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SIJIL TINGGI PERSEKOLAHAN MALAYSIA

MARK SGHEME (SKEMA PEMARKAHAN)

ftlaP /e

l
l

i
j
j

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,i

PAPER1 SGHEME

1D 2B 3D 4A 5C 6A 7B 8B 9D

21 C 22C 23D 24C 25A. 26D 27D 28D

29c
30D 31 A 32D 33D 34D 35D 36D 374 38A 39C 40D

10c
11A 128 13C 14C 15D 16D 178 184

41 D 429 43B 44C 45D 468 478 48D 494 50D

19c 20D

ITEM(JSl) JADUAL SPEFIKASI STPM 2OO9 PERCUBAAN PEPERIKSAAN JOHOR NEGERI Question No. Moderate No.of questions

No.

I oprc

eaS
1,46,43 5.6

Difficult

Mattter
of structure Atoms Electronic
Chemi c a l b o n d i n q

2
3,4,41
7,8 9, 10,20,42 11,12

4
a J

2
a J

2
z

5 6

7
I 9 I

kinetics Reaction lonicEquilibria Equilibria Chemical PhaseEquilibria

4
z

Electrochemistry Thermochemistry
13 Group 14 Group 15 Group Group17 d-Blockelements of Chemistry Carbon Hydrocarbon Haloalkanes Alcohols

14 44,45 18

0 Period3 and Group2

22
23

15 17 21

13 16

z 4

19
1 1 1 1 1 1 4 49 40
4

2
a J

4 5 6 8 9

27,29 28,47

24 25 26 31,48

37
?A

1
z
J

20 2l 22 23 24 25 26 27

compounds Carbonyl
acids carboxvlic acidsderivatives Carboxvlic Amines Amides

32,33
35

38 39

30 50 34 27

1 1

nitriles
rminoacids

rolymerisation
Totalno. of questions 15

1 50

Question1 (a) (i)

(1) (1)

+ (ii) (8X2X1/8) (6X2Xl12\=g

and gas exist and pressurevalueswhere solid,liquid set of temPerature (b) (i) A (1) equilibrium.

(ii)

Tamparaturs /bC

sketchof graPh' General axes. The correct The labellings.

(1) (1) ( 1)

(iii)becauseitstrip|epointoccursatapressureabovethenorma|atmospheric (1) pressure.

I(

@ (iv) PV= nRT o' =#

p = 5.50 x 8.31 x (24.0+273) x 10-3 kPa x 1 0 .0x1 0 -3 44.0 = 3 0 '9 kP a 124'6 kPa

(1)

(1) (1) Total:10 marks

Pt = 30.9 + 93.7 =

Question2 for answer the top line) (a)Ca2*(g 2e-+2Cl(g)(Thisis the only 1+ +2e- +Clz(g) Ca'*(g) Ca. (g)+ e- + Clz(g) essential) and (statesymbols electrons Ca(g)+ Clz(g) No te :C | zt o2C | c anbei nany ord e r b u t Ca m u s t b e in s e q u e n c e ) Max.3 marks ( 1) ( 1) ( 1) ( 1)

(1) ( b ) En th a l py offormati on=178 + 5 9 0 + 1 1 4 5 + ( 2 x 1 2 1 ) . ( 2 x 3 6 4 ) - 2 2 3 7 ( 1 ) = - 810kJ mol-1 + formation) EAH(hydration) (c)AH = -AH(lattice or numbers labels) (or cyclewithstatesymbols' = 2237- 1650- (2 x 364) = '141kJmol-1 = = of (d) Moles NHaCI 2t53'5 0'0374 = 0'561 = Heatabsorbed 15 x 0'0374 Q=m cA T = 2'6 (0'561x1000)/(50x4'2) (oC) LT = Q/m6'= mustbe at least2 sigfigs) answer units, to 2.1)canuse52; ignore 2.5 (allow = = 2O temPerature -2'6 17'4oC Final ans;mustbe < 20) previous lnnr*"r is for 20 first2 marks) Note;maynot usemoles(loses Af = (15x1000)/(50x4'2) so last2 outof first4' of So answers 71'4 and68'7 score wrongunits) penalise trffo* no unitsfor temperature' (1 )

(1 )

(1)

(1) (1)

Total: 10 marks

Question3 (a) 3s23p1 (b) (i) aluminium hydroxide (ii) Ar(oH)4(c) (i) whiteprecipitate Effervescence (ii)Al(HzO)o + HzO+ 13* + (d) (i) AlCle CH3CI + (ii) as lewisacid
A!(H2O)5(OH)12.+ AlCl+- + CH:* HsO*

(1) (1) (1) (1) (1) (1) (1) (1)

InAlClg,Al has an incomplete octetand accepts pairof electrons a fromthe Cl atomin CHgCI compound. actsas an and @ Alcl3is an electron-deficient
electron-pa acceptor. ir (e) light

(1) (1) Total= 10 marks

QuEstion 4 (a) (i) Ag*/silver

(1) (1)

(ii)

Carbonyl C = O or

(iii) Helpsto speedup the reaction/slow roomtemperature/flammable ) at (1 (iv) Propanal: silverminorformed Propanone: change/solution no remains colourless (b) (i) optical isomerism (1) (1) (1)

(iiXa) Hil
Nao-( O l-c
N^{-

ll

\ " / r ll
Ho

-c_N_=H
H cH.

(1)

(B)
HH

-(O Ho

,or-

L-l

ll -?--TH2* *

*6 i

Jr.

(1) (1) (1)

(c) (i) nucleophilic addition (ii)dry ether,roomtemperature

Total= {0 marks

Question5 by supplied one atom / (a) Lonepairdonated bothelectrons atom] or charge hydrogen missing fromN (to H.) [ignore ing inatebond cova dative/dative lent/coord molecules methane (b) Van derwaals ( or Vdw) forcesbetween (orVdWforcesin methane) and in.ammonia water bonding Hydrogen thanvanderWaalsforces bondsare stronger Hydrogen ( or VdWforcesare the weakest) O because hastwo lone thanammonia bondsin watermoreextensive Hydrogen (1) (N pairs one) (thanammonia)] [orWaterformsmoreH bondsper molecule than O because moreelectronegative N) (or H bondsin waterstronger O because - H bondmorepolarthanN - H) (or H bondsin waterstronger per in (c) (i)The change concentration unitof time Bothaxesmust be labetledto gain marksfor graph.y axisconc NOz and x axistime off. startsat originand levels Curve (1) (1) (1)
( 1) ( 1)

(1) (1) (1)

( 1)

graph does not leveloff then secondmark can be scoredfor a Note:tf candidates gradient. decreasing cuwe witha continuously (1) at the ratecan be foundby finding gradient t = 0 Initial may Note:Candidates score thismarkif theyhaveshownthison theirgraph + (ii) 2SOz Oz* 2SOs NO is a catalyst at it is regenerated the end of the reaction energy activation routeof lower provides alternative an (1) (1) (1) (1)

Total= 15 marks

Question6

in changes pH whena littleacidor baseis to has solution the ability resist (a) (i)A buffer (1) added The acidis usedup' pH remains withNHg' when a littleacidis added,it reacts
(1)

unchanged NHs + H*

(1)

wh e n a l i ttl ebas ei s added,i t r e a c t s wit h o H- ' T h e b a s e is u s e d u p ' p Hr e m a i n s

( 1)

unchanged NHa* + OH(ii) POH= 14.0 9'0 = 5'0

(1)

( 1) ( 1)

= logffi pOH PKu+

/ + 5.0= -logl.7x10-5log[NHa.l 0'10 = [NH+.] 0.17moldm-3 = x 450| 1000= 4'1S in of mass NH+CI 450 cm3 0'17x53'5 fromno' 1 to no' 3 or increases (b) (i) acidstrength downthe tableor of as number Cl increase effect dueto the electron-withdrawing or (atoms) of electronegativity chlorine the O-Hbond the stabilising anionor weakening NOTH* moreavailable

(1) (1 )

(1) (1 ) (1 )

(1) 4' so has lessinfluence atomis furtheraway(fromO-H)in no' (ii)chlorine = x = -PKa 1.259 10-3 [acid] or Ka 1Q (iii)either: = PKa- logro PH ( 1) = = (4.9+ 2) [H.]= {(Ka' c) 3'55x 1oa ( 1) pH = 3.4 = 3.4(allow 3.5) & expression values; Note: [1]for correct working [1]for correct Total = 15 marks

Question7 (a) (i) lncrease (ii) Colourless solution turnsto a brownsolution/ blackppt (needbothcolours) + Cl2+ 2Kl -) 12 2 KCI Clzis an oxidising agent ' (iii) Add silver nitrate solution ppt KBrformscreamy yellow ppt Kl forms + AgNOg KBr-+ AgBr+ KNO. or + AgNOg Kl -> Agl + KNOg or ionic equations Thenadd(dilute conc) or ammonia AgBr/creamppt dissolves concNH3 in or slightly dissolves dilute in NHs Agl is insoluble dilute concNH3 in or (1)

(1) (1) (1) (1) (1) (1) (1) (1) (1) (1) (1)

(b) SiCIoreacts/hydrolyses, doesnot CClt statedand notjust implied] [Thismustbe clearly pairof electrons (lone) (fromthe oxygen atom)in a watermolecule cannot forma bondwith/be donated the C atom to Or cannot accepted C atom be by

(1) (1)

because has no available C orbital OR no 3d orbitalsin C ORC is a small atom'surroundedCl atoms by OR Cl atomsare largeand surround atom(so attackis sterically C hindered) (1) RejectsCCI+ has no d orbitals Si has(available) orbitals 3d Rejects SiCl4 available orbitals has 3d (1)

Question8 formedfor bariumnitrate (a) whiteprecipitate nitrate no visiblechangefor magnesium ) HzSO+(ag)+Ba(NOs\z Ba2*(aq) + SOa2-(aq) BaSOaG) + 2HNOs(aq) @ BaSO+(s)

(1) (1)

(1) (1) (1) (1)

(1)

(b) ionicsizeof Mg2* Ba2* ' >> energyof Mg2* Ba2* of magnitude hydration and Ba2* Mg2* >> ionicsizeof SOa2- size of cations morethan Basoe slightly latticeenergyfor MgSOa magnitude'of
= AHsolution -AHl"tti"" AHnvdration

ForMgSoa,AHsoution=Xothermic;ForBaSo+,AHsotution=endothermic;.(1) (1) sulphate soluble in sulphate insoluble water; magnesium barium

(c)(i) (K"p=) lMgt-tt^ott1

'units are mol3dm-e

(1) (1)

= = [^M!tt] t (ii)LettMg(oFl)z(?.q)l
' =4 Ks P=2 x1 0 -1 1 x3 x = 1.7 1 x 1 0 a mo l d m-3

(1) (1)

' ioneffect of (iii) lesst?Hb]":: rcause the common ,*(aq)+ 2oH-(aq1 moved,tothe teft + lrag(oH)z(s) Mg'-(aq) zuil' (aq'is or theequilibrium (1)
I

Total= 15 marks

to

Question 9 (a) (i)

| H o - + t-)-cr -> I " o --/\-"' H' lHHl

L_l (1) substitution nucleophilic bimolecular (ii)

cH 3 c H 2 \

cH.cH" I "r-

," Ho -c -H

cH"cH"
+ Cl-

I"-

\ .H

(1) ( 1) (1) ( 1) (1)

rateincreases. atomicsize of BPCI ' breakthan G-Clbond Hencethe c-Br bsnd is weakerand is easierto (1) reflux + NaOH(aq) CHiCH2CFlzCl conc.HzSOa (1)
CHgCHzCHzOH

(iii)

-l (1)
CH2 CH3CH= ( 1) CHgCHCICHg ( 1)

18ooc
HCI -+

CH2 + CH3CH= (b)

Tr H,N-f-fi-T-f-cffiFI
ff{, ETI o i{ cll2CItl {:#CINH- agein per:atise

t3

E{

( 1)

TI

H.N-C-ql.i-{-C(l0i{ Ctlz0tt O H CHs prnalise palvmer'both tirnes

( 1) (1)

or (ii) serylalanine alanYlserine

(iii)
fl

EI3C-q-s-c+-ic-cooH

I
I

ill

+rI
c-0
ffl*3

( 1)

t(

Total = 15 marks

Question10 solution theyare ketones reactwith Fehling's They'don't AandBgivespositiveiodoformtest-theyhavethestructure CHgC=O ormethYlketone I to compared B pointof A > B - A is lessbranched Boiling A is CHgCOCHzCHzCHg B is CHgCOCH(CHg)z a,: CHgCHzCgCl-l2CHa (1) ( 1) ( 1) (1) (1)

solution - they afe ddehydes testwith Fehlingls D and E gives,6,positive of active.Henceisomers D are D is optically
CH.CH" I

--' / Hrct / , CHO

\,

(2) (1) ( 1) ( 1) (3)

NO^

F of Reduction E givesa longchaincompound' E is CHgCHzCHzCHzCHO F is CHgCHzCHzCHzCHzOH oxide (rejectCu2O) P is copper(l) of Examples equations:

*r.cHrcHrb=o .

9H.

HTNNHIO)-No,

Yi

-->

HrO cH3cH2cHrC+rr'ftr-Q) - NO2+

9H.

!----'

l, CH.CH2CHTCOCHT+ + NaOH -_--->

cHl. + cH3cH2cH2cooTotal = 15 marks

lL