T=50°C P=400mmHg

P1sat/mmHg P2sat/mmHg Pt/mmHg x1 y1 x2 t/°C x1 y1

400 159.4 253.5 0 0 1 38.45 1 1
458.3 184.6 289.65 0.1 0.2123252 0.9 42 0.786993 0.901697
532 216.8 325.8 0.2 0.3775322 0.8 46 0.581218 0.77302
615 253.5 361.95 0.3 0.5097389 0.7 50 0.405256 0.623081
707.9 295.2 398.1 0.4 0.6179352 0.6 54 0.253937 0.449406
65
811.8 342.3 434.25 0.5 0.7081174 0.5 58 0.122897 0.249419
937.4 400 470.4 0.6 0.7844388 0.4 62.33 0 0
506.55 0.7 0.8498667 0.3 60
542.7 0.8 0.9065782 0.2
578.85 0.9 0.9562063 0.1 55
615 1 1 0

Loi de Raoult 50

T / °C
650 45

600
40
550
35
500
450
P / mm Hg

30
x1
0 0.1
400 x2

350
300
250
200
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1 ; y1
 x1 x2 p partielle 1 g1 ln g1 delta ln g1 delta lng2 lng2 g2 p partielle2 P totale y1
0.000 1.000 0 8.00 2.079 0.000 1.00 149 149 0.000
0.017 0.984 0.178 -0.003
0.033 0.967 190 6.69 1.901 0.003 1.00 145 335 0.568
0.075 0.925 0.419 -0.034
0.117 0.883 443 4.40 1.482 0.037 1.04 137 580 0.764
0.218 0.783 0.717 -0.199
0.318 0.682 588 2.15 0.765 0.236 1.27 129 717 0.820
0.436 0.564 0.422 -0.326
0.554 0.446 672 1.41 0.344 0.562 1.75 117 789 0.852
0.645 0.355 0.228 -0.414
0.736 0.264 711 1.12 0.116 0.976 2.65 104 815 0.872
0.868 0.132 0.116 -0.765
1.000 0.000 860 1.00 0.000 1.740 5.70 0 860 1.000

1000
1000

900 900

800 800

700 700

600 600
P Partielle

500
P totale

500
p partielle 1
y1
400 p partielle2 400 Column K
Column K
300 300

200 200

100 100

0
0
0.0 0.2 0.4 0.6 0.8 1.0 0.0 0.2 0.4 0.6 0.8 1.0

x1 x1 ; y1
A12 2.20 A21 1.44 B calculés… par margules
x1 y1 p/kPa P1 P2 ln g1 ln g2 ge/rtx1x2 margules lng1 lng2 p1 p2 P margules
0.00 0.00 29.83 0.00 29.83 2.20 0.00 2.20 2.20 2.20 0.00 0.00 29.83 29.83
0.05 0.15 33.63 4.93 28.70 1.75 0.01 2.04 2.16 2.00 0.00 6.31 28.56 34.87
0.10 0.21 35.21 7.28 27.94 1.41 0.04 1.95 2.13 1.79 0.02 10.65 27.48 38.13
0.20 0.27 36.27 9.66 26.61 0.96 0.11 1.76 2.04 1.39 0.09 14.93 26.01 40.95
0.30 0.30 36.45 10.76 25.69 0.70 0.20 1.67 1.98 1.09 0.19 15.97 25.46 41.44
0.39 0.32 36.29 11.65 24.64 0.51 0.30 1.60 1.91 0.83 0.33 16.05 25.42 41.47
0.48 0.35 35.93 12.44 23.49 0.37 0.41 1.55 1.84 0.61 0.50 15.80 25.73 41.53
0.55 0.37 35.32 13.04 22.28 0.27 0.51 1.52 1.78 0.44 0.67 15.57 26.12 41.69
0.62 0.40 34.58 13.66 20.92 0.19 0.61 1.50 1.73 0.32 0.85 15.45 26.41 41.86
0.71 0.44 33.02 14.46 18.57 0.12 0.76 1.47 1.66 0.19 1.11 15.49 26.23 41.72
0.81 0.51 30.28 15.47 14.82 0.05 0.95 1.46 1.59 0.08 1.43 15.89 24.11 40.00
0.91 0.67 25.24 16.80 8.43 0.02 1.17 1.46 1.51 0.02 1.83 16.83 16.36 33.19
0.97 0.83 21.31 17.58 3.72 0.00 1.29 1.45 1.47 0.00 2.05 17.56 8.00 25.56
1.00 1.00 18.14 18.14 0.00 0.00 1.44 1.44 1.44 0.00 2.20 18.14 0.00 18.14

45 2.50

40

35 2.00

30
P / kPa (T=45°C)

25 Column C 1.50
Column C
20 Column D
Column E
15 1.00
Column N
10 Column N

5
0.50
0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
x1 0.00
0.00 0.10 0.20
 y1 margules
0.00
0.18
0.28
0.36
0.39
0.39
0.38
0.37
0.37
0.37
0.40
0.51
0.69
1.00

Column F
Column G
Column H
Column I

0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00

 45

40

35

30
P / kPa (T=45°C)

Column C
25 Column C
Column D
20 Column E
Column N
Column N
15 Column L
Column M

10

0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0

x1
 x1 gamma1 gamma2 P y1 xl=0,75-y1/(x1-y1)
0.00 2.72 1.00 755.00 0.00
0.10 2.18 1.01 759.15 0.09 122.34
0.20 1.81 1.05 750.56 0.16 14.42 Equilibre
0.30 1.55 1.10 734.86 0.21 5.92
0.40 1.37 1.18 713.79 0.25 3.36 800.00
0.50 1.23 1.28 686.76 0.30 2.22
0.60 1.14 1.41 651.51 0.34 1.59 750.00
0.70 1.07 1.58 604.32 0.41 1.17
0.80 1.03 1.78 539.93 0.50 0.83 700.00
0.90 1.01 2.03 451.27 0.66 0.37
1.00 1.00 2.33 329.00 1.00 650.00
x1 gamma1 gamma2 P y1 y1=1,5-x1 xl=0,75-y1/(x1-y1) 600.00
0.85 1.02 1.90 499.16 0.57 0.65 0.64

P / mmHg
0.89 1.01 2.00 461.47 0.64 0.61 0.44
550.00
0.88 1.01 1.97 471.35 0.62 0.62 0.50
500.00

450.00

400.00

350.00

300.00
0.00 0.2
 Equilibre binaire présentant un azéotrope
800.00

750.00

700.00

650.00

600.00
P / mmHg

550.00 x1
y1
500.00

450.00

400.00

350.00

300.00
0.00 0.20 0.40 0.60 0.80 1.00
x1 ; y1
enthalpie de fusion 1 enthalpie de fusion 2
9910 19100
Tfusion1 Tfusion2
278.75 353.05

T1 lnxi xi T2 lnxi xi
278.75 0 1 353.05 0 1
278.5 -0.00383852 0.99616884 350 -0.056704683 0.94487307
278 -0.01153627 0.98853002 345 -0.151832211 0.85913242
277.5 -0.01926175 0.98092257 340 -0.249757608 0.77898958
277 -0.02701513 0.97334652 335 -0.350606151 0.70426107
276.5 -0.03479655 0.96580189 330 -0.45451071 0.63475847
276 -0.04260616 0.95828873 325 -0.561612332 0.57028883
275.5 -0.05044412 0.95080706 320 -0.672060881 0.51065509
275 -0.05831058 0.94335692 315 -0.786015732 0.45565664
274.5 -0.06620569 0.93593833 310 -0.903646547 0.40508978
274 -0.07412963 0.92855132 305 -1.025134109 0.35874835
273.5 -0.08208253 0.92119593 300 -1.150671257 0.3164243
273 -0.09006457 0.91387218 295 -1.280463901 0.27790835
272.5 -0.09807589 0.9065801 290 -1.414732154 0.24299069
272 -0.10611667 0.89931972 285 -1.553711573 0.21146166
271.5 -0.11418707 0.89209106 280 -1.697654544 0.1831125
271 -0.12228725 0.88489415 275 -1.846831804 0.15773611
270.5 -0.13041737 0.87772902 270 -2.001534148 0.13512782
270 -0.1385776 0.87059569 265 -2.162074316 0.11508615

370

350

330

310 Column E
Column A
290

270

250
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

370

350

330

310

290

270

250
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
310

290

270

250
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1-xi
0
0.05512693
0.14086758
0.22101042
0.29573893
0.36524153
0.42971117
0.48934491
0.54434336
0.59491022
0.64125165
0.6835757
0.72209165
0.75700931
0.78853834
0.8168875
0.84226389
0.86487218
0.88491385