density (ρ)

T= 80 C = 353 K
ρ= A.B^-(1-T/Tc)^n (ρ = gr/mL; T=K)
KOMPONEN A B n Tc Tmin Tmax
C8H4O3 0.35183 0.2322 0.2346 791 404.26 791
C2H5OH 0.2657 0.26395 0.2367 516.25 195.05 516.25
C12H14O4 0.34999 0.25154 0.3525 757 296.15 757
H2O 0.3471 0.274 0.28571 647.13 273.16 647.13
H2SO4 0.42169 0.19356 0.28570 925.00000 283.46 363.49
Na2SO4 0.26141 0.1 0.28571 3700 1157 2000

kapasitas panas (Cp)

T= 130 C = 403 K
Cp = A+(B*T)+(C*T^2)+(D*T^3) (Cp= Joule/mol K; T=K)
KOMPONEN A B C D Tmin Tmax
C8H4O3 -105.627 1.96E+00 -3.66E-03 2.85E-06 405 712
C2H5OH 59.342 3.64E-01 -1.22E-03 1.80E-06 160 465
C12H14O4 125.381 1.58E+00 -3.47E-03 3.33E-06 270 681
H2O 92.503 -4.00E-02 -2.11E-04 5.35E-07 273 615
H2SO4 26.00400 0.70337 -0.00139 0.00000 296 879

Viskositas (µ)
Yaws, hal 487, table 22.1 viscosity of liquid
log µ = A+(B/T)+(C*T)+(D*T^2) (µ = cP; T=K)
T= 80 = 353 K
Komponen A B C D Tmin Tmax
C8H4O3 -25.1512 5.0387E+03 4.1950E-02 -2.4927E-05 405 791
C2H5OH -6.4406 1.1176E+03 1.3721E-02 -1.5465E-05 240 516
C12H14O4 -12.1587 2.5728E+03 1.8732E-02 -1.1566E-05 269 757
H2SO4 -18.7045 3.4962E+03 3.3080E-02 -1.7018E-05 283 367
H2O -10.2158 1.7925E+03 1.7730E-02 -1.2631E-05 273 643
Na2SO4 11.2905 -4.58E+03 -6.78E-03 9.24E-07 1180 1267
TOTAL -61.3803 9.4409E+03 0.1184282 -8.06826E-05 2650 4341

Konduktifitas panas (k)

Yaws, hal 535, table 24.1 thermal conductifity of liquid

organic: log k = A+B(1-T/C)^(2/7) (k=W/m.K;T=K) T=
inorganic:k= A+BT+CT^2
Komponen A B C Tmin Tmax k (25ᵒC)
C8H4O3 -1.6831 1.0293 791 404 751 -
C2H5OH -1.3172 0.6987 516.25 159 490 0.1694
C12H14O4 -1.3265 0.5567 757 269 719 0.1432
H2SO4 0.1553 1.07E-03 -1.29E-06 283 833 0.36
H2O -0.2758 4.61E-03 -5.54E-06 273 633 0.607
TOTAL -4.4473 2.2903819 2064.249993175 1388 3426 1.2796

Vapor Pressure (P)

Yaws, pers 7-1 hal. 159. Vapor Pressure Organic and Inorganic Compound
log P= A+(B/T)+(C log T)+(D*T)+(E*T^2) (P=mmHg , T=K) T=
 Komponen A B C D E log P
C2H5OH 71.2535 -5.50E+03 -2.14E+01 3.81E-10 5.03E-06 1.41E+00
C12H14O4 23.8442 -2.86E+03 -5.47E+00 3.74E-11 2.74E-07 1.47E+00
H2O 29.8605 -3.15E+03 -7.30E+04 2.42E-09 1.81E-06 -1.84E+05
 ρ (g/cm^3) ρ (kg/m^3) fv (m3/jam)
1.25419 1254.19
0.73262 732.62
1.0578 1057.8
0.9757 975.7
1.7647 1764.7
2.4495 2449.5

Cp 25 (g/cm^3) Cp (kg/m^3) fv (m3/jam)

264.72 2.77E+02
107.4 1.26E+02
374.9 4.15E+02
75.55 7.71E+01
139.95 1.52E+02

log µ µ fraksi mol

0.8250 6.6828
-0.3582 0.4384
0.3009 1.9992
0.7564 5.7068
-0.4531 0.3523
-3.9551 0.0001
-2.8841605583 15.1795426745

333 K

k fraksimol
0.157550286
0.1594126978
0.1397125053
2.6693365175
3.1199624425
6.2459744491

333 K
P
2.56E+01
2.92E+01
0.00E+00
NERACA MASSA
PABRIK DIETYL PHTHALATE dari PHTHALIC ANHYDRIDE dan ETYL ALKOHOL KAPASITAS 30.000 TON/TH

Kapasitas produksi = 30000.0000 ton/tahun

= 30000.0000 ton/th x 1 th/330 hari x 1 hari/24 j x 1000 kg/ton
= 3787.8788 kg/j 17.0625
kemurnian produk 0.9900 C12H14O4 3750.0000
impuritis 0.0100 H20 37.8788
3787.8788
REAKTOR
reaksi yang terjadi

C8H4O3 + 2 C2H5OH C12H14O4

kmol/jam kg/jam
DEP Terbentuk = 16.8919 3750.0000
Etanol 20% berlebihan

komposisi bahan terbentuk / berx

kmol/jam kg/jam
DEP Terbentuk = 16.8919 3750
H2O terbentuk = 16.8919 304.0540540541
PA brx = 16.8919 2500
EA brx = 33.7837837838 1554.0540540541

Komposisi Bahan Masuk Reaktor

kmol/jam kg/jam
PA masuk reaktor = 21.1149 3125.00000
MA masuk reaktor = 0.1602399754 15.70352
EA stci = 42.2297297297 1942.56757 EA recycle=
EA masuk reaktor = 50.6756756757 2331.08108 EA (FF)=
H2O dalam EA = 6.8160265529 122.68848 H2O impurities EA FF=
H2SO4 MR = 0.637755102 62.50000
H2O dalam H2SO4 = 0.070861678 1.27551 H2O dari recycle (Asumsi 2% H2O
5623.433509
Komposisi Bahan Keluar
kmol/jam kg/jam
PA = 4.2230 625.0000
MA = 0.1602 15.7035
EA = 16.8918918919 777.0270
H2O = 21.8446 393.2030
H2SO4 = 0.637755102 62.5000
DEP = 16.8919 3750.0000
5623.4335085886
NETRALIZER
Reaksi: H2SO4 +2NaOH -----> Na2SO4
M 0.637755102 1.2755102041 0
R 0.637755102 1.2755102041 0.637755102
S 0 0 0.637755102
C6H4(CO)2O +2NaOH ----> C8H4Na2O4
M 4.2229730 8.4459459459 0
R 4.2229730 8.4459459459 4.2229730
S 0 0 4.2229730
Kebutuhan NaOH= 10.0419361008 kmol/jam = 401.67744403
H2O (Impurities NaOH)= 24.1750313538 kmol/jam = 435.15056437
Neraca Massa Netralizer
Komponen BM Masuk kg/j Keluar
PA 148.0000 4.2230 625 0
MA 98.0000 0.1602 15.7035175879 0.0000
DEP 222.000 16.8919 3750 16.8919
H2O 18.0000 46.0196 828.3535283417 51.6784
H2SO4 98.0000 0.637755102 62.5 0
EA 46.000 16.8918918919 777.027027027 16.891891892
NaOH 40.0000 10.0419361008 401.6774440321 0
Na2SO4 142.0000 0 0 0.637755102
C8H4Na2O4 210.0000 0 0 4.2229730
C4H2Na2O4 160 0 0 0.1602
DECANTER 6460.2615
Komponen BM Masuk Decanter kg/j Densitas
MA 98.0000 0.0000 0 0.185
DEP 222.000 16.8919 3750 1.0578
H2O 18.0000 51.6783636159 930.2105450857 0.9757
EA 46.000 16.8919 777.027027027 0.73262
Na2SO4 142.0000 0.6378 90.5612244898 2.4495
C8H4Na2O4 210.0000 4.2230 886.8243243243 2.34
C4H2Na2O4 160 0.1602400 25.6383960619 2.2
6460.2615169888
Hasil Atas Decanter
Asumsi H2O sebagai hasil atas decanter sebesar 2% H2O terbentuk di reaktor
Komponen BM kmol/jam kg/j Densitas
DEP 222.000 16.8919 3750 1.0578
EA 46.000 16.8919 777.027027027 0.73262
H2O 18.0000 2.4422 43.9598689599 0.9757
4570.9868959869
Hasil Bawah Decanter
Komponen BM kmol/jam kg/j Densitas
H2O 18.0000 49.2361 886.2506761258 0.9757
Na2SO4 142.0000 0.6378 90.5612244898 2.4495
C8H4Na2O4 210.0000 4.2230 886.8243243243 2.34
C4H2Na2O4 160 0.1602400 25.6383960619 2.4
1889.2746210019
KELUAR DECANTER 6460.2615169888
EVAPORATOR
Bahan Masuk Evaporator 0.953358709
Komponen BM kmol/jam kg/j
DEP 222.000 16.8919 3750
EA 46.000 16.8919 777.027027027
H2O 18.0000 2.4422 43.9598689599
4570.9868959869
Evaporator dijalankan pada suhu 85 C
TD Bahan MA 202 C Berdasarkan titik didih bahan maka komponen yang menja
DEP 295 C dan yang menjadi hasil bawah evaporator adalah DEP dan
EA 78.29 C
H2O 100 C
Hasil Atas Evaporator
Komponen BM kmol/jam kg/j
EA 46.000 16.8919 777.027027027
H2O 18.0000 0.3378 6.0810810811
783.1081081081
Hasil Bawah Evaporator
Komponen BM kmol/jam kg/j
DEP 222.000 16.8919 3750
H2O 18.0000 2.1044 37.8787878788
3787.8787878788
KELUAR EVAPORATOR 4570.9868959869
MIXER
Komponen Masuk Mixer
Komponen BM kmol/jam kg/j
PA 148.0000 21.1149 3125
MA 98.0000 0.1602399754 15.7035175879
EA 46.000 50.6757 2331.0810810811
H2O 18.0000 4.8819 87.8733997155
5559.6579983845
Komponen Keluar Mixer
Komponen BM kmol/jam kg/j
PA 148.0000 21.1149 3125
MA 98.0000 0.1602399754 15.7035175879
EA 46.0000 50.6756756757 2331.0810810811
H2O 18.0000 4.8818555398 87.8733997155
5559.6579983845
AS 30.000 TON/TH
KOMPONEN BM
C8H4O3 148.0000
hari/24 j x 1000 kg/ton C2H5OH 46.000
C12H14O4 222.000
kg/jam 16.8919 kmol/jam H2SO4 98.0000
kg/jam 2.1044 kmol/jam NaOH 40.0000
Na2SO4 142.0000
H2O 18.0000
MA 98.0000
C8H4Na2O4 210.0000
+ H2O x= 0.8000

C8H4O3 + 2 C2H5OH C12H14O4 +

21.1148649 50.6756757 0
16.8919 33.7837838 16.8919
4.2230 16.8918919 16.8919

EA keluar reaktor= 16.8918918919 kmol/jam

EA masuk reaktor= 50.6756756757 kmol/jam

2331.08108
16.8918919 kmol/jam 777.027027 kg/jam
33.7837838 kmol/jam 1554.05405 kg/jam
O impurities EA FF= 81.7923186 kg/jam 4.5440177 kmol/jam

O dari recycle (Asumsi 2% H2O terbentuk )= 0.33783784 kmol/jam 6.0810810811 kg/jam

+2H2O C4H2O3 + 2NaOH ---> C4H2Na2O4

0 M 0.1602 0.3204799508 0
1.2755102041 R 0.1602 0.3204799508 0.1602
1.2755102041 S 0 0 0.1602
+H2O
0
4.2229730
4.222972973
kg/jam
kg/jam

kg/j
 0
0
3750
930.21054509
0
777.02702703
0
90.56122449
886.82432432
25.638396062
6460.261517
Data Kelarutan Bahan
MA bereaksi menjadi maleic acid
DEP 1g/100mL
H2O tercampur dengan etanol
EA tercampur dengan air
Na2SO4 13,9g/100mL
C8H4Na2O sedikit larut dalam air

volume
3545.0935905
1060.6139977
45.054698124
4650.7622863 densitas rata-rata= 0.98284681

volume
908.32292316
36.971310263
378.98475398
10.682665026 densitas rata-rata= 1.41522763
1334.9616524

han maka komponen yang menjadi hasil atas evaporator adalah EA dan H2O
wah evaporator adalah DEP dan MA
Tabel Neraca Massa Total
MIXER
Komponen Masuk (kg/jam)
FF RC
PA 3125.0000
MA 15.7035
EA 1554.0541 777.0270
H2O 81.7923 6.0811
DEP
H2SO4
NaOH
Na2SO4
C8H4Na2O4
C4H2Na2O4
TOTAL 5559.6580
Neraca Massa Overall
Masuk (kg/jam)
Komponen
FF Katalis
PA 3125.0000
MA 15.7035
EA 1554.0541
H2O 81.7923 1.2755
H2SO4 62.5000
NaOH
DEP
Na2SO4
C8H4Na2O4
C4H2Na2O4
TOTAL 5677.1534
Kemurnian Bahan Baku
PA 99.50%
EA 95%
H2SO4 98%
NaOH 48%

H2O x= 0.8000
0.3378378378
16.8919
17.2297

777.027027027
2331.0810810811

Tabel Neraca Massa Reaktor

Masuk (kg/jam)
Komponen Keluar (kg/jam)
MF Katalis
PA 3125.00000 625.0000
MA 15.70352 15.7035
EA 2331.08108 777.0270
H2SO4 62.50000 62.5000
H2O 87.87340 1.27551 393.2030
DEP 3750.0000
TOTAL 5623.4335 5623.4335

+ H2O
0
0.1602
0.1602

Tabel Neraca Massa Netralizer

Masuk (kg/jam)
Komponen Keluar (kg/jam)
Keluar Reaktor Penetral
PA 625.0000
MA 15.7035 0
DEP 3750.0000 3750
H2O 393.2030 435.1505643681 930.2105450857
H2SO4 62.5000
EA 777.0270 777.027027027
NaOH 401.6774440321
Na2SO4 90.5612244898
C8H4Na2O4 886.8243243243
C4H2Na2O4 25.6383960619
TOTAL 6460.2615 6460.261516989

Tabel Neraca Massa Dekanter

Keluar (kg/jam)
Komponen Masuk (kg/jam)
Hasil Atas Hasil Bawah
C4H2Na2O4 25.6383960619 0 25.6383960619
DEP 3750 3750
H2O 930.2105450857 43.9598689599 886.2506761258
EA 777.027027027 777.027027027
Na2SO4 90.5612244898 90.5612244898
C8H4Na2O4 886.8243243243 886.8243243243
TOTAL 6460.2615169888 6460.2615169888

Tabel Neraca Massa Evaporator

Keluar (kg/jam)
Komponen Masuk (kg/jam)
Hasil Atas Hasil Bawah

DEP 3750 3750

EA 777.027027027 777.027027027
 H2O 43.9598689599 6.0810810811 37.8787878788
TOTAL 4570.9868959869 4570.9868959869

Tabel Neraca Massa Mixer

Masuk (kg/jam)
Komponen Keluar (kg/jam)
FF RC
PA 3125 3125
MA 15.7035175879 15.7035175879
EA 1554.0540540541 777.027027027 2331.081081081
H2O 81.7923186344 6.0810810811 87.8733997155
TOTAL 5559.6579983845 5559.657998385

MIXER REAKTOR NETRALIZER

Masuk (kg/jam) Masuk (kg/jam)
Keluar (kg/jam) Keluar (kg/jam)
MF Katalis Keluar Reaktor Penetral
3125.0000 3125.0000 625.0000 625.0000
15.7035 15.7035 15.7035 15.7035
2331.0811 2331.0811 777.0270 777.0270
87.8734 87.8734 1.2755 393.2030 393.2030 435.1506
3750.0000 3750.0000
62.5000 62.5000 62.5000
401.6774

5559.6580 5623.4335 5623.4335 6460.2615

uk (kg/jam) Keluar (kg/jam)

Penetral Hasil Bawah Dekanter Produk

435.1506 886.2507 37.8788

401.6774
3750.0000
90.5612
886.8243
25.6384
677.1534 5677.1534
TRALIZER DECANTER EVAPORATOR
Keluar (kg/jam) Keluar (kg/jam)
Keluar (kg/jam) Masuk (kg/jam) Masuk (kg/jam)
Hasil Atas Hasil Bawah Hasil Atas Hasil Bawah

0.0000 0.0000 0.0000 0.0000 0.0000

777.0270 777.0270 777.0270 777.0270 777.0270
930.2105 930.2105 43.9599 886.2507 43.9599 6.0811 37.8788
3750.0000 3750.0000 3750.0000 3750.0000 3750.0000

90.5612 90.5612 90.5612

886.8243 886.8243 886.8243
25.6384 25.6384 25.6384
6460.2615 6460.2615 6460.2615 4570.9869 4570.9869
 PABRIK DIETYL PHTHALATE dari PHTHALIC ANHYDRIDE dan ETYL ALKOHOL
KAPASITAS PRODUKSI 30.000 TON/TH
H2SO4 62.500
H2O 1.2755
63.7755 EA= 777.027027027
H2O= 6.0810810811
783.1081081081
EA= 1554.05405405
H2O= 81.7923186344
1635.8464 Reaktor DEP= 3750
Mixer
1 atm PA= 3125 1 atm H2O= 43.9598689599
PA= 3125 MA= 15.703518 PA= 625.0000 EA= 777.027027027
MA= 15.7035 EA= 2331.0811 MA= 15.7035 4570.98690
Evaporator
3140.7035 H2O= 87.8734 EA= 777.0270 1 atm
5559.658 H2SO4= 62.5000
H2O= 393.2030
NaOH= 401.677444032 DEP= 3750.0000
H2O= 435.150564368 5623.4335
836.8280084 Netralizer Decanter Produk :
1 atm 1 atm DEP=
FF+RC 5559.6580 DEP= 3750 H2O=
Katalis+MF 5623.4335 H2O= 930.2105
RP+Netral 6460.2615 EA= 777.0270
UPL+HADec 6460.26152 Na2SO4= 90.5612 ke UPL
HAEvap+P 4570.9869 C8H4Na2O4= 886.8243 H20= 886.2506761258
C4H2Na2O4= 25.6384 Na2SO4= 90.5612244898
6460.2615 C4H2Na2O4= 25.6383960619
C8H4Na2O4= 886.8243243243
1889.2746210019
Evaporator
1 atm

3750
37.8788
3787.8788
NERACA MASSA
PABRIK DIETYL PHTHALATE dari PHTHALIC ANHYDRIDE dan 2-ETYL ALKOHOL KAPASITAS 25.000 TON/TH

Kapasitas produksi = 25000.0000 ton/tahun

= 25000.0000 ton/th x 1 th/330 hari x 1 hari/24 j x 1000 kg/ton
= 3156.5657 kg/j 14.2188
kemurnian produk 0.9900 C12H14O4 3125.0000
impuritis 0.0100 H20 31.5657
3156.5657
REAKTOR
reaksi yang terjadi

C8H4O3 + 2 C2H5OH C12H14O4

kmol/jam kg/jam
DEP Terbentuk = 14.0766 3125.0000
Etanol 20% berlebihan

komposisi bahan terbentuk / berx

kmol/jam kg/jam
DEP Terbentuk = 14.0766 3125
H2O terbentuk = 14.0766 253.3783783784
PA brx = 14.0766 2083.3333333333
EA brx = 28.1531531532 1295.0450450451

Komposisi Bahan Masuk Reaktor

kmol/jam kg/jam
PA masuk reaktor = 17.5957 2604.16667
MA masuk reaktor = 0.1335333128 13.08626
EA stci = 35.1914414414 1618.80631 EA recycle=
EA masuk reaktor = 42.2297297297 1942.56757 EA (FF)=
H2O dalam EA = 5.6800221274 102.24040 H2O impurities EA FF=
H2SO4 MR = 0.531462585 52.08333
H2O dalam H2SO4 = 0.0590513983 1.06293 H2O dari recycle (Asumsi 2% H2O
4686.194590
Komposisi Bahan Keluar
kmol/jam kg/jam
PA = 3.5191 520.8333
MA = 0.1335 13.0863
EA = 14.0765765766 647.5225
H2O = 18.2038 327.6691
H2SO4 = 0.531462585 52.0833
DEP = 14.0766 3125.0000
4686.1945904905
NETRALIZER
Reaksi: H2SO4 +2NaOH -----> Na2SO4
M 0.531462585 1.0629251701 0
R 0.531462585 1.0629251701 0.531462585
S 0 0 0.531462585
C6H4(CO)2O +2NaOH ----> C8H4Na2O4
M 3.5191441 7.0382882883 0
R 3.5191441 7.0382882883 3.5191441
S 0 0 3.5191441
Kebutuhan NaOH= 8.368280084 kmol/jam = 334.73120336
H2O (Impurities NaOH)= 20.1458594615 kmol/jam = 362.62547031
Neraca Massa Netralizer
Komponen BM Masuk kg/j Keluar
PA 148.0000 3.5191 520.8333333333 0
MA 98.0000 0.1335 13.0862646566 0.0000
DEP 222.000 14.0766 3125 14.0766
H2O 18.0000 38.3497 690.2946069514 43.0653
H2SO4 98.0000 0.531462585 52.0833333333 0
EA 46.000 14.0765765766 647.5225225225 14.076576577
NaOH 40.0000 8.368280084 334.7312033601 0
Na2SO4 142.0000 0 0 0.531462585
C8H4Na2O4 210.0000 0 0 3.5191441
C4H2Na2O4 160 0 0 0.1335
DECANTER 5383.5513
Komponen BM Masuk Decanter kg/j Densitas
MA 98.0000 0.0000 0 0.185
DEP 222.000 14.0766 3125 1.0578
H2O 18.0000 43.0653030132 775.1754542381 0.9757
EA 46.000 14.0766 647.5225225225 0.73262
Na2SO4 142.0000 0.5315 75.4676870748 2.4495
C8H4Na2O4 210.0000 3.5191 739.0202702703 2.34
C4H2Na2O4 160 0.1335333 21.3653300516 2.2
5383.5512641573
Hasil Atas Decanter
Asumsi H2O sebagai hasil atas decanter sebesar 2% H2O terbentuk di reaktor
Komponen BM kmol/jam kg/j Densitas
DEP 222.000 14.0766 3125 1.0578
EA 46.000 14.0766 647.5225225225 0.73262
H2O 18.0000 2.0352 36.6332241332 0.9757
3809.1557466558
Hasil Bawah Decanter
Komponen BM kmol/jam kg/j Densitas
H2O 18.0000 41.0301 738.5422301048 0.9757
Na2SO4 142.0000 0.5315 75.4676870748 2.4495
C8H4Na2O4 210.0000 3.5191 739.0202702703 2.34
C4H2Na2O4 160 0.1335333 21.3653300516
1574.3955175016
KELUAR DECANTER 5383.5512641573
EVAPORATOR
Bahan Masuk Evaporator
Komponen BM kmol/jam kg/j
DEP 222.000 14.0766 3125
EA 46.000 14.0766 647.5225225225
H2O 18.0000 2.0352 36.6332241332
3809.1557466558
Evaporator dijalankan pada suhu 120 C
TD Bahan MA 202 C Berdasarkan titik didih bahan maka komponen yang menja
DEP 295 C dan yang menjadi hasil bawah evaporator adalah DEP dan
EA 78.29 C
H2O 100 C
Hasil Atas Evaporator
Komponen BM kmol/jam kg/j
EA 46.000 14.0766 647.5225225225
H2O 18.0000 0.2815 5.0675675676
652.5900900901
Hasil Bawah Evaporator
Komponen BM kmol/jam kg/j
DEP 222.000 14.0766 3125
H2O 18.0000 1.7536 31.5656565657
3156.5656565657
KELUAR EVAPORATOR 3809.1557466558
MIXER
Komponen Masuk Mixer
Komponen BM kmol/jam kg/j
PA 148.0000 17.5957 2604.1666666667
MA 98.0000 0.1335333128 13.0862646566
EA 46.000 42.2297 1942.5675675676
H2O 18.0000 4.0682 73.2278330963
4633.0483319871
Komponen Keluar Mixer
Komponen BM kmol/jam kg/j
PA 148.0000 17.5957 2604.1666666667
MA 98.0000 0.1335333128 13.0862646566
EA 46.0000 42.2297297297 1942.5675675676
H2O 18.0000 4.0682129498 73.2278330963
4633.0483319871
ITAS 25.000 TON/TH
KOMPONEN BM
C8H4O3 148.0000
hari/24 j x 1000 kg/ton C2H5OH 46.000
C12H14O4 222.000
kg/jam 14.0766 kmol/jam H2SO4 98.0000
kg/jam 1.7536 kmol/jam NaOH 40.0000
Na2SO4 142.0000
H2O 18.0000
MA 98.0000
C8H4Na2O4 210.0000
+ H2O x= 0.8000

C8H4O3 + 2 C2H5OH C12H14O4 +

17.5957207 42.2297297 0
14.0766 28.1531532 14.0766
3.5191 14.0765766 14.0766

EA keluar reaktor= 14.0765765766 kmol/jam

EA masuk reaktor= 42.2297297297 kmol/jam

1942.56757
14.0765766 kmol/jam 647.522523 kg/jam
28.1531532 kmol/jam 1295.04505 kg/jam
O impurities EA FF= 68.1602655 kg/jam 3.78668142 kmol/jam

O dari recycle (Asumsi 2% H2O terbentuk )= 0.28153153 kmol/jam 5.0675675676 kg/jam

+2H2O C4H2O3 + 2NaOH ---> C4H2Na2O4

0 M 0.1335 0.2670666256 0
1.0629251701 R 0.1335 0.2670666256 0.1335
1.0629251701 S 0 0 0.1335
+H2O
0
3.5191441
3.5191441441
kg/jam
kg/jam

kg/j
 0
0
3125
775.17545424
0
647.52252252
0
75.467687075
739.02027027
21.365330052
5383.5512642
Data Kelarutan Bahan
MA bereaksi menjadi maleic acid
DEP 1g/100mL
H2O tercampur dengan etanol
EA tercampur dengan air
Na2SO4 13,9g/100mL
C8H4Na2O sedikit larut dalam air

volume
2954.2446587
883.84499812
37.54558177
3875.6352386 densitas rata-rata= 0.98284681

volume
756.9357693
30.809425219
315.82062832
1103.5658228 densitas rata-rata= 1.42664396

han maka komponen yang menjadi hasil atas evaporator adalah EA dan H2O
wah evaporator adalah DEP dan MA
Tabel Neraca Massa Total
MIXER
Komponen Masuk (kg/jam)
FF RC
PA 2604.166666667
MA 13.0862646566
EA 1295.045045045 647.5225225225
H2O 68.1602655287 5.0675675676
DEP
H2SO4
NaOH
Na2SO4
C8H4Na2O4
C4H2Na2O4
TOTAL 4633.0483319871
Neraca Massa Overall
Masuk (kg/jam)
Komponen
FF Katalis
PA 2604.166666667
MA 13.0862646566
EA 1295.045045045
H2O 68.1602655287 1.06293
H2SO4 52.08333
NaOH
DEP
Na2SO4
C8H4Na2O4
C4H2Na2O4
TOTAL 4730.9611740672
Kemurnian Bahan Baku
PA 99.50%
EA 95%
H2SO4 98%
NaOH 48%

H2O x= 0.8000
0.2815315315
14.0766
14.3581

647.5225225225
1942.5675675676

Tabel Neraca Massa Reaktor

Masuk (kg/jam)
Komponen Keluar (kg/jam)
MF Katalis
PA 2604.16667 520.8333
MA 13.08626 13.0863
EA 1942.56757 647.5225
H2SO4 52.08333 52.0833
H2O 73.22783 1.06293 327.6691
DEP 3125.0000
TOTAL 4686.1946 4686.1946

+ H2O
0
0.1335
0.1335

Tabel Neraca Massa Netralizer

Masuk (kg/jam)
Komponen Keluar (kg/jam)
Keluar Reaktor Penetral
PA 520.8333
MA 13.0863 0
DEP 3125.0000 3125
H2O 327.6691 362.62547 775.1754542381
H2SO4 52.0833
EA 647.5225 647.5225225225
NaOH 334.731203
Na2SO4 75.4676870748
C8H4Na2O4 739.0202702703
C4H2Na2O4 21.3653300516
TOTAL 5383.5513 5383.551264157

Tabel Neraca Massa Dekanter

Keluar (kg/jam)
Komponen Masuk (kg/jam)
Hasil Atas Hasil Bawah
C4H2Na2O4 21.3653300516 0 21.3653300516
DEP 3125 3125
H2O 775.1754542381 36.6332241 738.5422301048
EA 647.5225225225 647.522523
Na2SO4 75.4676870748 75.4676870748
C8H4Na2O4 739.0202702703 739.0202702703
TOTAL 5383.5512641573 5383.5512641573

Tabel Neraca Massa Evaporator

Keluar (kg/jam)
Komponen Masuk (kg/jam)
Hasil Atas Hasil Bawah

DEP 3125 3125

EA 647.5225225225 647.522523
 H2O 36.6332241332 5.06756757 31.5656565657
TOTAL 3809.1557466558 3809.1557466558

Tabel Neraca Massa Mixer

Masuk (kg/jam)
Komponen Keluar (kg/jam)
FF RC
PA 2604.1666666667 2604.166666667
MA 13.0862646566 13.0862646566
EA 1295.0450450451 647.522523 1942.567567568
H2O 68.1602655287 5.06756757 73.2278330963
TOTAL 4633.0483319871 4633.048331987

MIXER REAKTOR NETRALIZER

Masuk (kg/jam) Masuk (kg/jam)
Keluar (kg/jam) Keluar (kg/jam)
MF Katalis Keluar Reaktor Penetral
2604.1666666667 2604.16667 520.8333 520.8333
13.0862646566 13.08626 13.0863 13.0863
1942.5675675676 1942.56757 647.5225 647.5225
73.2278330963 73.22783 1.06293 327.6691 327.6691 362.625470307
3125.0000 3125.0000
52.08333 52.0833 52.0833
334.73120336

4633.0483319871 4686.1946 4686.1946 5383.5513

uk (kg/jam) Keluar (kg/jam)

Penetral Hasil Bawah Dekanter Produk

362.6254703067 738.5422301048 31.5656566

334.7312033601
3125
75.4676870748
739.0202702703
21.3653300516
9611740672 4730.9611740672
TRALIZER DECANTER EVAPORATOR
Keluar (kg/jam) Keluar (kg/jam)
Keluar (kg/jam) Masuk (kg/jam) Masuk (kg/jam)
Hasil Atas Hasil Bawah Hasil Atas Hasil Bawah

0 0 0 0 0
647.5225225225 647.5225225225 647.52252 647.5225225225 647.52252
775.1754542381 775.1754542381 36.633224 738.542230105 36.6332241332 5.0675676 31.565656566
3125 3125 3125 3125 3125

75.4676870748 75.4676870748 75.4676870748

739.0202702703 739.0202702703 739.02027027
21.3653300516 21.3653300516 21.3653300516
5383.5513 5383.5512641573 5383.5512641573 3809.155746656 3809.15575