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354.1 364.1 374.1 crítico:
T = 354,1 K T = 364,1 K T = 374,1 K
65.43 67.27 69.12 Tc /K Pc /MPa a3 a2 a1 a0
64.00 65.81 67.62 324.1 7.3773 ### ### 0.00E+00 0.00E+00
62.64 64.41 66.18
61.34 63.07 64.80
60.08 61.78 63.48 Cree datos para trazar la presión de vapor saturado a temperaturas seleccionada
58.88 60.55 62.21
57.73 59.36 60.99 Etiqueta T /K P /MPa P /MPa V /cm3 mol−1 V /cm3 mol−1
56.62 58.22 59.82 P⁰ at 273,1 K 273.1 #N/A #N/A 0 600
55.55 57.12 58.69 P⁰ at 284 K 284 #N/A #N/A 0 600
54.52 56.06 57.60 P⁰ at 294,4 K 294.4 #N/A #N/A 0 600
53.53 55.04 56.55 P⁰ at 304,1.0 K 304.1 #N/A #N/A 0 600
52.57 54.06 55.54 P⁰ at 314,1 K 314.1 #N/A #N/A 0 600
51.65 53.11 54.57 P⁰c at 324,1 K 324.1 #N/A #N/A 0 600
50.76 52.19 53.63
49.90 51.31 52.72
49.07 50.45 51.84
48.26 49.63 50.99
47.49 48.83 50.17
46.73 48.05 49.37
46.00 47.30 48.60
45.29 46.57 47.85
44.61 45.87 47.13
43.94 45.18 46.42
43.30 44.52 45.74
42.67 43.87 45.08
42.06 43.25 44.43
41.47 42.64 43.81
40.89 42.05 43.20
40.33 41.47 42.61
39.79 40.91 42.03
39.26 40.36 41.47
38.74 39.83 40.93
38.24 39.32 40.40
37.75 38.81 39.88
37.27 38.32 39.37
36.80 37.84 38.88
36.35 37.37 38.40
35.90 36.92 37.93
35.47 36.47 37.48
35.05 36.04 37.03
34.64 35.62 36.59
34.23 35.20 36.17
33.84 34.80 35.75
33.46 34.40 35.35
33.08 34.01 34.95
32.71 33.64 34.56
32.35 33.27 34.18
32.00 32.91 33.81
31.66 32.55 33.45
31.32 32.21 33.09
30.99 31.87 32.74
30.67 31.53 32.40
30.35 31.21 32.07
30.04 30.89 31.74
29.74 30.58 31.42
29.44 30.27 31.10
29.15 29.97 30.80
28.86 29.68 30.49
28.58 29.39 30.20
28.31 29.11 29.91
28.04 28.83 29.62
27.78 28.56 29.34
27.52 28.29 29.07
27.26 28.03 28.80
27.01 27.77 28.54
26.77 27.52 28.28
26.52 27.27 28.02
26.29 27.03 27.77
26.05 26.79 27.53
25.83 26.56 27.28
25.60 26.32 27.05
25.38 26.10 26.81
25.16 25.87 26.58
24.95 25.66 26.36
24.74 25.44 26.14
24.53 25.23 25.92
24.33 25.02 25.71
24.13 24.81 25.50
23.94 24.61 25.29
23.74 24.41 25.08
23.55 24.22 24.88
23.37 24.03 24.69
23.18 23.84 24.49
23.00 23.65 24.30
22.82 23.47 24.11
22.65 23.29 23.93
22.47 23.11 23.74
22.30 22.93 23.56
22.14 22.76 23.39
21.97 22.59 23.21
21.81 22.42 23.04
21.65 22.26 22.87
21.49 22.10 22.70
21.33 21.94 22.54
21.18 21.78 22.38
21.03 21.62 22.22
20.88 21.47 22.06
20.73 21.32 21.90
20.59 21.17 21.75
20.45 21.02 21.60
20.30 20.88 21.45
20.17 20.73 21.30
20.03 20.59 21.16
19.89 20.45 21.02
19.76 20.32 20.88
19.63 20.18 20.74
19.50 20.05 20.60
19.37 19.92 20.46
19.24 19.79 20.33
19.12 19.66 20.20
18.99 19.53 20.07
18.87 19.41 19.94
18.75 19.28 19.81
18.63 19.16 19.69
18.52 19.04 19.56
18.40 18.92 19.44
18.29 18.80 19.32
18.17 18.69 19.20
18.06 18.57 19.08
17.95 18.46 18.97
17.84 18.35 18.85
17.74 18.24 18.74
17.63 18.13 18.63
17.52 18.02 18.51
17.42 17.91 18.40
17.32 17.81 18.30
17.22 17.70 18.19
17.12 17.60 18.08
17.02 17.50 17.98
16.92 17.40 17.88
16.82 17.30 17.77
16.73 17.20 17.67
16.63 17.10 17.57
16.54 17.01 17.47
16.45 16.91 17.38
16.36 16.82 17.28
16.27 16.73 17.18
16.18 16.63 17.09
16.09 16.54 17.00
16.00 16.45 16.90
15.91 16.36 16.81
15.83 16.28 16.72
15.74 16.19 16.63
15.66 16.10 16.54
15.58 16.02 16.46
15.50 15.93 16.37
15.41 15.85 16.29
15.33 15.77 16.20
15.25 15.69 16.12
15.18 15.60 16.03
15.10 15.52 15.95
15.02 15.45 15.87
14.94 15.37 15.79
14.87 15.29 15.71
14.79 15.21 15.63
14.72 15.14 15.55
14.65 15.06 15.47
14.58 14.99 15.40
14.50 14.91 15.32
14.43 14.84 15.25
14.36 14.77 15.17
14.29 14.70 15.10
14.22 14.62 15.03
14.15 14.55 14.95
14.09 14.48 14.88
14.02 14.42 14.81
13.95 14.35 14.74
13.89 14.28 14.67
13.82 14.21 14.60
13.76 14.15 14.53
13.69 14.08 14.47
13.63 14.02 14.40
13.57 13.95 14.33
13.51 13.89 14.27
13.44 13.82 14.20
13.38 13.76 14.14
13.32 13.70 14.07
13.26 13.64 14.01
13.20 13.58 13.95
13.14 13.51 13.89
13.09 13.45 13.82
13.03 13.40 13.76
12.97 13.34 13.70
12.91 13.28 13.64
12.86 13.22 13.58
12.80 13.16 13.52
12.75 13.11 13.47
12.69 13.05 13.41
12.64 12.99 13.35
12.58 12.94 13.29
12.53 12.88 13.24
12.48 12.83 13.18
12.42 12.77 13.12
12.37 12.72 13.07
12.32 12.67 13.01
12.27 12.61 12.96
12.22 12.56 12.91
12.17 12.51 12.85
12.12 12.46 12.80
12.07 12.41 12.75
12.02 12.36 12.70
11.97 12.31 12.64
11.92 12.26 12.59
11.87 12.21 12.54
11.82 12.16 12.49
11.78 12.11 12.44
11.73 12.06 12.39
11.68 12.01 12.34
11.64 11.97 12.29
11.59 11.92 12.25
11.55 11.87 12.20
11.50 11.83 12.15
11.46 11.78 12.10
11.41 11.73 12.06
11.37 11.69 12.01
11.32 11.64 11.96
11.28 11.60 11.92
11.24 11.55 11.87
11.19 11.51 11.83
11.15 11.47 11.78
11.11 11.42 11.74
11.07 11.38 11.69
11.03 11.34 11.65
10.99 11.30 11.61
10.94 11.25 11.56
10.90 11.21 11.52
10.86 11.17 11.48
10.82 11.13 11.44
10.78 11.09 11.39
10.75 11.05 11.35
10.71 11.01 11.31
10.67 10.97 11.27
10.63 10.93 11.23
10.59 10.89 11.19
10.55 10.85 11.15
10.51 10.81 11.11
10.48 10.77 11.07
10.44 10.74 11.03
10.40 10.70 10.99
10.37 10.66 10.95
10.33 10.62 10.91
10.29 10.58 10.88
10.26 10.55 10.84
10.22 10.51 10.80
10.19 10.48 10.76
10.15 10.44 10.73
10.12 10.40 10.69
10.08 10.37 10.65
10.05 10.33 10.62
10.01 10.30 10.58
9.98 10.26 10.54
9.95 10.23 10.51
9.91 10.19 10.47
9.88 10.16 10.44
9.85 10.12 10.40
9.81 10.09 10.37
9.72 9.99 10.27
9.62 9.89 10.16
9.53 9.80 10.07
9.44 9.70 9.97
9.35 9.61 9.87
9.26 9.52 9.78
9.17 9.43 9.69
9.09 9.34 9.60
9.00 9.26 9.51
8.92 9.17 9.43
8.84 9.09 9.34
8.76 9.01 9.26
8.68 8.93 9.18
8.61 8.85 9.09
8.53 8.77 9.02
8.46 8.70 8.94
8.39 8.62 8.86
8.32 8.55 8.79
8.25 8.48 8.71
8.18 8.41 8.64
8.11 8.34 8.57
8.04 8.27 8.50
7.98 8.20 8.43
7.91 8.14 8.36
7.85 8.07 8.29
7.79 8.01 8.23
7.73 7.95 8.16
7.67 7.88 8.10
7.61 7.82 8.04
7.55 7.76 7.98
7.49 7.70 7.91
7.43 7.64 7.85
7.38 7.59 7.80
7.32 7.53 7.74
7.27 7.47 7.68
7.22 7.42 7.62
7.16 7.37 7.57
7.11 7.31 7.51
7.06 7.26 7.46
7.01 7.21 7.41
6.96 7.16 7.35
6.91 7.11 7.30
6.86 7.06 7.25
6.82 7.01 7.20
6.77 6.96 7.15
6.72 6.91 7.10
6.68 6.86 7.05
6.63 6.82 7.01
6.59 6.77 6.96
6.54 6.73 6.91
6.50 6.68 6.87
6.46 6.64 6.82
6.41 6.60 6.78
6.37 6.55 6.73
6.33 6.51 6.69
6.29 6.47 6.65
6.25 6.43 6.60
6.21 6.39 6.56
6.17 6.35 6.52
6.13 6.31 6.48
6.10 6.27 6.44
6.06 6.23 6.40
6.02 6.19 6.36
5.98 6.15 6.32
5.95 6.12 6.28
5.91 6.08 6.25
5.88 6.04 6.21
5.84 6.01 6.17
5.81 5.97 6.13
5.77 5.94 6.10
5.74 5.90 6.06
5.71 5.87 6.03
5.67 5.83 5.99
5.64 5.80 5.96
5.61 5.77 5.92
5.58 5.73 5.89
5.54 5.70 5.86
5.51 5.67 5.82
5.48 5.64 5.79
5.45 5.61 5.76
5.42 5.58 5.73
5.39 5.54 5.70
5.36 5.51 5.67
5.33 5.48 5.63
5.30 5.45 5.60
5.28 5.43 5.57
5.25 5.40 5.54
5.22 5.37 5.51
5.19 5.34 5.49
5.17 5.31 5.46
5.14 5.28 5.43
5.11 5.26 5.40
5.08 5.23 5.37
5.06 5.20 5.34
5.03 5.17 5.32
5.01 5.15 5.29
4.98 5.12 5.26
4.96 5.10 5.24
4.93 5.07 5.21
4.91 5.05 5.18
f(Vc) Vc (calc) /cm3 mol−1
### 128.54 Note: use Solver to make f(Vc) zero by varying Vc
mperaturas seleccionadas:
V /cm3 mol−1
Diagrama de presión-volumen para CO2 (van der Waals)
15
Tc = 324,1 K
10
Presion, P /Mpa
0
0 100 200 300 400 500 600
T = 294,4 K Tc = 324,1 K
P⁰ at 294,4 K Critical Point (lit)
10
Presion, P /Mpa
0
0 100 200 300 400 500 600
0
0 100 200 300 400 500 600
Volumen, V /cm3 mol−1
15 Diagrama de presión-volumen para CO2 (van der Waals)
T = 273,1 K T = 284 K T = 294,4 K
T = 304,1.0 K T = 314,1 K Tc = 324,1 K
P⁰ at 273,1 K P⁰ at 284 K P⁰ at 294,4 K
P⁰ at 304,1.0 K P⁰ at 314,1 K P⁰c at 324,1 K
10 Critical Point (calc) Critical Point (lit)
Presion, P /Mpa
0
0 100 200 300 400 500 600
0
0 100 200 300 400 500 600
0
0 100 200 300 400 500 600
0
0 100 200 300 400 500 600
Pressure /MPaTemp /°CSpecific Volume /m3 kg−1 (liq)Specific Volume /m3 kg−1 (gas)
2.0 -19.50 0.000971 0.019033
2.1 -17.90 0.000979 0.018074
2.2 -16.36 0.000986 0.017199
2.3 -14.86 0.000993 0.016396
2.4 -13.42 0.001000 0.015656
2.5 -12.01 0.001007 0.014973
2.6 -10.65 0.001014 0.014340
2.7 -9.32 0.001021 0.013751
2.8 -8.03 0.001028 0.013202
2.9 -6.78 0.001035 0.012688
3.0 -5.55 0.001043 0.012207
3.1 -4.36 0.001050 0.011755
3.2 -3.19 0.001057 0.011329
3.3 -2.05 0.001064 0.010928
3.4 -0.93 0.001072 0.010548
3.5 0.16 0.001079 0.010189
3.6 1.23 0.001087 0.009848
3.7 2.28 0.001095 0.009524
3.8 3.30 0.001103 0.009215
3.9 4.31 0.001111 0.008921
4.0 5.30 0.001119 0.008640
4.1 6.27 0.001127 0.008372
4.2 7.22 0.001135 0.008114
4.3 8.16 0.001144 0.007868
4.4 9.08 0.001152 0.007631
4.5 9.98 0.001161 0.007404
4.6 10.87 0.001170 0.007185
4.7 11.74 0.001179 0.006974
4.8 12.60 0.001189 0.006770
4.9 13.45 0.001199 0.006573
5.0 14.28 0.001209 0.006383
5.1 15.11 0.001219 0.006198
5.2 15.91 0.001230 0.006019
5.3 16.71 0.001241 0.005846
5.4 17.50 0.001252 0.005677
5.5 18.27 0.001264 0.005512
5.6 19.03 0.001276 0.005351
5.7 19.78 0.001289 0.005194
5.8 20.53 0.001303 0.005041
5.9 21.26 0.001317 0.004890
6.0 21.98 0.001332 0.004742
6.1 22.69 0.001347 0.004596
6.2 23.39 0.001364 0.004452
6.3 24.08 0.001382 0.004310
6.4 24.77 0.001401 0.004168
6.5 25.44 0.001421 0.004027
6.6 26.11 0.001444 0.003885
6.7 26.77 0.001469 0.003742
6.8 27.41 0.001497 0.003597
6.9 28.05 0.001529 0.003446
7.0 28.68 0.001567 0.003289
7.1 29.30 0.001613 0.003120
7.2 29.92 0.001675 0.002927
7.3 30.52 0.001774 0.002680
7.377 30.98 0.002139 0.002139