Tabel 1.

Pengamatan konsentrasi sulfur

Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k2 1/ca k1
(menit)
1 0 906.5 0% 1 0 0.001103
2 30 844.4 7% 1.073543 0.070965 0.001184
3 60 813.5 10% 1.114321 0.108245 0.0018 0.001229 0.000002
4 90 770.4 15% 1.176661 0.162681 0.001298
5 120 730.8 19% 1.240421 0.215451 0.001368

310 HDM Sulfur

1000 100%

80%
800
S content (ppm)

60%

XA
40%
600
20%

400 0%
0 15 30 45 60 75 90 105 120

Waktu (menit)
S (ppm) XS

Orde 1 S
0.25

0.2 f(x) = 0.00181922583687728 x

R² = 0.996891400754224
0.15
Axis Title

0.1

0.05

0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S
0.0016
0.0014
0.0012 f(x) = 2.14731032193241E-06 x + 0.00110777409128046
R² = 0.994274239544382
0.001
Axis Title

0.0008
0.0006
 Orde 2 S
0.0016
0.0014
0.0012 f(x) = 2.14731032193241E-06 x + 0.00110777409128046
R² = 0.994274239544382
0.001
Axis Title 0.0008
0.0006
0.0004
0.0002
0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 2. Pengamatan konsentrasi Fe
Waktu
Fe (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
No (menit)
1 0 0.21 0% 1 0 4.761905
2 30 ND #VALUE! #VALUE! #VALUE! #VALUE!
3 60 ND #VALUE! #VALUE! #VALUE! #VALUE!
4 90 0.14 33% 6475 8.775704 7.142857
5 120 ND #VALUE! #VALUE! #VALUE! #VALUE!

310 C Fe
0.25 100%

0.2 80%
Fe content (ppm)

0.15 60%

XA
0.1 40%

0.05 20%

0 0%
0 15 30 45 60 75 90 105 120

Waktu (menit)
Fe (ppm) XFe

Orde 1 Fe
10
f(x) = 0.0975078209618638 x
9 R² = 1
8
7
6
Axis Title

5
4
3
2
1
0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 Fe
8
f(x) = 0.0264550264550265 x + 4.76190476190476
7 R² = 1
6
5
e
 Orde 2 Fe
8
f(x) = 0.0264550264550265 x + 4.76190476190476
7 R² = 1
6
5
Axis Title

4
3
2
1
0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 3. Pengamatan konsentrasi Ni
Waktu
Ni (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
No (menit)
1 0 0.1 0% 1 0 10
2 30 0.32 -220% 2832.813 7.949025 3.125
3 60 0.22 -120% 4120.455 8.323719 0.0926 4.545455 -0.0279
4 90 0.21 -110% 4316.667 8.370239 4.761905
5 120 0.2 -100% 4532.5 8.419029 5

310 C Ni
0.35 0%
0.3
-50%
0.25
Ni content (ppm)

0.2 -100%

XA
0.15 -150%
0.1
-200%
0.05
0 -250%
0 15 30 45 60 75 90 105 120

Waktu (menit)
Ni (ppm) XNi

Orde 1 Ni
9
f(x) = 0.0926481054943638 x
8 R² = 0.847654540393954
7
6
5
Axis Title

4
3
2
1
0
0 20 40 60 80 100 120 140
t (menit)

Orde 2 Ni
12

10

8
itle

f(x) = − 0.0278769841269841 x + 7.15909090909091

6
 Orde 2 Ni
12

10

8
Axis Title f(x) = − 0.0278769841269841 x + 7.15909090909091
6 R² = 0.253450663515065

0
0 20 40 60 80 100 120 140
Axis Title
Kadar nikel pada umpan jauh lebih kecil saat setelah terjadi
reaksi, dicurigai karena adanya kebocoran katalis. Namun,
kadar nikel secara gradial menurun dari menit 30 hingga akhir
reaksi. Hal ini terjadi pada setiap variasi temperatur. Mungkin
perlu dilakukan cek kembali untuk kadar nikel pada umpan
segar.
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k No
(menit)
1 0 906.5 0% 1 0 0.001103 1
3 30 857.8 5% 1.056773 0.05522 0.001166 2
4 60 785.5 13% 1.154042 0.143271 0.0023 0.001273 3.00E-06 3
5 90 755.3 17% 1.200185 0.182476 0.001324 4
6 120 682.2 25% 1.328789 0.284268 0.001466 5

320 HDM Sulfur

1000 100% 0.25

900 80% 0.2

800
S content (ppm)

Fe content (ppm)
60% 0.15
700

XA
40% 0.1
600

500 20% 0.05

400 0% 0
0 15 30 45 60 75 90 105 120 0

Waktu (menit)
S (ppm) XS

Orde 1 S
0.3 10
f(x) = 0
9 R² = 0.
0.25 f(x) = 0.0022514020784206 x
R² = 0.994017450942751 8
0.2 7
6
Axis Title

0.15 Axis Title 5

0.1 4
3
0.05 2
1
0
0 20 40 60 80 100 120 140 0
0
Axis Title

Orde 2 S
0.0016
9
0.0014 f(x) = 0.
f(x) = 2.94535995208522E-06 x + 0.00108964127551398 8 R² = 0.5
R² = 0.976971729166291
0.0012 7
0.001 6
is Title

5
s Title

0.0008
4
 Orde 2 S
0.0016
9
0.0014 f(x) = 0.
f(x) = 2.94535995208522E-06 x + 0.00108964127551398 8 R² = 0.5
R² = 0.976971729166291
0.0012 7
0.001 6
Axis Title

Axis Title
0.0008
4
0.0006
3
0.0004
2
0.0002 1
0 0
0 20 40 60 80 100 120 140 0

Axis Title
 Tabel 2. Pengamatan konsentrasi Fe
Waktu
Fe (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k No
(menit)
0 0.21 0% 1 0 4.761905 1
30 0.13 38% 6973.077 8.849812 7.692308 2
60 0.14 33% 6475 8.775704 #VALUE! 7.142857 #VALUE! 3
90 ND #VALUE! #VALUE! #VALUE! #VALUE! 4
120 ND #VALUE! #VALUE! #VALUE! #VALUE! 5

320 C Fe
0.25 40% 0.2
35% 0.18
0.2 0.16
30%
0.14
25%
Fe content (ppm)

0.15

Ni content (ppm)
0.12
20% 0.1

XA
0.1 15% 0.08
10% 0.06
0.05 0.04
5%
0.02
0 0% 0
0 15 30 45 60 75 90 105 120 0

Waktu (menit)
Fe (ppm) XFe

Orde 1 Fe
10 10
f(x) = 0.176008130879046 x f(x) = 0.09
9 R² = 0.897463151259542 9 R² = 0.832
8 8
7 7
6 6
Axis Title

Axis Title
5 5
4 4
3 3
2 2
1 1
0 0
0 20 40 60 80 100 120 140 0
Axis Title

Orde 2 Fe
9 12
f(x) = 0.0396825396825397 x + 5.34188034188034
8 R² = 0.584101382488479
10
7
6 8 f(x) = − 0.
R² = 0.406
5
is Title
s Title

6
4
 Orde 2 Fe
9 12
f(x) = 0.0396825396825397 x + 5.34188034188034
8 R² = 0.584101382488479
10
7
6 8 f(x) = − 0.
R² = 0.406
5

Axis Title
Axis Title

6
4
3 4
2
2
1
0 0
0 20 40 60 80 100 120 140 0

Axis Title
 Tabel 3. Pengamatan konsentrasi Ni
Waktu
Ni (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
0 0.1 0% 1 0 10
30 0.15 -50% 6043.333 8.706711 6.666667
60 0.18 -80% 5036.111 8.524389 0.0963 5.555556 -0.024032
90 0.13 -30% 6973.077 8.849812 7.692308
120 0.17 -70% 5332.353 8.581548 5.882353

320 C Ni
0.2 0%
0.18 -10%
0.16 -20%
0.14 -30%
Ni content (ppm)

0.12
-40%
0.1

XA
-50%
0.08
0.06 -60%
0.04 -70%
0.02 -80%
0 -90%
0 15 30 45 60 75 90 105 120

Waktu (menit)

Ni (ppm) XNi

Orde 1 Ni
10
f(x) = 0.0962567966625844 x
9 R² = 0.832678312204993
8
7
6
Axis Title

5
4
3
2
1
0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 Ni
12

10

8 f(x) = − 0.0240321769733535 x + 8.60130718954249

R² = 0.406119974246656
is Title

6
 Orde 2 Ni
12

10

8 f(x) = − 0.0240321769733535 x + 8.60130718954249

R² = 0.406119974246656
Axis Title

0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 906.5 0% 1 0 0.001103
3 30 856.9 5% 1.057883 0.05627 0.001167
4 60 776.2 14% 1.167869 0.155181 0.0025 0.001288 0.000003
5 90 710.9 22% 1.275144 0.243059 0.001407
6 120 673.3 26% 1.346354 0.2974 0.001485

330 C Sulfur
1000 100% 1
0.9
80% 0.8
0.7
800

S content (ppm)
0.6
S content (ppm)

60%
0.5

XA
40% 0.4
600 0.3
20% 0.2
0.1
400 0% 0
0 15 30 45 60 75 90 105 120 0

Waktu (menit)
S (ppm) XA

Orde 1 S
0.35

0.3
f(x) = 0.00253934370821458 x
R² = 0.99617350753361
0.25

0.2
Axis Title

0.15

0.1

0.05

0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S
0.0016
0.0014 f(x) = 3.3460881645181E-06 x + 0.00108930644451149
R² = 0.990136328570481
0.0012
0.001
 Orde 2 S
0.0016
0.0014 f(x) = 3.3460881645181E-06 x + 0.00108930644451149
R² = 0.990136328570481
0.0012
0.001
Axis Title

0.0008
0.0006
0.0004
0.0002
0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 2. Pengamatan konsentrasi Fe
Waktu
No Fe (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 0.21 0% 1 0 4.761905
2 30 ND #VALUE! #VALUE! #VALUE! #VALUE!
3 60 ND #VALUE! #VALUE! #VALUE! #VALUE!
4 90 ND #VALUE! #VALUE! #VALUE! #VALUE!
5 120 ND #VALUE! #VALUE! #VALUE! #VALUE!

330 C Fe
1 100%
0.9
0.8 80%
0.7
S content (ppm)

0.6 60%
0.5

XA
0.4 40%
0.3
0.2 20%
0.1
0 0%
0 15 30 45 60 75 90 105 120

Waktu (menit)
Fe (ppm) XFe
f(x) = NaN x
R² = 0 Orde 1 Fe
1
0.9
0.8
0.7
0.6
Axis Title

0.5
0.4
0.3
0.2
0.1
0
0 20 40 60 80 100 120 140
Axis Title

f(x) = NaN x + NaN

R² = 0 Orde 2 Fe
5
4.5
4
3.5
3
e
f(x) = NaN x + NaN
R² = 0 Orde 2 Fe
5
4.5
4
3.5
3
Axis Title

2.5
2
1.5
1
0.5
0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 3. Pengamatan konsentrasi Ni
Waktu
No Ni (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 0.1 0% 1 0 10
2 30 0.22 -120% 4120.455 8.323719 4.545455
3 60 0.24 -140% 3777.083 8.236707 0.0933 4.166667 -0.0268
4 90 0.25 -150% 3626 8.195885 4
5 120 0.16 -60% 5665.625 8.642172 6.25

330 C Ni
1 100%
0.9
0.8 80%
0.7
S content (ppm)

0.6 60%
0.5

XA
0.4 40%
0.3
0.2 20%
0.1
0 0%
0 15 30 45 60 75 90 105 120

Waktu (menit)
Ni (ppm) XNi

Orde 1 Ni
10
f(x) = 0.0932816440935689 x
9 R² = 0.84211552643877
8
7
6
Axis Title

5
4
3
2
1
0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 Ni
12

10

8
f(x) = − 0.0268181818181818 x + 7.40151515151515
Title

6 R² = 0.255605978743695
 Orde 2 Ni
12

10

8
f(x) = − 0.0268181818181818 x + 7.40151515151515
Axis Title
6 R² = 0.255605978743695

0
0 20 40 60 80 100 120 140
Axis Title
100%

80%

60%
XA

40%

20%

0%

140
140
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 906.5 0% 1 0 0.001103
2 30 800.1 12% 1.132983 0.124854 0.00125
3 60 721.6 20% 1.256236 0.22812 0.0049 0.001386 0.000008
4 90 597.9 34% 1.51614 0.416168 0.001673
5 120 472.3 48% 1.919331 0.651977 0.002117

310 C HDS 1 Ord

1000 100% 0.7
900 80% 0.6
f(x) = 0.00493055954369699 x
800 0.5 R² = 0.985710917420334
S content (ppm)

60%
700 0.4

XA

Axis Title
40%
600 0.3

500 20% 0.2

400 0% 0.1
0 15 30 45 60 75 90 105 120
0
0 20 40
Waktu (menit)
S (ppm) XA
 Orde 1 S Orde 2 S
0.0025

) = 0.00493055954369699 x 0.002
= 0.985710917420334 f(x) = 8.16995150980727E-06 x + 0.00101552608104447
R² = 0.933149684152458
0.0015
Axis Title

0.001

0.0005

0
20 40 60 80 100 120 140 0 20 40 60 80 100 120
Axis Title Axis Title
2S

+ 0.00101552608104447

80 100 120 140

s Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 990.2 0% 1 0 0.00101
2 30 864.2 13% 1.1458 0.136103 0.001157
3 60 782.7 21% 1.265108 0.235157 0.0037 0.001278 0.000004
4 90 698.3 29% 1.418015 0.349258 0.001432
5 120 649.3 34% 1.525027 0.422012 0.00154

320 C HDS 1
1000 100% 0.45

0.4
80%
0.35
800
S content (ppm)

60% 0.3

0.25

XA

Axis Title
40%
0.2
600
0.15
20%
0.1

400 0% 0.05
0 15 30 45 60 75 90 105 120
0

Waktu (menit)
S (ppm) XA

DATA LAMA (UMPAN LCGO SEBELUM 11 JANUARI 2024)

Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 906.5 8% 1 0 0.001103
2 30 832.1 16% 1.190001 0.173954 0.001202
3 60 799.5 19% 1.238524 0.21392 0.0027 0.001251 0.000004
4 90 717.7 28% 1.379685 0.321855 0.001393
5 120 635.6 36% 1.557898 0.443338 0.001573
 Orde 1 S
0.45 0.0018
f(x) = 0.00371360041837786 x
0.4 R² = 0.9958650093947 0.0016
f(x) = 4.451186630
0.35 0.0014 R² = 0.9974093088

0.3 0.0012

0.25 0.001
Axis Title

Axis Title
0.2 0.0008

0.15 0.0006

0.1 0.0004

0.05 0.0002

0 0
0 20 40 60 80 100 120 140 0 20

Axis Title
 Orde 2 S
0.0018

0.0016
f(x) = 4.45118663063674E-06 x + 0.00101629573306083
0.0014 R² = 0.997409308866293

0.0012

0.001
Axis Title

0.0008

0.0006

0.0004

0.0002

0
0 20 40 60 80 100 120 140

Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 990.2 0% 1 0 0.00101
2 30 899.1 9% 1.101324 0.096513 0.001112
3 60 807.3 18% 1.226558 0.204212 0.0036 0.001239 7.00E-06
4 90 737.7 25% 1.34228 0.29437 0.001356
5 120 621.7 37% 1.59273 0.465449 0.001608

330 C HDS 1
1000 100% 0.5

0.45
900
80% 0.4

800 0.35
S content (ppm)

60%
0.3
700

XA

Axis Title
0.25
40%
600 0.2

20% 0.15
500
0.1
400 0% 0.05
0 15 30 45 60 75 90 105 120
0
Waktu (menit)
S (ppm) XA

DATA LAMA (UMPAN LCGO SEBELUM 11 JANUARI 2024)

No. Waktu (menS (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k

1 0 906.5 0 1 0 0.0042 0.001103 0.000007
2 30 827.7 0.086928 1.095204 0.09094 0.001208
3 60 752.6 0.169774 1.204491 0.186057 0.001329
4 90 629.1 0.306012 1.440947 0.365301 0.00159
5 120 517.5 0.429123 1.751691 0.560582 0.001932
 Orde 1 S
0.5 0.0018

0.45 0.0016
f(x) = 0.00361093568300958 x f(x) = 4.801776538690
0.4 R² = 0.993608755919919 0.0014 R² = 0.9638370439632
0.35
0.0012
0.3
0.001
Axis Title

Axis Title
0.25
0.0008
0.2
0.0006
0.15

0.1 0.0004

0.05 0.0002

0 0
0 20 40 60 80 100 120 140 0 20

Axis Title
 Orde 2 S
0.0018

0.0016
f(x) = 4.80177653869017E-06 x + 0.000976868337815194
0.0014 R² = 0.963837043963291

0.0012

0.001
Axis Title

0.0008

0.0006

0.0004

0.0002

0
0 20 40 60 80 100 120 140

Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 915 0% 1 0 0.001093
3 30 829 9% 1.103739 0.098704 0.001206
4 60 751 18% 1.218375 0.197518 0.0035 0.001332 0.000005
5 90 695.2 24% 1.316168 0.274724 0.001438
6 120 574.6 37% 1.592412 0.46525 0.00174

310 C HDS 2
1000 100% 0.5

0.45
900
80%
0.4

800 0.35
S content (ppm)

60%
0.3
700

XA

Axis Title
0.25
40%
600 0.2

20% 0.15
500
0.1

400 0% 0.05
0 15 30 45 60 75 90 105 120
0

Waktu (menit)
S (ppm) XA

DATA LAMA (SULFIDASI HANYA MENGGUNAKAN 1.5 ML CS2)

No. Waktu (menS (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k

1 0 915 0 1 0 0.0023 0.001093 0.000003
3 30 898.3 0.018251 1.018591 0.01842 0.001113
4 60 837 0.085246 1.09319 0.0891 0.001195
5 90 749.7 0.180656 1.220488 0.199251 0.001334
6 120 659.2 0.279563 1.388046 0.327897 0.001517
 Orde 1 S Or
0.5 0.002

0.45 0.0018

0.4 f(x) = 0.00353212654006372 x 0.0016 f(x) = 5.09017409704771E-

R² = 0.988736772491133 R² = 0.945696862195329
0.35 0.0014

0.3 0.0012
Axis Title

Axis Title
0.25 0.001

0.2 0.0008

0.15 0.0006

0.1 0.0004

0.05 0.0002

0 0
0 20 40 60 80 100 120 140 0 20 40
Axis Title
 Orde 2 S
0.002

.0018

.0016 f(x) = 5.09017409704771E-06 x + 0.0010564901151452

R² = 0.945696862195329
.0014

.0012

0.001

.0008

.0006

.0004

.0002

0
0 20 40 60 80 100 120 140

Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 915 0% 1 0 0.001093
2 30 806.5 12% 1.134532 0.12622 0.00124
3 60 745.2 19% 1.227858 0.205271 0.0039 0.001342 0.000006
4 90 647.8 29% 1.412473 0.345342 0.001544
5 120 563.1 38% 1.624933 0.485467 0.001776

320 C HDS 2
1000 100%

80%

800
S content (ppm)

60%

XA
40%
600

20%

400 0%
0 15 30 45 60 75 90 105 120

Waktu (menit)
S (ppm) XA

DATA LAMA (SULFIDASI HANYA MENGGUNAKAN 1.5 ML CS2)

No. Waktu (menS (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k

1 0 915 0 1 0 0.0026 0.001093 0.000004
2 30 904.6 0.011366 1.011497 0.011431 0.001105
3 60 819.1 0.104809 1.11708 0.110718 0.001221
4 90 730.6 0.20153 1.252395 0.225058 0.001369
5 120 644.1 0.296066 1.420587 0.35107 0.001553
 Orde 1 S
100% 0.6 0.002

0.0018
0.5 f(x) = 5.565
80% 0.0016 R² = 0.9774
f(x) = 0.00390517392053456 x
R² = 0.996981353856477 0.0014
0.4
60%
0.0012

Axis Title
Axis Title
XA

0.3 0.001
40%
0.0008
0.2
0.0006
20%
0.0004
0.1
0% 0.0002
120
0 0
0 20 40 60 80 100 120 140 0 20

Axis Title
 Orde 2 S
0.002

0.0018
f(x) = 5.56578457611068E-06 x + 0.00106491557265041
0.0016 R² = 0.977437228635374
0.0014

0.0012
Axis Title

0.001

0.0008

0.0006

0.0004

0.0002

0
0 20 40 60 80 100 120 140

Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 915 0% 1 0 0.001093
3 30 821.3 10% 1.114087 0.108036 0.001218
4 60 741.5 19% 1.233985 0.210249 0.0038 0.001349 7E-06
5 90 645.9 29% 1.416628 0.348279 0.001548
6 120 572.5 37% 1.598253 0.468911 0.001747

330 C HDS 2
1000 100% 0.5

0.45
900
80% 0.4

800 0.35
S content (ppm)

60%
0.3
700

Axis Title
XA
0.25
40%
600 0.2

0.15
20%
500
0.1

400 0% 0.05
0 15 30 45 60 75 90 105 120
0

Waktu (menit)
S (ppm) XA

DATA LAMA (SULFIDASI HANYA MENGGUNAKAN 1.5 ML CS2)

No. Waktu (menS (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k

1 0 915 0 1 0 0.0047 0.001093 0.000007
3 30 864.4 0.055301 1.058538 0.056888 0.001157
4 60 682.2 0.254426 1.341249 0.293601 0.001466
5 90 587.8 0.357596 1.556652 0.442537 0.001701
6 120 517.5 0.434426 1.768116 0.569915 0.001932
 Orde 1 S
0.5 0.002

0.45 f(x) = 0.00383224095336026 x 0.0018

R² = 0.998668331943934 f(x) = 5.46100943
0.4 0.0016
R² = 0.986790950
0.35 0.0014

0.3 0.0012
Axis Title

Axis Title
0.25 0.001

0.2 0.0008

0.15 0.0006

0.1 0.0004

0.05 0.0002

0 0
0 20 40 60 80 100 120 140 0 20
Axis Title
 Orde 2 S
0.002

0.0018

0.0016 f(x) = 5.46100943105231E-06 x + 0.00106314901308302

R² = 0.986790950393685
0.0014

0.0012
Axis Title

0.001

0.0008

0.0006

0.0004

0.0002

0
0 20 40 60 80 100 120 140

Axis Title
HDM
T K ln (k) 1/T
310 0.0018 -6.319969 0.003226 HDM
320 0.0023 -6.074846 0.003125
-5.8
330 0.0025 -5.991465 0.00303 0.003 0.00305 0.0031 0.0031
-5.9
HDS 1
-6 f(x) = − 1688.36645872114 x − 0.84917
T K ln (k) 1/T R² = 0.934447215402237
310 0.0049 -5.31852 0.003226

ln (k)
-6.1
320 0.0037 -5.599422 0.003125
330 0.0036 -5.626821 0.00303 -6.2

-6.3
HDS 2
T K ln (k) 1/T -6.4
310 0.0035 -5.654992 0.003226 1/T
320 0.0039 -5.546779 0.003125
330 0.0038 -5.572754 0.00303
-Ea/R -1688.4
R 8.314
Ea 14037.36 J/mol
 HDM HDS 1
00305 0.0031 0.00315 0.0032 0.00325 -5.1
0.003 0.00305 0.0031 0.00315 0.0032

-5.2
x) = − 1688.36645872114 x − 0.849176240792447
² = 0.934447215402237 -5.3

-5.4 f(x) = 1589.95087113249 x − 10.486755719893

R² = 0.829849762265129

-5.5

-5.6

1/T
-5.7

-Ea/R 1590
R 8.314
Ea -13219.26 J/mol
1 HDS 2
0.00315 0.0032 0.00325 -5.48
0.003 0.00305 0.0031 0.00315 0.0032 0.00325
-5.5
-5.52
-5.54
-5.56 f(x) = − 427.65842219767 x − 4.25420492302778
486755719893 R² = 0.54778701256088
-5.58
-5.6
-5.62
-5.64
-5.66
-5.68

-Ea/R -427.66
R 8.314
Ea 3555.565 J/mol
0032 0.00325
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 526.01 0% 1 0 0.001901
3 30 469.27 11% 1.120911 0.114142 0.002131
4 60 427.89 19% 1.229311 0.206454 0.002407 0.002337 6E-06
5 90 340.56 35% 1.544544 0.434729 0.002936
6 120 398.04 24% 1.3215 0.278768 0.002512

HDS 1 330 Or
600 40% 0.5
0.45
35%
500 0.4
30%
f(x) = 0.0029270747222542
S content (ppm)

400 0.35
25% R² = 0.710802893528621
0.3

Axis Title

Axis Title
300 20% 0.25
15% 0.2
200
10% 0.15
100
5% 0.1
0 0% 0.05
0 30 60 90 120
0
Waktu (menit) 0 20 40

S (ppm) XA
 Orde 1 S Orde 2 S
0.5 0.0035
0.45
0.4 0.003
0.35 f(x) = 0.00292707472225423 x + 0.0311940411892761 0.0025 f(x) = 6.75927441778842E-06 x + 0.0019579982604426
0.3 R² = 0.710802893528621 R² = 0.664420801676691
0.002

Axis Title
0.25
0.2 0.0015
0.15
0.001
0.1
0.05 0.0005
0 0
0 20 40 60 80 100 120 140 0 20 40 60 80 100
Axis Title Axis Title
 Orde 2 S

78842E-06 x + 0.00195799826044261
76691

40 60 80 100 120 140

Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 477.91 0% 1 0 0.002092
3 30 469.57 2% 1.017761 0.017605 0.00213
4 60 400 16% 1.194775 0.177958 0.003954 0.0025 1E-05
5 90 373.05 22% 1.281088 0.24771 0.002681
6 120 323.66 32% 1.47658 0.389729 0.00309

HDS 1 320 Or
600 35% 0.45
500 30% 0.4
25% 0.35 f(x) = 0.003365208732
S content (ppm)

400 R² = 0.9574661703409
0.3

Axis Title
20%
300 0.25

Axis Title
15%
200 0.2
10%
0.15
100 5% 0.1
0 0% 0.05
0 30 60 90 120
0
Waktu (menit) 0 20 40

Column C Column D
 Orde 1 S Orde 2 S
0.45 0.0035
0.4 0.003
f(x) = 8.4847783052994E-06 x + 0.00198937728790656
0.35 f(x) = 0.00336520873237073 x − 0.0353121738324907 R² = 0.947810435260384
0.0025
0.3 R² = 0.957466170340998
0.002

Axis Title
0.25
0.2 0.0015
0.15 0.001
0.1
0.0005
0.05
0 0
0 20 40 60 80 100 120 140 0 20 40 60 80 100

Axis Title Axis Title

 Orde 2 S

2994E-06 x + 0.00198937728790656
60384

0 60 80 100 120 140

Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur 310
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 534.45 0% 1 0 0.001871
3 30 443.88 17% 1.204042 0.185684 0.002253
4 60 418.6 22% 1.276756 0.244322 0.003042 0.002389 8E-06
5 90 400.12 25% 1.335724 0.289474 0.002499
6 120 332.42 38% 1.607755 0.474839 0.003008

HDS1 310
600 40%
35%
500
30%
S content (ppm)

400
25%
300 20%
15%
200
10%
100
5%
0 0%
0 30 60 90 120
waktu (menit)

S (ppm) XA

Orde 1 S HDS1 310

0.5
0.45
f(x) = 0.00351155885223122 x + 0.0281702539612497
0.4 R² = 0.939234380967635
0.35
0.3
Axis Title

0.25
0.2
0.15
0.1
0.05
0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S HDS1 310

0.0035

0.003
f(x) = 8.40236472765183E-06 x + 0.00189992847570661
0.0025 R² = 0.932689163366381
0.002
xis Title

0.0015
 Orde 2 S HDS1 310
0.0035

0.003
f(x) = 8.40236472765183E-06 x + 0.00189992847570661
0.0025 R² = 0.932689163366381

Axis Title 0.002

0.0015

0.001

0.0005

0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 2. Pengamatan konsentrasi sulfur 320
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 481.41 0% 1 0 0.002077
3 30 453.87 6% 1.060678 0.058908 0.002203
4 60 448.18 7% 1.074144 0.071524 0.004599 0.002231 1E-05
5 90 359.198 25% 1.340236 0.292846 0.002784
6 120 308.49 36% 1.560537 0.44503 0.003242

HDS1 320
600 40%
35%
500
30%
S cotent (ppm)

400
25%
300 20%
15%
200
10%
100
5%
0 0%
0 30 60 90 120
Waktu (menit)

S (ppm) XA

Orde 1 S HDS1 320

0.5
0.45
0.4
0.35 f(x) = 0.0037466559496046 x − 0.0511377081233491
R² = 0.892183175422709
0.3
Axis Title

0.25
0.2
0.15
0.1
0.05
0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S HDS1 320

0.0035

0.003
f(x) = 9.69811731030809E-06 x + 0.00192557854810064
R² = 0.873256419672044
0.0025

0.002
xis Title

0.0015
 Orde 2 S HDS1 320
0.0035

0.003
f(x) = 9.69811731030809E-06 x + 0.00192557854810064
R² = 0.873256419672044
0.0025

0.002

Axis Title
0.0015

0.001

0.0005

0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 3. Pengamatan konsentrasi sulfur 330
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 593.89 0% 1 0 0.001684
3 30 454.91 23% 1.305511 0.266595 0.002198
4 60 418.41 30% 1.419397 0.350232 0.003673 0.00239 1E-05
5 90 401.3 32% 1.479915 0.391985 0.002492
6 120 319.49 46% 1.858869 0.619968 0.00313

Chart Title
700 50%
45%
600
40%
500 35%
S content (ppm)

400 30%
25%
300 20%
200 15%
10%
100
5%
0 0%
0 30 60 90 120
Waktu (menit)

S (ppm) XA

Orde 1 S HDS1 330

0.7

0.6
f(x) = 0.00455108868375171 x + 0.0526906402132446
0.5 R² = 0.926668928638973

0.4
Axis Title

0.3

0.2

0.1

0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S HDS1 330

0.0035

0.003
f(x) = 1.06200471441509E-05 x + 0.00174158527004736
0.0025 R² = 0.928860493531597

0.002
is Title

0.0015
 Orde 2 S HDS1 330
0.0035

0.003
f(x) = 1.06200471441509E-05 x + 0.00174158527004736
0.0025 R² = 0.928860493531597

0.002

Axis Title
0.0015

0.001

0.0005

0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 1. Pengamatan konsentrasi sulfur 310
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 504.95 0% 1 0 0.00198
3 30 463.3 8% 1.089899 0.086085 0.002158
4 60 456.17 10% 1.106934 0.101594 0.006126 0.002192 2E-05
5 90 428.77 15% 1.177671 0.163539 0.002332
6 120 256.33 49% 1.969922 0.677994 0.003901

HDS 2 310
0 30 60 90 120
600 60%
500 50%
S content (ppm)

400 40%
300 30%
200 20%
100 10%
0 0%
0 30 60 90 120
XA

S (ppm) XA

Orde 1 S HDS 2 310

0.8
0.7
0.6
0.5
f(x) = 0.00477813874347196 x − 0.0808461252209843
Axis Title

0.4 R² = 0.70296755384937
0.3
0.2
0.1
0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S HDS 2 310

0.0045
0.004
0.0035
0.003 f(x) = 1.33849267550623E-05 x + 0.00170979674850259
R² = 0.652227810779931
0.0025
Axis Title

0.002
0.0015
 Orde 2 S HDS 2 310
0.0045
0.004
0.0035
0.003 f(x) = 1.33849267550623E-05 x + 0.00170979674850259
R² = 0.652227810779931
0.0025

Axis Title
0.002
0.0015
0.001
0.0005
0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 2. Pengamatan konsentrasi sulfur 320
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca k
(menit)
1 0 483.98 0% 1 0 0.002066
3 30 446.8 8% 1.083214 0.079933 0.002238
4 60 439.14 9% 1.102109 0.097225 0.005274 0.002277 1E-05
5 90 381.59 21% 1.268325 0.237697 0.002621
6 120 276.31 43% 1.751583 0.56052 0.003619

HDS 2 320
600 50%
45%
500 40%
35%
S content (ppm)

400
30%
300 25%
20%
200 15%
100 10%
5%
0 0%
0 30 60 90 120
XA

S (ppm) XA

Orde 1 S HDS 2 320

0.6

0.5

0.4 f(x) = 0.00426268217625019 x − 0.0606859624629852

R² = 0.833280535524526
Axis Title

0.3

0.2

0.1

0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S HDS 2 320

0.004
0.0035
0.003 f(x) = 1.16277353655663E-05 x + 0.00186658673184508
R² = 0.783667969265756
0.0025
xis Title

0.002
0.0015
 Orde 2 S HDS 2 320
0.004
0.0035
0.003 f(x) = 1.16277353655663E-05 x + 0.00186658673184508
R² = 0.783667969265756
0.0025

Axis Title
0.002
0.0015
0.001
0.0005
0
0 20 40 60 80 100 120 140
Axis Title
 Tabel 3. Pengamatan konsentrasi sulfur 330
Waktu
No. S (ppm) XA Ca0/Ca lnCa0/Ca k 1/ca
(menit)
1 0 572.79 0% 1 0 0.001746
3 30 466.57 19% 1.227661 0.205111 0.002143
4 60 423.48 26% 1.352579 0.302013 0.00337 0.002361
5 90 384.83 33% 1.488423 0.397717 0.002599
6 120 343.87 40% 1.665717 0.510255 0.002908

HDS 2 330
700 45%
600 40%
35%
500
S contetn (ppm)

30%
400 25%
300 20%
15%
200
10%
100 5%
0 0%
0 30 60 90 120
XA

S (ppm) XA

Orde 1 S HDM 2 330

0.6

0.5 f(x) = 0.00404372447044598 x + 0.0403959162082997

R² = 0.972529148358701
0.4
Axis Title

0.3

0.2

0.1

0
0 20 40 60 80 100 120 140
Axis Title

Orde 2 S HDS 2 330

0.0035

0.003
f(x) = 9.26573093151464E-06 x + 0.00179548694188929
0.0025 R² = 0.989253054238972
0.002
s Title
 Orde 2 S HDS 2 330
0.0035

0.003
f(x) = 9.26573093151464E-06 x + 0.00179548694188929
0.0025 R² = 0.989253054238972
0.002

Axis Title
0.0015

0.001

0.0005

0
0 20 40 60 80 100 120 140
Axis Title
 k

8E-06

45%
40%
35%
30%
25%
20%
15%
10%
5%
0%
120

120 140

9
9

120 140