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5 Sifat-Sifat Fisik KIMIA LIPIDA-2 PDF
5 Sifat-Sifat Fisik KIMIA LIPIDA-2 PDF
5 Sifat-Sifat Fisik KIMIA LIPIDA-2 PDF
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Temperature
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COfi.1PAMiSON ua FO~McS POL~MOP-ff/IQUES .pc.J B.EUR.IlJ; PC CACAO
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Af"ES/.. VA-CCI<. e.f WIL.l..E ~ 1-UTrON
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-
· Figure-3. S~.:Mma des Possibilit6s . de Transformation cristallines
. du Beurrf' de Ca(·no<87)
...·
....
I
Tablt>au-3. Classification des formes cristallines du beurre de cacao
ct ses poiL.J de fusions (0 C)(S_o).
-·-
Form y y y i I a '· {f2 I VI I 1
MP 18.0 J 1.0 18.0 17.3 13.0 17.9 17.60
For1 a a a a f.. II {fl II v II II
., ·MP 23.5 21-2...0 23.5 23.3. ..;. 20.0 2.C •.C 19.9
Form P" If fJ' ~ Ill {f2 mix or m· IV u. Ill
a&/f
MP 28.0 28.0 28.0 25.5 23.0 27.7 24.5
Form fJ fJ fJ fJ' 1 IV pre fJ If IV Ill IV IV ·
MP .3.4.5 3.C-35.0' 33.0 £4 27.3 34.6 25.G 2S.O 28.1 27.90
Form fJ \' fJ fJ v u v v
MP 3-c.O 33.8 36.2 30.8 30.0 33.0 34.4
{t
Form
MP
VI
36.3
'.
32.2
f
33.5
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3.C.G
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. U,':f-9 ..· .tctS1 291Si U/ 181 tBO, ri
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A 8 c
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Figure-6. Thennogrammcs de· fusion de b~rre de cacao stockcs sous
differentcis conditions d'oxydation (A), diffcrente·s du.rce d'o~ydation ·.. expose a
lumi~re et a temperature tuitbhintc (B) ·ct a·· 90 oc a l'obscurite (C).
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TEMPERATURES DE MESURE (OC)
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TEMPERATURES DE MESURE (0 C)
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<~
':'IHYDROL YSIS I
. i
jsoLUBIUZATION] .··:... tree fatty acids
t .: : diglycerides
; hydroperoxidos Jorod compounds · · glycerine
(conjugated diaries)·------ food lip1 mori~lycerides
. I .
. , FISSION I DEHYDRATION IFREE RA~ICALS I
.J
l dimors;
alcohols ·· ketones trimers
cpoxides
... ~ .. alcohols
hydrocarbons
-'-- dimers
cyclic compounds
I
(
.....·
. ·......
... ~
l---"=-r ~\:-·\-~.~f'
RH
A
RH
R-R .i INITOATION
R•
ROO·
PROPAGATION
AH
TERMINATION
ROOH
R"CHR' - R"CHR'+OH'
If
0 ·OH I~
0' RO
/
/'/ 1 Rll
R" R"CR' + ROH
II td/.::,
. . 0
R"CHO + R' R"CHR' + R J...tfon
I
~/d... OH R"CR~+ RH
II
0
J...t:.for'
I Olea1e
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g
02
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-H/
.J<" 'Z /02
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I
02
\
02
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HOO\-.... ll, 11 'L-/OOH
_/'0~ ~-~ • ~ _// i"\..__
- HOO/ OOH
8- + 10-00H g.+ 11-ooH
ll ll
r=v=='\
___ ..) ~-~......'\..Uf.'· b
13-00H 9-00H
linolenat~
15 u ~
Oz Oz
\ I a
~
. '·'
It H· I+II•
HOO f l DOH
~
Hi-DOH
~a<
9-00H
DOH HOD .
~ ~
12-00H 13-00H
·.·.:·
OOH
J-2H·
0-0
t isomers
0
0
H
FJG. of
don M~hanian of 1,3-cyclization
$. m.Ionaldehyde (61). · of 12- and 13-hydropcroxides of linolenatc and forma-
Autoxidized Linolenata
o-o 001-1
~--0--( A
~~~ -0-ZOHC
... :
Sensitized Phorooxidized linolenare
A + HOO 0-0 HOO 0-0 0-0
t
D
E
OOH
FIG. 6. Structures of hydroperoxy "ycHc peroxldes.
.....
.,
LmoiU~o..f . .. >pi- ~A .,
' .9-00/-f 1ot /'l.t J!
.,...... · ·11•V
~~
~
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~-·-···
•
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lA
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perotsrd..o. £ik
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• IB 7.A,
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)tf 9C. ftc. IY t
. 1\ oo·
.r · pero~sr# sl~
0 Oft 9t ll.t Nt. oo• ~~
rryL.:.-w-=/ } !3 - OOH 9t' Ht
• _ .,..t ..J..._ ~~Pn . ; -· ............
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- CH(OOI;
I
1-/+-. E -. Ft.
l-f
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·f"e%.-I - 0
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OL:J~l-c(·
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p-entaf\a.
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2.t ~-
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&m-1-oh hebefO-/'-A r,r;_l\yOMJa.at-1 r.a.sl/ ok._~icla.s/
lmo/-etti- dtrtgafA. ~
0 OH
~ ~
ok. sod t'e/'0.. H ldro l<t>iai'eM ·
OH oH
~
X'( f~-:>r- e•. .c{:c \ --=t ~: r·--. ·~,. ·f
~
t·l,_. A ·--::.
l,
_oH OH o oH.
-~>=./
6'
~0
~OH
(7>..- k.fJo/ f- k.f.fo( /C.efo d lo( .
oH Of-f OH Of-f
~ ~ ~
0\-\
\'
oH
d.- dro( ~'- dlol c;- dio/.
oH OH
~OH
H3C(CHt~o~.
, [Cffz..), C.O()H
li
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...
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Mtrs·P-Asi II<ATAN R.ANGKAP ; .J'Ik.LISASf' . ~ VtfVl£Rt'sAS f •
· .oJc.sidas {.. pd.. ~fW' tt~2!, el..p-{-. rn.t.nyeb abk.aV? · 'k!r]'"'-~lV\ Y<
rnlq~~( .. :.tk.+ ~p. AAVI peL a~. pofte.nt;... bt.>a. "'U'-b e11tuk. .sutvt
·sert'{etUJiAa.tA !lk.t/'fc.- Senyawa.a.."' Stkfik. -tsb blsa.. b€1"UptA. J'tSJ
>tkfohllk:~ctt'IQ. J sr'k..foh ~e.no... ) slk.(oh£ksac(i'eno... ; b~n -t.ena ·1 1ncU'J
~ md~n yrAM!j dt.fl!j cu, mu~ah dttpa.t aA.'pr'so.l11~VJ d!M-1'
stn'(»..V~l CJ.$i'ldik. seceu'D. K.rls+ctlt'sas{ e0 Uf'e(i\ •
8
- C:Hcf{.=: CffCH === CH- -~
~
-·Cffz.Cfl = CHCH 1:
·'
c. c
t
r-J~
11:::. Ct(CHz._CH = Gf( - --~ - Of~CHCI-fCH = CH-
ic_;
e c t
· - Cl-f = C/-fCJ-f =- CI-t €.1{ - -7. - CH= CHCI:f =- C
--r··......
-'r
ce --) a:~ aR' ll...
R..' dan
. ' R.
.
A9Ct'2.C /r"C
~-
-~~-·--! 'It~
'V'
.
49 ( {(I IS
I
~
1 de
£\ 9 1 I?, tlf:
It' fl..'
..
P.. = Ef , 12.. 1 =. (C.H~.)f. CDOI-f o.to.u
e
R.. -= H~O ( 0-/~)b 1 R) -:::. €f
0
Skf.IY\9-- r-.w. pet'r1 bo\h.-t.l:.o.J/1 T'tlonosildik.
'<U1 ko;fctfis cla. y· f"ra.{<.s rIJYi 01;; pro tA.tt.k , pc 11;, erfsa.s i f! k> 1>1ttjc
~ .
~noi>\.Qr ; cl1rner c;{avt -f-rtfV)ef" dpf r:lt1akukav, d.!} dt'sfi'lasr'.
D1rner Wflenfuk.. b€f'.d.a.!C1.1'/<.ClCIJ smfr.So... Diets Afder a11ta~
W~u.8as( hasr'( -lrau.sfer fu~ e11_ ~
1..
fY\(}Yl))ert.r;.
C~rrtoA
"!J
cltmeri'sa.s(
suct/u. cUertet
d.l.~c;r,~AA..btxt'/~itt peL siG.rn..a.- .r~11. 9 '
--·)J.
~I CHL CH {l..7.-
/
{l} c = Cf/ {1.. 1..
o.slk.hk. ct,,..,,ef.
... ·.
...
i ;: ;; ... :, clrrrJtr. . '
... :
. . • ! !" • :
: ,· o·
~
,. ~
't'•
. _2 •.C,7~Dcatrien 11 +Me octanoate
't'
.
I
I
I
3-Hcxcnal + Me 12-oxo-9-dodcceno~tc
.
ACIDE ISOMERIQUE %FORMATION PRODUITS DE~O~IPOSffiON
~ . ..
GRAS D'HYDROPER- Auto- Photo- : Aldeliydes/ AlciJols . Hydroc.arbures
OXYDE Ox. Ox. Ceions
•.
. .
Ol~ique 8-00H; A9
--~·.·.!
" l
i
I.
;.
!
n·
!! · Alcooi refroidi
I
!.
1-
l
I
l.
l
I ..
..... .
I
.~;
I Microdistillateur
.B
·Ba.in-marie
A
· Echantillon
I
I
I·
I
I
I
de vapeur d'eau
I
[
!''
I
! Chauffe-ba1Ion
···:
· Figure 3 Couplage entrainement a Ia vancur-mil"rl'\rH.-f:n~·----
:.. -.-:;,;:::_
-·-·-·-- ... _,_~--- ... - ..
""'"···
Figure-4. Chromatogrammcs des produil.:; volatils isol6s du beurrc de. cacao noz, .
raffincS (A), raffincS (B) et :1prcs. I'oxydation pendant 12 semaincs ~- 90°C ct ?t
I'obscuritcS. Lanum~rat:on- des. pies du c"'lromatogrammc C "st · dificSrcntc de· ccllc
des chromatogrammcs I\ ct. B (voir tub! ... :u-2~c~·~.~ta~b~Ic~a~u~-3~)~.- - - - - - - - - - - - - - - - - - -
. ·.·. -·
~}
. 22
·'4.. .
2
.....
'9.4 :.
3
:0.' ~ . . 0
109:"'.
'•.
5
s·
4
25
2o9·
:Jig'··..
·~
·ii.
29.: .'
39.):
t.Q·.
5
.i6
5.
;/(;.;.:·
ql
·,.
'14.1!
t8).:
41 .
{o:·
2(5~:
..• Y
·'9'.
4. . i.
'. ....
4. ~
~~ i
5:
io·
·at
A6~ .
;
24·
·g~l ::
4
3~n.
,()<
'. -~ '··.!~.., .. o 'I I , . _ , ,..,. • '" , .. ,ooo • oo I '•,. •,' ,'
.. •• :;.,~-
,J.·• ~-·-
.
:
-
... .,.
.
:
o,,
.
• •:
"-~·
'j
•
i''""'~····
. ·•. ' .
,
.... .,..(.
. . ~
•••• -
j{'~J-!,~1.,.>\.,_
I'! 0.
'
~
I
• • : ~ 1 •· ... : . ili<P.IImP ..
......... ~~-···t'···)'
.. 1 •IL • I
.'
1.· .z·
.2 1
1 .tr
3 . 1 .
a~ .. ·tr
2'· 1
r .fi'
2
1 tr
3 t;
2
1
:tr
1·
t
2 ·.tr.
3· 1
3- tr
.1 tr
i15· 1
5 . : ·tr ..
.Tr :tt
'•
. ....·.
1
tt
1
1 .fr ..
;tr.
l-
,.l
·~·
., .
0
tr
tr.
i :.. .:
- . ·:
- :. ·.
.,
) 7
.,. 8
I
~
;.J"
t
t.J~
4i"
~
N
I
~'
~
U)
.. -1
'-"
z.
~
v
0
0
(l)
-
G
\.)
~ ~"t
~ ~ (]'
~ lJJ
~
S> --IIC:II!:--5
-
\'l
-tD
~
:-.!
•
!,r,
::J
{,)·
tl1
-~ ::J ro 0'
.._J 0
::J
£:4
0
cl..
Q (;;,'
~.,.'j
'
---·--..---..------
----·--· --~---·-.. -~· ____ ,._ -~ ·- ---··-- ~-- ..,. ___ _
....... 0
'~J
·---~·-,__ .....,..,~i*''-~.-;,.~~~~1tlXI
I
H
:···i
-I
El\~rf<AI<S! ~~Pr1RA.SJ
"'1
.......
9< LIPID
~
J
l
Il rl.. e~<.srAAtc>r L/(JJ/).
~
'i ;I
..
~
be"' ~I<
II .
lkf tco{/(l.fe!2_
a'7 sfru.k fur.
o.:f-o.J.J. a~. he.rc a.ban_j •
_,.
pofr'l at<a.rlAA
ufer 1
A.r
«tnida..
a.s. fWJa!:.
1
a:fa.u ·"JIIf;cst'd.A.
1
ai. h t'dl'rJJ::. si
_, llpo;otc'safc.arl~ & cJ.incltn!j .te.l ba.k.!--er-t'.
I
I
Nrm po{o..r
(;;: ~ ....:
it:;/a.f' ,'
~· fall:..af/
w·, C!.! ctJ , b-e_() ~&t.a..
efano/ ) mefayzo/ HC/ KOH
l
1
L l
Jk..f llaH JJ;. Wa./r;.
lk.+
I~
I
.. , --:·····-~~-~ .
l
j.
·~
1
I
l
.~ .. 1·.
1
t
J.
I ·'
Aktifasi dengan asan-. borat · atau · natrium · bor~t.. dapat memperbaiki
..
!
"' I
..·.. j>"emisa:Jan
. . . . ), . DG (d'IgIi sen'd a) dan TG(S-8
AT.., MG. (mono glisenda · •38-40)• •
Ii.. ·M.etoda ini banyak digWiakan dalam analisis hasil hidrolisa TG, terutama sec~~
euzimatik.
Is
i·
I I '
- - - · - 0
' 0
l' ~
~
0
I C)
"C
a0 <c: =·g CJ
l - ··-, -·· ............ - ~ ~
g
:a M· 0
u u
I
FPH :0
:2 ~
:3
0
l d: J: tt .
~
:I:
I·
!
I AL J.ENUH
· MONOENA TRANS
~&~~~~~~~~r.i-~~-......,_'~~1 1 ~.ss
I SES
.
I.
I
I
MONOENA CIS ~~·f~f-t~~i~?j~~l~~~~~~~~~~t~ sos
I
SSO·
I
J
ss.:.
sso
··:·. 000
·-·:
. (A)
(B),
. .
Gambar-8. T.LC-AgN03 dari pan1oleiv '.'G'P) dan palomei.. terhidrogenasi
(FP.I:I). :A) TLC metil ester asam Iemal'"Ya dan (B) T:LC fraksi
triglkeridik FPHnya de:ngan pembanding campuran TG (St,St,St;
St,St,O, dan OO(l) ~e.r:ta lemakcoklat. }rasa gerak Toluen : Reksan {il:2)
·~.rt~.pcwarnaan deng,•n diklor0.:2',7'-!luorcscin dan di•mati p•~~ 366 (.,; -J)
'-
I.
17
.. o:··:>.<">--,:-.,;;'<"'~~;"~~.£i;l!i!m!\,·"J{.;
I
L 'ENt;EIJIBLE l>l: LA- ME.IHODOL06-!E D1 ANALYSE
to:'
DES MATIERES <7MSS£S tiYDROfi'EN£:5
mtion de _;})J_ ~
·(~,::;·t:l
I
.JL__)
I
\rictions .
1 J-
...._
.f --- Mono~neo
(TENEUR EN Cl8: 1
cia
TRAN~
T~,LAT<~ . Ozonolyse ~
ll
j J
l ~ h
j1
~•• "A t~
lUJ
CPG
A A I
CCM Silice+AgN0 3
lJJ
CPG
J__L_j_~.
POSITION DE LA DOUBLE LIAISON
DES ACIOE:S !.'18:1 CIS ET TRANS
( ANALYSE TRIGLYCERIDIQUE )
...
I •rl
1 .,...;::.~·.,.-
r
01 l
1·-· . .
··'"'.
Aktifasi <!engan asalT_ bo.rat atau natrium borat d~pat mempe·:..-. :•iki
pem.is.i.~an A 1_;, :"viG (mono gliserida), DG (digliseridu) dan TG(S- 8•38-40).
Metoda ini banyak digunakan dalam analisis hasil hidrolisa TG, tcmtama secra
cnzimatik.
!-
I
0
0 Cll
0
E-<
u u Pl (.)
-o
0
0
""0-
< Q c::
t;.Q" t:l 0 0
~ l:
0
".::1 u... u ~
e:
0
FP FPH ~
::a ~
=='
0
u..e
~
~
.. tE
ALJENUH sss
MONOENA TRANS SES
MONOENA CIS sos
sso
SSL.
sso
000
(A) (B)
17
I•
(A)
r
0
!C
~
!lJ
:r:
ct
::::
::u
fD
d-
fD
:s
lfl
IJ•
r (B) m
·=·
liJ
~
!lJ
:r:
c1"
::::
:::u
fD I J
L_~llv-
c1"
Ill
:s
L'l-
1-'•
1
14 !7 18' 19 20
10
··"".
ll
I
T~b!Ji~3~·Wfiil~i ~~ktii" retenii meffi:~fer aiii'iid~Ynak; pa"di ·
l
I
' . b.efb'a.~~ft~p~ ·(a:~a citir. k~~~~ ;~~~~~?'~q,_ou{~)·;~()~r(lO)~· ·..
l
I
Fasil Cair d~ Reiatlfwa!du rd~iisi mdil ester
!···
I
I Kondtsi yaiig (ligunakan 18:0 18:1 lt:2 18:3 20:0
lI
II 10°/o fasa, zooot
SP-~330 (50% fe,nl, 50o/. sianopropil) l,tro 1, tr ·},90
l SP-2310 (25% fehii, 75% sianopropil) 1,00 1.12
1,32:
1.?4
1;62
1,64 1,82
I SP-2330 (10% feiill, 90% sianopropil) ·1,00 1.15 1, t.-;. 1,82 1,71
I SP-2330 (lOb% siab.opropil) 1,00 1.18 1,49 1,91 1,66
Catatari-": dianggap bahwa waktu rctt.ns• relatifmetil ester st".ara'.: ~:18:0) c>c;.h'"l 1,00.
G~ ..,.. .:.)
0 0 (Jl . ~
0 (D J (D (D ,.,
'
0T _._-'----b_,... -~.···==-··.--1. ~ =--..~~-· :·:'=··_....;,.....~-QJ~=~·~--~-~~-~· ~QJ~. ; __; :~::;:;;_~_;'3-~-::.~.-'.j) L-~0t4f1W
'- I ,.--·-----· ;::;:=;;;;'
..
I f
I I
·I ! •
1 j".l3GG
i,
; I.-, "r(j I
I"' I._, ·'I
l
·- ·: :·... ==-~====-=-----15.67~1
C.JJ.4Iill ·- _'/; ;)i! ; 19.010
:.•"-• IL.J I
ro!
... ' I
}
ll.f
...
_.
_;
oJ
V' j'
l
.......... ·- - -·· .. '·.~ ·:'v'oe t.Vidth Ref// .-. ·...
-. .. :.:__I .• ,. ·····-1--- . _.. ____ _
~~. ~ ~: ~- ·;; ·· ·)t ;. v..!:1d *1 • .•
lt •:-~c;, :_;1:
·~ .. ..::1d * ...;6 .
·:a
X :·
fount::'
i:. ·• ~.:; ti .:· . :
.· ~ - C10
1·"..... 'l
• I ,J
'J. 695
.!..77 1
1
~- ... "J':J7 c:.. c;. 2
1',,}10 '"':~J
; .
0
C1a:·r trans C16
C18
C18:1 cis
... :
"' C14
_ ___,. . . . . _
_j '- - '-
Esters methyfiques des ~~i_de~~~~ __ to~~~~
C16
B
C18:1 trans
C18
_j '- -
. C]4 -;L
'
Esters methyliques des acides gras saturcs et mono~nes ~an~
c C18:1 cis )
I
I.
i f-"igure-5. Chromato:::-ammcs des esters mcthyliques des acides gras de FPH
i
! totaux (A). Ir.Onoin.s;Iturcs trans (B) ct monoinsatur~s cis (C).
i ...
I
I
I!
!
... :
I AC!DES GRAS
I QUANTITE (%)
.. FP FPH
C12: 0 0,5
.
C14: 0 1,4 1.1
trans 50.4
-
c (Q; 2 13,8 .0.3
·-
I . Quantitc (%)
EM EM Position double
(mono acid<') (di · acidc) liaison CIS: 1 trans CIS : 1 c:s
Ei«L2 A .0 0 o
qc -g;R
ca.
'...
.i"~"
'i"
CtO~
... :
'.
·.:· .:·
CIS CIO
..
E2tGt2 ill~(li1H'tffi1~d1Cfuc#p~llfdWbqq>ePI15\.J6~!hr~ctt,QifGH6yi\Je.sqc2°t~C!EiG~Gg~ {orsmc qG. 1:1)
,....
- -
~
- [Y l
:J '
I
~ .
' .
.
..
... I
C"
( ~
·l
c"
N
·~
\" .I .I
.I
· .~ !
C><l c.o
- .
'
L ..
ca ~ c•
' •'--"
..:j':l. ..\•')t;
Cj"i\.itS ,.
!. l..
WC"HD ~Al.;r~
c••
.
. ca~
. ~..,. A..,l· . -
. co Q1C">'
.. --~- . .J .
. . ·: . ;;:·. ~.
quh~f fl!wwn?.f-ijHIJ·:ifq!\1twn~J(!m z~prrri;! : · · · ...--/--- ___
:An!!n J.C J.m1R 1.~!tHh.r.e{·1-.bt.UCktG\Ml~-m~:,~c~~n~!;;m~f'~1t~~~ ~'Nl1p\iry i,:ms <!~m.1:1 <rrn
J!UCJC'f-c IfG\!-!if-~jbqc~~tPJP-fh. i.~t~Jf!~~2P~Rffr-~~~IYJ! ·~iiji?.~1iq'.~ll.~.·o-H:c~~ ~~~u ..
(!{cAc1!.'20 b1frr?.~~-liB'-'btk'Clfbi~~"€~~.oliP-&ftr.~bn~- ~N'lt&!~M1Wp~~9}H~!~rm~vpu :~q~Ji:rp _
i
\·
'
j
.·•
··-······ ··-·-
··~· . •''!/•
.-
,; '
.
- -fll;., .
(:[C.
I .I
I . ·L-.. -·
I
I_
I :
~~:;~~----~~----------------------~----~~~·l~~-
ift..
~~«;
il
'1"' ..
I T"CN • ; . '
i ~~-'f~
"'''
'/1-,3 i
'N,·f -- I
C/"1};" ' . ' . . )_'.~ "-_,~-:~'· t~>~--~~:-i1
II ':i·
1-IPLe • _..,
I ECN. ..- (N - ..t-4-
.£CN .:: -c.,u7 vq/en Cnt~ ~
Il .. . d =- (J:.J- rk.p •
i J
;
TOJ = . ECI{ - l l!;
Tcf\1: iltt.N'+,"CAJ C, N . ,
I
..
Ui ~ .fa.K/iJr .vcf.!G{?':~~~{~~~b
6.: OJ(, ;,· ;
E.: o, L . l
L .:. O,"f ..
~a,r ... 0
F'Oo
?LO
CN
... . . ,
a:~
f
I
I· ..
i
I
I
,.I·
l
!·
'
1
i'
'
'Fableau-4. R6sultats de.· J'analyse.- CLHP et CPG de fractions A. B. C et
• de. J~ fr:K"tion de palmc hydrogen6c (FPH) •
.
FRACTION INTERVAL~I;
cuw NOMBREDE
-
.
Ncr QUANT.ITE
CARBONE (NC)
46 I. I
A 44.0 - 46.8 48 0.3
, 50 1.9 11.9
52 5.5
54 3. I
48 0.6
B 50
47,0 - 48,5 11.1
52
70.3 -·
49,3
54 9.3
50 3,8
c 49,0 - 50.0
52 8.9 16,5
54 3,8
-
D .:..__
51.2 - 54.0 52 - 54
I .3
-
(
-- \
DETEP...lVI!N/t-TION r>E LA FRACTION C
I
I
B
II '
I '
NCT
I
f
49t0 -f:OtO
I f
I
HPLC.
I I
I
I
I
II ......
I NC.
I
I
I
!
I
!
CFG--TG-
. ...' ·
&LYCER..IDE~ ''\
N.C. NCT CRUANTITE
j· ··~ . fp
/.1Sf
r'f
r . 50 50 .6,8 ~ 3,4'
so 6"0 fr..
PO Sf 52. llfJ, :z. j , 3,/
PE Sf 52. 'la,R f1,.9 < 5,&
(
\
.•
... ,r;
. I
I I
'I I
,_, ..
.I
·,•
8
c. .·.
' I
··:·
I.
I I,
••••
~· ·.
I§ I
..
..
.I.
,
:~ .......
;;;,~ :
~.,...-
.,~ .
.
.-· ·- 1 , II
..:
i - - ..... I :
.I
I' I
I ·''
n I
·' ....
• I
... ,·..
j I
.,. '
.......-l···
. .,
'I
....Fraeuon A Fraction C
.
:.· ·.:/.·~:./',:A~ ··:.,I ···.I:. I,.\',·. ~····. ~.... : 1
• SO·
~ .":".;·;:··:~:·.~: 7 ~L-"-
~~.·
· ·~ i<romato~a·m
.· . ·· ..·
utLC prepiraitif Bidr.ogcnasi
~..1~-·--·-- ... ~ . . __..:,.. ---
?almolein
. . ...
·. • • ·-\ • -· ~ I . F.taetioo s
., m
. ,\ s :··
IJ' . ~I~·~·
:( . . 1· ·• I
•o
z N
on.
I 0
II)
~ .g I
:·.•. ·r r
ww
wg·..·c.o~ :::S:l:
wg
w w
QJ •-
.§. . wtuc.
0
.....c.::!:: ~
~ '-''
.a..gig
. .. .....
ll.·
UJ. .~·
Q.<ll
a. "'.
w
.(I)
(I)
+
n.
0
c. c.
a.
+
a...
.
CL
-~
..
:i·
(I)
CL a.
c.
.. ' . GC dari frabf A, B dan C.
..
Gambar-7. Krom~.togram HPLC dari Palolein (I),'Pimotcin
terhidrogenasi (ll) '1~tn kr~matogram GC dari faksi A, B dan C dari
palolein terh.idrogena.t?~ .-. __ .
.,
., I'
.I
,I
'.. ' I· 16
- ---··-·· ... ·----------·-··-.-.-.-~~..,
·""
I
I Tableau 4 : Composition triglyceridiquc des fractions de palmc non
l ..
,
.. -.
hydrogene (FP) ct hydrogcne (FPH)
..· . Ot:JANTITE
..f.···· ...
FP FPH
1G l'C NCE Ncr (%)
% Fraction
..
QL S4 44 40,8 0,6
R.L Sl 44 4.1,6 4,5
·.
MD so 44 . 42,0 0,8
ao 54 46 43,3 1,8
11,7 0.9
R.O 'l 46 ~4.0
RE S:! 46 44,6 - -
PlP so 46 44,8 8,9
POSt ~
~
2
2
so
50
49.2
49.8
1,9
-
3.1
5.8
c
I'C:St
- 0,1
StPP .so so 50.0 3.11
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Insapcmifia&fu O)(]llles. paoe 137·. :''
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Tableau- !a. TENEUR EN STEROLS DU BEURRE 1)p CI~CAO
-
AUTEUR . TENEUR ( % w/w ) '
chole campe stigma· 13- AS-avena A7~stigma
st6rol s16rol st6rol sitost6rol sterol st6rol
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Tableau-lb. TENEUR EN TOCOPHEROLS DU BEURRE DE CACAO
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Gertz ct Hermann 3.9 - 15.6 0 -11,2 ° 73,2 - 96,1
(1980),(20)
Lcccrf (1990).(6) 21 389 7
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~--------------~----------------------~---------------~--~
AtfrEUR TENEUR ( 9f, w/w)
cholc campc stigina· P- t.S-avcna A7i.stigma
sr6rol
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Sltrol rtdrol dtost.Srol sicrol si6rol
..
Chavcron (1967),(2) dgnale 9 24 67
Itob ci ai (1973),(15) 2 9•1 26;3 59,6 3
Braco et al (1976),(16) 1,3 - 1,8 3,8 • ,10,5 · 23,7 • 29,S 58,5 -64,9
-Lerckcr ct .al 1.9 9.4 . 26.1 59.5 J.S 0,4
(1981),(17) .
Lecerr {1990},(6) o;6 • t.3 g,g •.10.6 24,5 ~ 29~3 58;9 • 59,5 o.6 • 2,1
. . ··:~
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AUTEUR TENEUR EN ppm ..
a.- ·~· r- 5-.
Tocoph~rol Tocoph6rol TQ,coph6tol TocopMrol
.·....
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Feeter (1974},(18) ~.~ - 11,1 2S,8 . 107 7
Mullcr.-Mullot · (1976),(19) 18,$ ,_. 3,9 196 14
Gertz ct Hormann 3.9 . 15.6 0 -11,2 73,2 . 96,1
..
(1980),(20)
Lccorf (1990),(6) 21 ~89 7
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