COSY – HSQC – HMBC

1
COSY

2
3
4
5
 HSQC

OH COOCH3

6
O

OH COOCH3

7
O

OH COOCH3

8
 6.8
6.669
0.99 6.602

6.6
HO
1.00 6.579
6.566

6.4
6.544

6.2
6.0
5.8
5.542
5.538
OH

5.6
1.01 5.520
5.515

5.4
5.183
5.179

5.2
1.01
5.148
5.143

5.0
2.242

4.8
2.3
3.3

3.311
2.222
3.302

4.6
2.216
3.2

3.288

2.2
2.209
3.279

4.4
3.1

2.184
2.172

4.2
2.1
3.0

1.916

4.0
1.901 2.804
f1 (ppm)

2.0
1.889 2.793
f1 (ppm)
2.9 2.8

1.874 2.769

f1 (ppm)
1.828

3.8 3.6
2.758
2.7

1.9

1.819 3.311

3.4
1.810 2.611 3.302
2.6

1.08
1.802 2.595 3.288
1.8

3.2
1.795 3.279
2.5

2.588
1.779 2.572

3.0
2.804
2.8 1.05 2.793
2.769
2.758
2.6

1.15
2.595
2.588
2.4

1.32 2.572
2.184
2.2

2.97 2.172
1.916
2.0

1.26 1.901
1.47 1.889
1.8

1.15 1.874
2.37
1.6
1.4

1.66
1.2

3.68 1.200
9

3.10 1.060
1.0

3.72 0.883
0.8
 160
156.191
151.974
147.985

150
HO
139.261

140
137.700
135.579

130
125.332
125.329
OH

119.725

120
119.535
119.019

109.541

110
100
90
f1 (ppm)
80
78.916

70
60
CRT8-CDCL3-13C

50

49.306
40

38.834
37.492
29.855
29.592
30

28.259
28.200
24.808
20

19.244
15.357
13.012
10
10
 0

10

20

30

40

50

60

70

80

90

100

110

120

130

140

7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5
f2 (ppm)

11
 0

10

20

30

40

50

60

70

80

f1 (ppm)
90

100

110

120

130

140

150

160

170

7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0
f2 (ppm)

12
OH

H
O
O

13
OH

H
O
O

14
OH

H
O
O

15
OH

H
O
O

16
 OH

4.4//74 + O
20CH3
4.1//67 3.4//68 19CH3
HO 11CH3
O
3.4//68

4.4//74
4.1//67

17
 123
114=> C-SP2
+ 160 194 44/41/40
19CH3//1.8 20/19/11
14
138
C-O:
20CH3//1.3 64/67/68/74
114
11CH3//1.2

18
 20CH3-
19CH3-
11CH3-
41CH2
40 64 44CH
44CH
41CH2
40IV
C-O:
64/67/68/74
67/68/74

19
 4.1//67

3.4//68
4.4//74
44CH
41CH2
67/68/74 40IV
20
19
11

20
5.6

20CH3//1.3
19CH3//1.8
11CH3//1.2
114-CH2

123-CH

21
22
 O 176 O
1 74
4
73 3
58 SP3: 73/74 – O
2
HO 5
136/130 58-IV
SP2: 176/136/130 8
32/27 6 32/27
7

23
 1
H

13
C

24
6.1 // 138