@,>;

( "!  #$ )748 *( 8

. p g>K h /$ . 6,( 1
. /$, 7 . > @K , ,A ;. 6,( 2
. c = 0,01mol / l :  1[ g>K hL X V = 100m D ;  ,.> (3
. 1,2 10 4 :  , #E /$, #@  H@L , #E K = 1,6 10 4 , ,A 
 ,>   "!  N< ,_ .$ X,( 4
.2_ pH Q,E,

:IJ
: p g>K h /$ . (1

HCOOH + H 2 O
HCOO + H 3O +
( aq )

( aq )

(l )

( aq )

--------------------------------------------------------------

K=

:, ,A ;. (2

[HCOO ] [H O ]

[HCOOH ]

--------------------------------------------------------------

no ( HCOOH ) = c.V = 0,01mol / 100 10 3 = 10 3 mol = 1m.mol :! #; HCOOH ( 3

(aq )

:/$, #@ #I

( aq )

no

no xq

/$, .

HCOO + H 3O +

HCOOH + H 2 O

( aq )

(l )

( aq )

m.mol : 
0
"
"
xq

m.mol : #@,
0

L
#; L

xq

xq

, #E
:E# #@, #I 31 

[HCOO ] = [H O ] = xV

: n( HCOO ) = n( H 3O + ) = xq

)
V
=
no xq

xq

V2
:
x q
[HCOOH ]
c
V
V
2
K .xq
xq
K .xq xq
Kc
2 =0

K (c
)= 2

V
V
V
V
2
K .c.V 2 K .V .xq xq
2
+ K .V .xq KcV = 0

= 0 : @#
V2
= ( KV ) 2 + 4 KcV 2 :>K I#  . !
K=

xq

[HCOO ] [H O ] =

xq

KV + ( KV ) 2 + 4 KV 2 .c 1,6.10 4.0,1 + (1,6.10 4.0,1) 2 + 4.1,6.10 4 (0,1) 2 .10 2

x1q =
=
1,2 10 4 mol
2
2
KV ( KV ) 2 + 4 KV 2 .c
<0
2
x q 1,2 10 4
:g7
HCOO = H 3O + =
=
= 1,2 10 3 mol /
V
0,1
n x
x
x
[HCOOH ] == o q = no q = c q = 10 2 1,2.10 3 = 8,8 10 3 mol / l
V
V
V
V
pH = og H 3O + = og (1,2 10 3 ) = 2,92 :2_ pH Q,E,>

x 2 q =

] [

888888888888888888888888888888888888888888888888888888888888888888888888888888888
(  /DE) !# ,      

 L$\ e>

-------------------------------------------------------------------------:IJ
. HNO2 / NO2 CH 3COOH / CH 3COO : ,1#, #* h ,IX(
-------------------------------------------------------------------------------------------------------------------------:/iL /$, .(

CH 3COOH + NO2
CH 3COO + HNO2
-----------------------------------------------------------------------------------------------------------------------:#;( 
2
3
4
3
n(CH 3COOH ) = C.V = 10 mol / 20 10 = 2 10 mol = 0,2 10 mol = 0,2m.mol
n( NO ) = C.V = 10 2 mol / 20 10 3 = 2 10 4 mol = 0,2 10 3 mol = 0,2m.mol
2

---------------------------------------------------------------------------------------------------------: /$, #@ #I (

CH 3COOH + NO2

CH 3COO + HNO2

/$, .

0,2 x f

0
x

#@,
0
x

L
#; L
,

xf

xf

DE L

: 
0
x

m.mol
0,2
0,2 x

0,2
0,2 x

0,2 x f

xf

-------------------------------------------------------------------------------------------------------:2_ i ;. (

[Na ] = [NO ] : 

( \w,> L !D  L)

: !  l;\ @* 3.

--------------------------------------------------------------------------------------------------------K=

: , ,A (

[HNO2 ].[CH3COO ]
[CH3COOH].[NO2 ]

n(CH 3COOH ) = n( NO ) = 0,2 x f

: #@, #I 31  ^3>

. CH 3COO = [HNO2 ] [ CH 3 COOH ] = NO2 : n(CH COO ) = n( HNO2 ) = x f : 1 DI 

K=

[CH COO ]

:!  l;\ , ,A

[NO ]

---------------------------------------------------------------------------------------------------------: e> E# (

[CH COO ] = 0,2. [NO ]]E 4.10

[CH COO ]

[NO ]

l;\ (1) K = 4.10 2 : p

[NO ] =

:l;\(2) *3.

:

Na +

+ NO + 0,2.CH COO

[NO ] = 0,87mol / m = 0,87 10

[CH COO ] = 1,74 10 mol /

mol / : X,;  .E

3

1,13 10 S (10 m)
1,13 10 S .m
=
0,87mo
2
2
1
(5 + 7,2 + 0,2 4,1) 10 S .m .mol
13,02 10 2 S .m 3 .mol 1

[CH COO ] = 0,2. [NO ] = 0,2 0,87 = 1,74mol / m

3

mol /

---------------------------------------------------------------------------------------------------------: (!   

x f = n( CH COO ) : #@, #I 31  E# =
3

xf
x max

n(CH 3 COO )
: .>
VS
n(CH 3 COO ) = [CH 3COO ] VS = 1,74 10 3 mol / 40 10 3 = 0,696 10 4 mol

: [ CH 3COO ] =

x max = 0,2m.mol = 0,2 10 3 mol : E#

0,696 10 4
=
= 0,348 34,8 O O :!,
0,2 10 3
 /DE !# ,  

xf

x max

. NO2 :! HNO2 hL @" #@(

------------------------------------------------------------------------------------------
HNO2 + H 2 O
NO2 + H 3O +
(

-------------------------------------------------------------------------------------------:hL #;(  

n( HNO2 ) = C.V = 10 2 mol / 50 10 3 = 5 10 4 mol = 0,5 10 3 mol = 0,5m.mol

: %& '* (

HNO2 + H 2 O

NO2 + H 3O

0,5
0,5 x

m.mol
"
"

0,5 x f

"

/$, .

0
x

0
x

#@,
0
x

xf

xf

xf

: 

L
#; L
,
DE L

.2@" = 22 o 0 N #L /$ D" !  j /$, 7 y" 100 o o  Ri! DE #@,  >; 3

0,5 x max = 0

,E h  7 #L
  /$, !  $,1V H" : M\*N #@,3

x max = 0,5m.mol
x f = x max = 0,22 0,5 = 0,11m.mol :
n( H O + )
3

[H O ] = n( HV O
+

10

xf
VS

:!DE #@,3

3
xf



x max
= x f : lS, #@, #I 31 3

0,11 10 3 mol
= 2,2 10 3 mol / :
50 10 3

HNO2 + H 2 O
0,5
0,5 x f = 0,39

m.mol
"
"

pH = og H 3O + = og (2,2 10 3 ) 2,66 : ]E

: /$, D> #E \ 3

+
/$, .
NO2 + H 3O
#@,
L
: 
0
0
0
#; L
0,11
0,11
0,11
DE L
x

[HNO2 ] = n( HNO2 ) = 0,39 10 3mol = 7,8 10 3 mol /

VS

50 10

 /DE !# ,  

11

.  z  L$\ j$> M 1N , 7 lL\ e,>

SBIRO ABDELKRIM lyce agricole

Oulad-Taima rgion d'agadir royaume du Maroc
Mail : sbiabdou@yahoo.fr
Msen messager :
sbiabdou@hotamail.fr
H", !

12