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Tarea 111111 Final
Tarea 111111 Final
casi 3 o 4
T oC A B ai
25 0.509 3.28E+07 4.00E-08
15 0.5 3.26E+07
0 0.488 3.24E+07
Constantes de carbonato
T oC pKH pKa,1 pKa,2 pKso p(Kso/Ka,2)
5 1.2 6.52 10.56 8.09 -2.47
10 1.27 6.46 10.49 8.15 -2.34
15 1.34 6.42 10.43 8.22 -2.21
20 1.41 6.38 10.38 8.28 -2.1
25 1.47 6.35 10.33 8.34 -1.99
40 1.64 6.3 10.22 8.51 -1.71
60 1.8 6.3 10.14 8.74 -1.4
Ecuación de Antoine:
B
ln Pv A
C T
ln Pv A B
C T
Pv = (Kpa)
T= oK
Sustancia A B C
H2O 16.2886 3816.44 -46.13
|𝐻^+ || 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/|
〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 | = 𝐾_(𝑎,1)
(𝐾_1^´)/ 1/𝐾_𝑚 ≫1
(1+1/𝐾_𝑚 )=
𝐾_(𝑎,1)
T=
pKa,1 1.99 Ka,1 = 0.010233
pKa,2 10.22 Ka,2= 6E-11
Kw= 1E-14
pC = 3 0.001
Sistema cerrado
1 2 3 4 5 6 7 8 9 10 11 12 13 14
0
2
H2CO3
CT
C
p
CO2,ac
4
10
12
14
Funciones
𝑓(𝑥,𝑦,𝑧)= |𝐻^+ || 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2
𝐶𝑂 〗 ^∗ 〗 _3 | − 𝐾_(𝑎,1)
ℎ(𝑥,𝑦,𝑧)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ |
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Derivadas de las funciones
𝑓´𝑥=−|𝐻^+ || 〖〖𝐻𝐶 𝑔´𝑥=0 ℎ´𝑥=1
𝑂〗 ^− 〗 _3 |/|
〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3
|^2 |𝐻^+ |/|
𝑓´𝑦= 𝑔´𝑦=−|𝐻^+ || ℎ´𝑦=1
〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 | 〖〖𝐶𝑂〗 ^= 〗 _3 |/|
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 ||
𝑓´𝑧=0 𝑔´𝑧=𝐻𝐶𝑂
〖〖 〗|/|
|𝐻^+ 〗 𝐻𝐶
^−〖〖 _3 | ℎ´𝑧=1
𝑂〗 ^− 〗 _3 |
Ka,1 = 0.010233
Ka,2= 6E-11
CT = 0.001
H= 0.04
H2CO3 0.001
HCO3 = 3.16E-07
CO3= 1E-15
Matriz
A(1,1) = -0.01265 -0.012649 40 0 0.01022
A(1,2) = 40 0 -0.0004 126491.1 -6.62E-11
A(1,3) = 0 1 1 1 -3.16E-07
A(1,4) = 0.01022
A(2,1) = 0 Minversa
A(2,2) = -0.0004 -2.5E-02 -7.9E-06 1.0E+00
A(2,3)= 126491 2.5E-02 -2.5E-09 3.2E-04
A(2,4) = -6.6E-11 7.9E-11 7.9E-06 1.0E-12
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = -0.000256
A(3,4) = -3.2E-07 ΔHCO3 = 0.000255
ΔCO3 = 8.072E-13
H2CO3 0.000744 E1 = 0.343621
HCO3 0.000256 E2 = 0.998763
CO3 8.082E-13 E3 = 0.998763
H2CO3 0.000744
HCO3 = 0.000256
CO3= 8.08E-13
Matriz
A(1,1) = -18.4678 -18.46784 53.74483 0 -0.003512
A(1,2) = 53.74483 0 -4.94E-07 156.4074 -6.62E-11
A(1,3) = 0 1 1 1 0
A(1,4) = -0.00351
A(2,1) = 0 Minversa
A(2,2) = -4.9E-07 -1.4E-02 -4.8E-03 7.4E-01
A(2,3)= 156.4074 1.4E-02 -1.6E-03 2.6E-01
A(2,4) = -6.6E-11 4.4E-11 6.4E-03 8.1E-10
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 4.863E-05
A(3,4) = 0 ΔHCO3 = -4.86E-05
ΔCO3 = -5.77E-13
H2CO3 0.000793 E1 = 0.061336
HCO3 0.000207 E2 = 0.234816
CO3 2.316E-13 E3 = 2.49027
H2CO3 0.000793
HCO3 = 0.000207
CO3= 2.32E-13
Matriz
A(1,1) = -13.1775 -13.17753 50.44834 0 -0.000215
A(1,2) = 50.44834 0 -2.16E-07 193.1344 1.553E-11
A(1,3) = 0 1 1 1 0
A(1,4) = -0.00022
A(2,1) = 0 Minversa
A(2,2) = -2.2E-07 -1.6E-02 -4.1E-03 7.9E-01
A(2,3)= 193.1344 1.6E-02 -1.1E-03 2.1E-01
A(2,4) = 1.55E-11 1.8E-11 5.2E-03 2.3E-10
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 3.386E-06
A(3,4) = 0 ΔHCO3 = -3.39E-06
ΔCO3 = 7.665E-14
H2CO3 0.000796 E1 = 0.004252
HCO3 0.000204 E2 = 0.016618
CO3 3.082E-13 E3 = 0.248683
H2CO3 0.000796
HCO3 = 0.000204
CO3= 3.08E-13
Matriz
A(1,1) = -12.8521 -12.85214 50.23385 0 -9.16E-07
A(1,2) = 50.23385 0 -2.97E-07 196.344 -2.58E-13
A(1,3) = 0 1 1 1 0
A(1,4) = -9.2E-07
A(2,1) = 0 Minversa
A(2,2) = -3E-07 -1.6E-02 -4.1E-03 8.0E-01
A(2,3)= 196.344 1.6E-02 -1.0E-03 2.0E-01
A(2,4) = -2.6E-13 2.4E-11 5.1E-03 3.1E-10
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 1.452E-08
A(3,4) = 0 ΔHCO3 = -1.45E-08
ΔCO3 = -1.34E-15
H2CO3 0.000796 E1 = 1.823E-05
HCO3 0.000204 E2 = 7.126E-05
CO3 3.069E-13 E3 = 0.004356
H2CO3 0.000796
HCO3 = 0.000204
CO3= 3.07E-13
Matriz
A(1,1) = -12.8508 -12.85075 50.23293 0 -1.67E-11
A(1,2) = 50.23293 0 -2.96E-07 196.358 1.84E-17
A(1,3) = 0 1 1 1 0
A(1,4) = -1.7E-11
A(2,1) = 0 Minversa
A(2,2) = -3E-07 -1.6E-02 -4.1E-03 8.0E-01
A(2,3)= 196.358 1.6E-02 -1.0E-03 2.0E-01
A(2,4) = 1.84E-17 2.4E-11 5.1E-03 3.1E-10
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 2.647E-13
A(3,4) = 0 ΔHCO3 = -2.65E-13
ΔCO3 = 9.329E-20
H2CO3 0.000796 E1 = 3.324E-10
HCO3 0.000204 E2 = 1.299E-09
CO3 3.069E-13 E3 = 3.04E-07
H2CO3 0.000796
HCO3 = 0.000204
CO3= 3.07E-13
Matriz
A(1,1) = -12.8508 -12.85075 50.23293 0 0
A(1,2) = 50.23293 0 -2.96E-07 196.358 0
A(1,3) = 0 1 1 1 0
A(1,4) = 0
A(2,1) = 0 Minversa
A(2,2) = -3E-07 -1.6E-02 -4.1E-03 8.0E-01
A(2,3)= 196.358 1.6E-02 -1.0E-03 2.0E-01
A(2,4) = 0 2.4E-11 5.1E-03 3.1E-10
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 0
A(3,4) = 0 ΔHCO3 = 0
ΔCO3 = 0 2
H2CO3 0.000796 E1 = 0
HCO3 0.000204 E2 = 0
CO3 3.069E-13 E3 = 0
CO3= 1E-15 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = 0.000744
Uf = 0.000256
Tf = 8.082E-13
A(1,1) = #REF! #REF! -0.000744 0 #REF!
A(1,2) = -0.000744 #REF! -1 #REF! #REF!
A(1,3) = 0 #REF! 0 #REF! #REF!
A(1,4) = #REF!
A(2,1) = #REF! Minversa
A(2,2) = -1 #REF! #REF! #REF!
A(2,3)= #REF! #REF! #REF! #REF!
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
γ(T) = #REF! Resultados
δ(T) = #REF! #REF!
ϐMf #REF! #REF!
γUf = #REF! #REF!
δTf = #REF! Mf = #REF! #REF!
A(3,1) = #REF! Uf = #REF! #REF!
A(3,2) = 0 Tf = #REF! #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 1E-15 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,1) = #REF! #REF! #REF! 0 #REF!
A(1,2) = #REF! #REF! -1 #REF! #REF!
A(1,3) = 0 #REF! 0 #REF! #REF!
A(1,4) = #REF!
A(2,1) = #REF! Minversa
A(2,2) = -1 #REF! #REF! #REF!
A(2,3)= #REF! #REF! #REF! #REF!
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
γ(T) = #REF! Resultados
δ(T) = #REF! #REF!
ϐMf #REF! #REF!
γUf = #REF! #REF!
δTf = #REF! Mf = #REF! #REF!
A(3,1) = #REF! Uf = #REF! #REF!
A(3,2) = 0 Tf = #REF! #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 1E-15 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,1) = #REF! #REF! #REF! 0 #REF!
A(1,2) = #REF! #REF! -1 #REF! #REF!
A(1,3) = 0 #REF! 0 #REF! #REF!
A(1,4) = #REF!
A(2,1) = #REF! Minversa
A(2,2) = -1 #REF! #REF! #REF!
A(2,3)= #REF! #REF! #REF! #REF!
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
γ(T) = #REF! Resultados
δ(T) = #REF! #REF!
ϐMf #REF! #REF!
γUf = #REF! #REF!
δTf = #REF! Mf = #REF! #REF!
A(3,1) = #REF! Uf = #REF! #REF!
A(3,2) = 0 Tf = #REF! #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 1E-15 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,1) = #REF! #REF! #REF! 0 #REF!
A(1,2) = #REF! #REF! -1 #REF! #REF!
A(1,3) = 0 #REF! 0 #REF! #REF!
A(1,4) = #REF!
A(2,1) = #REF! Minversa
A(2,2) = -1 #REF! #REF! #REF!
A(2,3)= #REF! #REF! #REF! #REF!
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
γ(T) = #REF! Resultados
δ(T) = #REF! #REF!
ϐMf #REF! #REF!
γUf = #REF! #REF! error
δTf = #REF! Mf = #REF! #REF!
A(3,1) = #REF! Uf = #REF! #REF!
A(3,2) = 0 Tf = #REF! #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 1E-15 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,1) = #REF! #REF! #REF! 0 #REF!
A(1,2) = #REF! #REF! -1 #REF! #REF!
A(1,3) = 0 #REF! 0 #REF! #REF!
A(1,4) = #REF!
A(2,1) = #REF! Minversa
A(2,2) = -1 #REF! #REF! #REF!
A(2,3)= #REF! #REF! #REF! #REF!
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
γ(T) = #REF! Resultados
δ(T) = #REF! #REF!
ϐMf #REF! #REF!
γUf = #REF! #REF!
δTf = #REF! Mf = #REF! #REF!
A(3,1) = #REF! Uf = #REF! #REF!
A(3,2) = 0 Tf = #REF! #REF!
A(3,3) = #REF!
A(3,4) = #REF!
H = 10 ^ (-pH)
H2CO3 = 10 ^ -15
HCO3 = 10 ^ -6.5
CO3 = 10 ^ -3
CT = 10 ^ -2
A(1, 1) = -H * HCO3 / H2CO3 ^ 2
A(1, 2) = H / H2CO3
A(1, 3) = 0
A(1, 4) = -(H * HCO3 / H2CO3 - K1)
A(2, 1) = 0
A(2, 2) = -H * CO3 / HCO3 ^ 2
A(2, 3) = H / HCO3
A(2, 4) = -(H * CO3 / HCO3 - K2)
A(3, 1) = 1
A(3, 2) = 1
A(3, 3) = 1
A(3, 4) = -(H2CO3 + HCO3 + CO3 - CT)
0.01 0.00049 0.000506 3.047483E-12 1.00E-12
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10
𝑔(𝑥,𝑦)=𝑦+ 3𝑥𝑦^2−57
X= 3
Y= 6
A(1,1) = 12 12 3 -17
A(1,2) = 3 108 109 -273
A(1,3) = -17
A(2,1) = 108 Minversa
A(2,2) = 109 0.1107723577 -0.00304878
A(2,3)= -273 -1.1E-01 1.2E-02
Resultados
-1.050813008
-1.463414634
error
X= 1.9491869919 1.0508130081
y= 4.5365853659 1.4634146341
X= 1.94919
Y= 4.53659
A(1,1) = 8.43496 8.4349593496 1.9491869919 -2.641983112
A(1,2) = 1.94919 61.741820345 54.055919096 -67.88293844
A(1,3) = -2.64198
A(2,1) = 61.7418 Minversa
A(2,2) = 54.0559 0.1610661644 -0.005807839
A(2,3)= -67.8829 -1.8E-01 2.5E-02
Resultados
-0.031280912
-1.220062466
error
X= 1.9179060796 0.0312809122
y= 3.3165228995 1.2200624663
X= 1.91791
Y= 3.31652
A(1,1) = 7.15234 7.1523350588 1.9179060796 -0.039143162
A(1,2) = 1.91791 32.997972429 39.164676593 -9.603534836
A(1,3) = -0.03914
A(2,1) = 32.998 Minversa
A(2,2) = 39.1647 0.1806223192 -0.00884513
A(2,3)= -9.60353 -1.5E-01 3.3E-02
Resultados
0.0778743824
-0.310821705
error
X= 1.995780462 0.0778743824
y= 3.0057011944 0.3108217051
X= 1.99578
Y= 3.0057
A(1,1) = 6.99726 6.9972621184 1.995780462 0.0181406289
A(1,2) = 1.99578 27.102719009 36.992318311 -0.096778262
A(1,3) = 0.01814
A(2,1) = 27.1027 Minversa
A(2,2) = 36.9923 0.180667248 -0.009747217
A(2,3)= -0.09678 -1.3E-01 3.4E-02
Resultados
0.0042207362
-0.005708528
error
X= 2.0000011983 0.0042207362
y= 2.9999926662 0.0057085281
X= 2
Y= 2.99999
A(1,1) = 7 6.9999950628 2.0000011983 6.279577E-06
A(1,2) = 2 26.999867992 36.999933564 0.0002389958
A(1,3) = 6.28E-06
A(2,1) = 26.9999 Minversa
A(2,2) = 36.9999 0.1804878471 -0.009756123
A(2,3)= 0.00024 -1.3E-01 3.4E-02
Resultados
-1.198285E-06
7.333778E-06
error
X= 2 1.198285E-06
y= 3 7.333778E-06
Sistema abierto
Equilibrios Funciones
𝐾_𝐻= | 〖𝐶𝑂〗 _(2(𝑎𝑐)) |/𝑃_( 〖𝐶𝑂〗 _2 )
〖𝐶𝑂〗 _2(𝑔) ⇄ 〖𝐶𝑂〗 _(2(𝑎𝑐)) 𝐾_𝐻= 10^(−1,5)
𝐾_(𝑎,1)=|𝐻^+ || 〖〖𝐻𝐶
𝐻_2 〖𝐶𝑂〗 _3^∗ ⇄ 𝐻^++ 〖𝐻𝐶𝑂〗 _3^− 𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2
𝐾_(𝑎,1)= 10^(−6,3)
𝐶𝑂 〗 ^∗ 〗 _3 |
𝐾_(𝑎,2)= |𝐻^+ || 〖〖𝐶𝑂〗
〖𝐻𝐶𝑂〗 _3^− ⇄ 𝐻^++ 〖𝐶𝑂〗 _3^(−2) 𝐾_(𝑎,2)= 10^(−10,3)
^= 〗 _3 |/|
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |
Balance de masa
Solución
1 2 3 4 5 6 7 8 9 10 11 12 13 14
0
2
CT
CO2,ac
4
C
p
6
HCO3
8
pOH pH
10
CO3
12
14
A(1, 1) = H / H2CO3
A(1, 2) = 0
A(1, 3) = -(H * HCO3 / H2CO3 - K1)
H= 6.3E-11 10.2
H2CO3= 0.00012
HCO3 1E-20
CO3 1E-15
Matriz
A(1,1) = 5.48E-07 5.48E-07 0 4.47E-07
A(1,2) = 0 -6E+14 6.3E+09 -6E-06
A(1,3) = 4.47E-07 Minversa Mmult
A(2,1) = -6E+14 1825908 3.52E-31 ΔHCO3 = 0.8156 HCO3 = 0.8156
A(2,2) = 6.3E+09 1.8E+11 1.58E-10 ΔCO3 = 81560.3 CO3 = 81560.3
A(2,3) = -6E-06 E1 = 1.0000
E2 = 1.0000
HCO3 0.8156
CO3 81560.3
Matriz
A(1,1) = 5.48E-07 5.48E-07 0 5.29E-23
A(1,2) = 0 -8E-06 7.74E-11 -6E-06
A(1,3) = 5.29E-23 Minversa Mmult
A(2,1) = -8E-06 1825908 0 ΔHCO3 = 9.67E-17 HCO3 = 0.8156
A(2,2) = 7.74E-11 1.8E+11 1.3E+10 ΔCO3 = -81560 CO3 = 0.60461
A(2,3) = -6E-06 E1 = 1.4E-16
E2 = 1.3E+05
HCO3 0.8156
CO3 0.60461
Matriz
A(1,1) = 5.48E-07 5.48E-07 0 0
A(1,2) = 0 -6E-11 7.74E-11 -7E-22
A(1,3) = 0 Minversa Mmult LOgC
A(2,1) = -6E-11 1825908 0 ΔHCO3 = 0 HCO3 = 0.8156 0.08852
A(2,2) = 7.74E-11 1353564 1.3E+10 ΔCO3 = -9E-12 CO3 = 0.60461 0.21852
A(2,3) = -7E-22 E1 = 0.0000
E2 = 0.0000
HCO3 0.8156
CO3 0.60461
Matriz
A(1,1) = 5.48E-07 5.48E-07 0 0
A(1,2) = 0 -6E-11 7.74E-11 1.29E-26
A(1,3) = 0 Minversa Mmult LOgC
A(2,1) = -6E-11 1825908 0 ΔHCO3 = 0 HCO3 = 0.8156 0.08852
A(2,2) = 7.74E-11 1353564 1.3E+10 ΔCO3 = 1.67E-16 CO3 = 0.60461 0.21852
A(2,3) = 1.29E-26 E1 = 0.0000
CT 1.42033 E2 = 0.0000
Sistema de carbonatos abierto sin sólidos
1 2 3 4 5 6 7 8 9 10 11 12 13 14
0
2
CT
CO2,ac
4
C
p
6
HCO3
8
pOH pH
10
CO3
12
14
T=
pKa,1 6.3 Ka,1 = 5.0119E-07
pKa,2 10.3 Ka,2= 5.0119E-11
Kw= 1E-14
pC = 3 c= 1.00E-03 M (esta condición es del río)
Cb = 2 c= 1.00E-02 M (esta condición es del contaminante)
Funciones
x, y, z, w
Matrices
H= 1.00E-03
H2CO3 1.00E-03
HCO3 = 1.00E-06
CO3= 1.00E-08
A(1,4) = 0 0 1 1 1 -1.01E-06
A(1,5) = -4.99E-07
A(2,1) = 1.00E-02
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 0.00800576
A(4,2) = 1
H= 9.01E-03
H2CO3 1.01E-03
HCO3 = -7.50E-06
CO3= -1.65E-07
A(1,4) = 0 0 1 1 1 0
A(1,5) = 6.75E-05
A(2,1) = 2.20E-02
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 8.284906E-06
A(3,4) = 2 ΔH2CO3 = -7.95194E-06
A(4,2) = 1
H= 9.01E-03
H2CO3 1.00E-03
HCO3 = 1.22E-07
CO3= 1.68E-07
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -6.00E-07
A(2,1) = 1.37E+00
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -5.85027E-07
A(4,2) = 1
A(4,3) = 1 H 9.01E-03 2.045108479 0%
H= 9.01E-03
H2CO3 1.00E-03
HCO3 = 5.56E-08
CO3= -9.14E-08
A(1,4) = 0 0 1 1 1 0
A(1,5) = -2.34E-10
A(2,1) = -1.64E+00
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.828654E-07
A(4,2) = 1
H= 9.01E-03
H2CO3 1.00E-03
HCO3 = 5.56E-08
CO3= 5.48E-11
A(1,3) = 9.01E+00 -1 0 1 2 0
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.73E-14
A(2,1) = 9.85E-04
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.09561E-10
A(4,2) = 1
H= 9.01E-03
H2CO3 1.00E-03
HCO3 = 5.56E-08
CO3= 3.16E-16
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 2.22E-21
A(2,1) = 5.69E-09
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.46376E-17
A(4,2) = 1
CO3 3.09E-16 2%
H= 9.01E-03
H2CO3 1.00E-03
HCO3 = 5.56E-08
CO3= 3.09E-16
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 0.00E+00
A(2,1) = 5.56E-09
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.73472E-18
A(4,2) = 1
CO3 3.09E-16 0%
Pcb = 2 pH = 2.0E+00
pCB pH =7 pH =7
Cb pH
2.00 2.045099673
0.00 0
0.00 0
0.00 0
0.00 0
0.00 0
Chart Title
9
Cb pH =7 pH =8
7
2 2.038304129 2.043665453
3 3.591602496 3.205110251 6
4.00 6.740763232 5.27207545
5
5.00 6.969570621 7.848171794
2
2 3 4 5 6 7 8
Column B Column C
3
2
2 3 4 5 6 7 8
Column B Column C
CO3= 1E-08 0 0 0 0
Mf = -1.75027E-07
Uf = 0
Tf = 0.00900576
A(1,4) = #REF!
ϐ(T) = #REF!
A(3,4) = #REF!
CO3= 1E-08 0 0 0 0
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,4) = #REF!
A(2,1) = #REF! Minversa
ϐ(T) = #REF!
A(3,4) = #REF!
CO3= 1E-08 0 0 0 0
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,1) = #REF! #REF! #REF! 0 #REF!
A(1,4) = #REF!
ϐ(T) = #REF!
γ(T) = #REF! Resultados
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 1E-08 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = #REF!
Uf = #REF! X=
Tf = #REF! Y=
A(1,1) = #REF! #REF! #REF! 0 #REF! A(1,1) =
A(1,2) = #REF! #REF! -1 #REF! #REF! A(1,2) =
A(1,3) = 0 #REF! 0 #REF! #REF! A(1,3) =
A(1,4) = #REF! A(2,1) =
A(2,1) = #REF! Minversa A(2,2) =
A(2,2) = -1 #REF! #REF! #REF! A(2,3)=
A(2,3)= #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
Uf = #REF!
Tf = #REF! X=
A(1,1) = #REF! #REF! #REF! 0 #REF! Y=
A(1,2) = #REF! #REF! -1 #REF! #REF! A(1,1) =
A(1,3) = 0 #REF! 0 #REF! #REF! A(1,2) =
A(1,4) = #REF! A(1,3) =
A(2,1) = #REF! Minversa A(2,1) =
A(2,2) = -1 #REF! #REF! #REF! A(2,2) =
A(2,3)= #REF! #REF! #REF! #REF! A(2,3)=
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 3 c= 1.00E-03 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
Matrices
H= 1.00E-03
H2CO3 1.00E-03
HCO3 = 1.00E-06
CO3= 1.00E-08
A(1,4) = 0 0 1 1 1 -1.01E-06
A(1,5) = -4.99E-07
A(2,1) = 1.00E-02
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -0.000984899
A(4,2) = 1
H= 1.51E-05
H2CO3 9.99E-04
HCO3 = 1.48E-06
CO3= 1.47E-08
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 4.79E-07
A(2,1) = 9.90E-03
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 2.922118E-05
A(3,4) = 2 ΔH2CO3 = -2.89805E-05
A(4,2) = 1
H= 4.43E-05
H2CO3 9.70E-04
HCO3 = 3.02E-05
CO3= 2.56E-07
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = -8.81E-07
A(2,1) = 8.47E-03
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.15775E-05
A(4,2) = 1
A(4,3) = 1 H 3.27E-05 4.484861215 26%
H= 3.27E-05
H2CO3 9.81E-04
HCO3 = 1.92E-05
CO3= -2.64E-08
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.40E-07
A(2,1) = -1.37E-03
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.57824E-06
A(4,2) = 1
H= 3.02E-05
H2CO3 9.83E-04
HCO3 = 1.66E-05
CO3= 1.57E-09
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = -7.28E-09
A(2,1) = 9.47E-05
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.53457E-07
A(4,2) = 1
H= 3.00E-05
H2CO3 9.84E-04
HCO3 = 1.64E-05
CO3= 2.13E-11
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -2.46E-11
A(2,1) = 1.30E-06
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -5.07194E-10
A(4,2) = 1
H= 3.00E-05
H2CO3 9.84E-04
HCO3 = 1.64E-05
CO3= 2.74E-11
A(1,4) = 0 0 1 1 1 0
A(1,5) = -2.81E-16
A(2,1) = 1.67E-06
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -5.9989E-15
A(4,2) = 1
CO3 2.74E-11 0%
Pcb = 3 pH = 4.5E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 4 c= 1.00E-04 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
Matrices
H= 1.00E-07
H2CO3 1.00E-04
HCO3 = 1.00E-05
CO3= 1.00E-06
A(1,4) = 0 0 1 1 1 8.89E-04
A(1,5) = 4.91E-07
A(2,1) = 1.00E-01
A(3,1) = -2.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.93118E-06
A(4,2) = 1
H= -1.83E-06
H2CO3 2.06E-04
HCO3 = 7.05E-04
CO3= 8.88E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 6.76E-06
A(2,1) = 1.26E-01
A(3,1) = -1.00E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.95223E-06
A(3,4) = 2 ΔH2CO3 = 1.081189E-06
A(4,2) = 1
CO3 9.39E-05 6%
H= 1.21E-07
H2CO3 2.07E-04
HCO3 = 6.99E-04
CO3= 9.39E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 9.32E-08
A(2,1) = 1.34E-01
A(3,1) = -1.68E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.60594E-08
A(4,2) = 1
A(4,3) = 1 H 9.50E-08 7.022310938 22%
H= 9.50E-08
H2CO3 1.50E-04
HCO3 = 8.14E-04
CO3= 3.60E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.58E-08
A(2,1) = 4.42E-02
A(3,1) = -2.11E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.40022E-08
A(4,2) = 1
H= 7.10E-08
H2CO3 1.25E-04
HCO3 = 8.63E-04
CO3= 1.17E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.24E-08
A(2,1) = 1.35E-02
A(3,1) = -2.98E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -5.4316E-09
A(4,2) = 1
H= 6.56E-08
H2CO3 1.15E-04
HCO3 = 8.83E-04
CO3= 1.77E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.29E-10
A(2,1) = 2.01E-03
A(3,1) = -3.33E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -7.8197E-10
A(4,2) = 1
H= 6.48E-08
H2CO3 1.14E-04
HCO3 = 8.85E-04
CO3= 7.00E-07
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.58E-11
A(2,1) = 7.91E-04
A(3,1) = -3.38E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -8.96701E-12
A(4,2) = 1
CO3 6.85E-07 2%
Pcb = 4 pH = 7.2E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 5 c= 1.00E-05 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
Matrices
H= 1.00E-08
H2CO3 1.00E-07
HCO3 = 1.00E-06
CO3= 1.00E-07
A(1,4) = 0 0 1 1 1 9.99E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-01
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 2.05645E-07
A(4,2) = 1
H= 2.16E-07
H2CO3 8.50E-05
HCO3 = 8.34E-04
CO3= 8.12E-05
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -1.61E-06
A(2,1) = 9.74E-02
A(3,1) = -1.22E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.63651E-07
A(3,4) = 2 ΔH2CO3 = 1.966419E-06
A(4,2) = 1
H= 5.20E-08
H2CO3 8.70E-05
HCO3 = 8.50E-04
CO3= 6.34E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -6.60E-09
A(2,1) = 7.46E-02
A(3,1) = -4.70E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.25324E-08
A(4,2) = 1
A(4,3) = 1 H 2.95E-08 7.530738825 43%
H= 2.95E-08
H2CO3 5.67E-05
HCO3 = 9.11E-04
CO3= 3.28E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.77E-08
A(2,1) = 3.61E-02
A(3,1) = -1.25E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.4761E-09
A(4,2) = 1
H= 2.00E-08
H2CO3 3.75E-05
HCO3 = 9.49E-04
CO3= 1.35E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -4.44E-09
A(2,1) = 1.42E-02
A(3,1) = -2.60E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.57078E-09
A(4,2) = 1
H= 1.54E-08
H2CO3 2.99E-05
HCO3 = 9.64E-04
CO3= 5.69E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 3.50E-09
A(2,1) = 5.90E-03
A(3,1) = -4.31E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.0264E-09
A(4,2) = 1
H= 1.44E-08
H2CO3 2.78E-05
HCO3 = 9.69E-04
CO3= 3.54E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.05E-10
A(2,1) = 3.65E-03
A(3,1) = -4.93E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -7.85063E-11
A(4,2) = 1
CO3 3.39E-06 4%
Pcb = 5 pH = 7.8E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 6 c= 1.00E-06 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
Matrices
H= 1.00E-08
H2CO3 1.00E-07
HCO3 = 1.00E-06
CO3= 1.00E-07
A(1,4) = 0 0 1 1 1 9.99E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-01
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.312648E-07
A(4,2) = 1
H= 1.41E-07
H2CO3 8.43E-05
HCO3 = 8.34E-04
CO3= 8.20E-05
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -8.96E-07
A(2,1) = 9.83E-02
A(3,1) = -1.50E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.04887E-07
A(3,4) = 2 ΔH2CO3 = -6.05262E-06
A(4,2) = 1
H= 3.64E-08
H2CO3 7.82E-05
HCO3 = 8.58E-04
CO3= 6.36E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.02E-07
A(2,1) = 7.41E-02
A(3,1) = -8.56E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.11304E-08
A(4,2) = 1
A(4,3) = 1 H 2.52E-08 7.597780803 31%
H= 2.52E-08
H2CO3 4.11E-05
HCO3 = 9.33E-04
CO3= 2.62E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -7.22E-08
A(2,1) = 2.80E-02
A(3,1) = -1.67E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.11291E-08
A(4,2) = 1
H= 1.41E-08
H2CO3 2.92E-05
HCO3 = 9.57E-04
CO3= 1.41E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 3.85E-08
A(2,1) = 1.47E-02
A(3,1) = -5.12E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.67452E-09
A(4,2) = 1
H= 1.14E-08
H2CO3 2.17E-05
HCO3 = 9.72E-04
CO3= 6.28E-06
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = -1.14E-08
A(2,1) = 6.46E-03
A(3,1) = -7.74E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.99812E-10
A(4,2) = 1
H= 1.04E-08
H2CO3 2.04E-05
HCO3 = 9.75E-04
CO3= 4.82E-06
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 8.95E-10
A(2,1) = 4.95E-03
A(3,1) = -9.27E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.23919E-11
A(4,2) = 1
CO3 4.70E-06 3%
Pcb = 6 pH = 8.0E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 7 c= 1.00E-07 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
Matrices
H= 1.00E-08
H2CO3 1.00E-07
HCO3 = 1.00E-06
CO3= 1.00E-07
A(1,4) = 0 0 1 1 1 9.99E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-01
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.238268E-07
A(4,2) = 1
H= 1.34E-07
H2CO3 8.42E-05
HCO3 = 8.34E-04
CO3= 8.20E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -8.24E-07
A(2,1) = 9.84E-02
A(3,1) = -1.56E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.86418E-08
A(3,4) = 2 ΔH2CO3 = -7.10561E-06
A(4,2) = 1
H= 3.52E-08
H2CO3 7.71E-05
HCO3 = 8.60E-04
CO3= 6.33E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.09E-07
A(2,1) = 7.37E-02
A(3,1) = -9.08E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.04333E-08
A(4,2) = 1
A(4,3) = 1 H 2.48E-08 7.606393398 30%
H= 2.48E-08
H2CO3 3.96E-05
HCO3 = 9.35E-04
CO3= 2.55E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -8.34E-08
A(2,1) = 2.73E-02
A(3,1) = -1.73E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.11801E-08
A(4,2) = 1
H= 1.36E-08
H2CO3 2.83E-05
HCO3 = 9.58E-04
CO3= 1.41E-05
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 4.22E-08
A(2,1) = 1.47E-02
A(3,1) = -5.53E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.51508E-09
A(4,2) = 1
H= 1.11E-08
H2CO3 2.09E-05
HCO3 = 9.73E-04
CO3= 6.36E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.31E-08
A(2,1) = 6.54E-03
A(3,1) = -8.28E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.78636E-10
A(4,2) = 1
H= 1.01E-08
H2CO3 1.97E-05
HCO3 = 9.75E-04
CO3= 4.99E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 9.73E-10
A(2,1) = 5.12E-03
A(3,1) = -9.95E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -3.79428E-11
A(4,2) = 1
CO3 4.87E-06 2%
Pcb = 7 pH = 8.0E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 8 c= 1.00E-08 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+ 𝐾_(𝑎,1) |𝐻^+ |+ |𝐻^+ |^2
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
Matrices
H= 1.00E-08
H2CO3 1.00E-07
HCO3 = 1.00E-06
CO3= 1.00E-07
A(1,4) = 0 0 1 1 1 9.99E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-01
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.23083E-07
A(4,2) = 1
H= 1.33E-07
H2CO3 8.42E-05
HCO3 = 8.34E-04
CO3= 8.20E-05
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -8.17E-07
A(2,1) = 9.84E-02
A(3,1) = -1.56E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.80136E-08
A(3,4) = 2 ΔH2CO3 = -7.215E-06
A(4,2) = 1
H= 3.51E-08
H2CO3 7.70E-05
HCO3 = 8.60E-04
CO3= 6.33E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.10E-07
A(2,1) = 7.36E-02
A(3,1) = -9.13E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.03685E-08
A(4,2) = 1
A(4,3) = 1 H 2.47E-08 7.607285914 30%
H= 2.47E-08
H2CO3 3.94E-05
HCO3 = 9.35E-04
CO3= 2.55E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -8.45E-08
A(2,1) = 2.73E-02
A(3,1) = -1.74E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.11831E-08
A(4,2) = 1
H= 1.35E-08
H2CO3 2.82E-05
HCO3 = 9.58E-04
CO3= 1.41E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 4.25E-08
A(2,1) = 1.47E-02
A(3,1) = -5.57E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.49978E-09
A(4,2) = 1
H= 1.10E-08
H2CO3 2.08E-05
HCO3 = 9.73E-04
CO3= 6.37E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.33E-08
A(2,1) = 6.55E-03
A(3,1) = -8.34E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.76359E-10
A(4,2) = 1
H= 1.00E-08
H2CO3 1.96E-05
HCO3 = 9.75E-04
CO3= 5.01E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 9.80E-10
A(2,1) = 5.13E-03
A(3,1) = -1.00E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -3.75107E-11
A(4,2) = 1
CO3 4.89E-06 2%
Pcb = 8 pH = 8.0E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10
𝑔(𝑥,𝑦)=𝑦+ 3𝑥𝑦^2−57
𝐻^+ |+ |𝐻^+ |^2 )
Efluentes básicos
T=
pKa,1 6.3 Ka,1 = 5.0119E-07
pKa,2 10.3 Ka,2= 5.0119E-11
Kw= 1E-14
pC = 3 c= 1.00E-03 M (esta condición es del río)
Ca = 2 c= 1.00E-02 M (esta condición es del contaminante)
Funciones
x, y, z, w
H= 1.00E-13
H2CO3 1.00E-12
HCO3 = 1.00E-06
CO3= 1.00E-04
A(1,4) = 0 0 1 1 1 8.99E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E+02
A(2,2) = 0 1.990079E-17 9.9E-08 -1.0E-12 1.990079E-12
A(3,1) = -1.00E+12
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 9.100676E-14
A(4,2) = 1
H= 1.91E-13
H2CO3 3.73E-12
HCO3 = 6.83E-06
CO3= 9.93E-04
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 1.51E-07
A(2,1) = 1.45E+02
A(3,1) = -2.74E+11
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.581956E-13
A(3,4) = 2 ΔH2CO3 = 1.564211E-12
A(4,2) = 1
A(4,3) = 1 H 3.49E-13 12.45692284 83%
CO3 9.93E-04 0%
H= 3.49E-13
H2CO3 5.29E-12
HCO3 = 6.99E-06
CO3= 9.93E-04
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 3.99E-08
A(2,1) = 1.42E+02
A(3,1) = -8.20E+10
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 2.394776E-13
A(3,4) = 2 ΔH2CO3 = 6.720787E-12
A(4,2) = 1
CO3 9.88E-04 0%
H= 5.89E-13
H2CO3 1.20E-11
HCO3 = 1.17E-05
CO3= 9.88E-04
A(1,5) = -7.11E-08
A(2,1) = 8.46E+01
A(3,1) = -2.89E+10
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 2.766708E-13
A(4,2) = 1
CO3 9.83E-04 1%
H= 8.65E-13
H2CO3 2.47E-11
HCO3 = 1.70E-05
CO3= 9.83E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = -9.66E-08
A(2,1) = 5.77E+01
A(3,1) = -1.34E+10
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.908719E-13
A(4,2) = 1
CO3 9.79E-04 0%
H= 1.06E-12
H2CO3 3.93E-11
HCO3 = 2.07E-05
CO3= 9.79E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = -5.37E-08
A(2,1) = 4.74E+01
A(3,1) = -8.96E+09
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 5.128057E-14
A(3,4) = 2 ΔH2CO3 = 7.534431E-12
A(4,2) = 1
CO3 9.78E-04 0%
H= 1.11E-12
H2CO3 4.69E-11
HCO3 = 2.16E-05
CO3= 9.78E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = -9.67E-09
A(2,1) = 4.52E+01
A(3,1) = -8.15E+09
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 2.604762E-15
A(4,2) = 1
A(4,3) = 1 H 1.11E-12 11.95463477 0%
CO3 9.78E-04 0%
H= 1.11E-12
H2CO3 4.80E-11
HCO3 = 2.17E-05
CO3= 9.78E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = -2.24E-10
A(2,1) = 4.51E+01
A(3,1) = -8.11E+09
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 6.12707E-18
A(4,2) = 1
CO3 9.78E-04 0%
Pcb = 2 pH = 1.2E+01
pCB pH =7 pH =7
Chart Title
2.00 11.955 1.2E+01
1.3E+01
14 Condición inicial pH 7
pH 7 pH
12 Acid
pC Acido Base
o
2.00 2.037824644 1.2E+01 10 Base
3.00 3.772600239 1.0E+01
8
4.00 6.740858337 7.4E+00
5.00 6.969549846 7.0E+00 6
6.00 6.996891434 7.0E+00
4
7.00 6.999688482 7.0E+00
0
2.00 3.00 4.00 5.00 6.00 7.00 8.00
pC
pH
pH 8
Condición inicial pH 7
pC Acido Base 14
2.00 2.045099673 1.2E+01 Acido
12
3.00 4.522700346 9.6E+00
Base
10
6
pH
Condición inicial pH 7
14
Acido
12
Base
10
4.00 7.188641659 9.2E+00
0
2.00 3.00 4.00 5.00 6.00 7.00 8.00
pC
Ca = 2.00 0.00 c= 1.00E-02 M pH = 11.97624452
Cb pH
2.00 11.97624452
0.00 0
0.00 0
0.00 0
0.00 0
0.00 0
Chart Title
9
Cb pH =7 pH =8
7
2 2.038304129 2.043665453
3 3.591602496 3.205110251 6
4.00 6.740763232 5.27207545
5
5.00 6.969570621 7.848171794
2
2 3 4 5 6 7 8
Column B Column C
CO3= 0.0001 0 0 0 0
#REF! #REF! #REF! #REF! #REF! #REF! #REF!
Mf = 0.00089317
Uf = 0
Tf = 1.910068E-13
A(1,1) = #REF! #REF! -0.00089317 0 #REF!
A(1,4) = #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 0.0001 0 0 0 0
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,1) = #REF! #REF! #REF! 0 #REF!
A(1,4) = #REF!
ϐ(T) = #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 0.0001 0 0 0 0
Mf = #REF!
Uf = #REF!
Tf = #REF!
A(1,4) = #REF!
ϐ(T) = #REF!
A(3,3) = #REF!
A(3,4) = #REF!
CO3= 0.0001 0 0 0 0
Mf = #REF!
Uf = #REF! X=
Tf = #REF! Y=
A(1,1) = #REF! #REF! #REF! 0 #REF! A(1,1) =
A(1,2) = #REF! #REF! -1 #REF! #REF! A(1,2) =
A(1,3) = 0 #REF! 0 #REF! #REF! A(1,3) =
A(1,4) = #REF! A(2,1) =
A(2,1) = #REF! Minversa A(2,2) =
A(2,2) = -1 #REF! #REF! #REF! A(2,3)=
A(2,3)= #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
Mf = #REF!
Uf = #REF!
Tf = #REF! X=
A(1,1) = #REF! #REF! #REF! 0 #REF! Y=
A(1,2) = #REF! #REF! -1 #REF! #REF! A(1,1) =
A(1,3) = 0 #REF! 0 #REF! #REF! A(1,2) =
A(1,4) = #REF! A(1,3) =
A(2,1) = #REF! Minversa A(2,1) =
A(2,2) = -1 #REF! #REF! #REF! A(2,2) =
A(2,3)= #REF! #REF! #REF! #REF! A(2,3)=
A(2,4) = #REF! #REF! #REF! #REF!
ϐ(T) = #REF!
X=
Y=
A(1,1) =
A(1,2) =
A(1,3) =
A(2,1) =
A(2,2) =
A(2,3)=
T=
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 3 c= 1.00E-03 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
H= 1.00E-09
H2CO3 1.00E-09
HCO3 = 1.00E-05
CO3= 1.00E-04
A(1,4) = 0 0 1 1 1 8.90E-04
A(1,5) = -9.50E-06
A(2,1) = 1.00E+01
A(2,2) = 0 9.997477E-09 4.8E-02 -5.2E-05 9.997477E-05
A(3,1) = -1.00E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.00038E-09
A(4,2) = 1
H= -3.00E-09
H2CO3 3.31E-09
HCO3 = 6.36E-05
CO3= 9.36E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = 5.82E-05
A(2,1) = 1.47E+01
A(3,1) = -1.11E+03
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 6.028514E-09
A(3,4) = 2 ΔH2CO3 = -6.43302E-09
A(4,2) = 1
A(4,3) = 1 H 3.03E-09 8.518824972 201%
CO3 9.96E-04 6%
H= 3.03E-09
H2CO3 -3.12E-09
HCO3 = 3.56E-06
CO3= 9.96E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = 3.95E-06
A(2,1) = 2.80E+02
A(3,1) = -1.09E+03
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 4.337031E-09
A(3,4) = 2 ΔH2CO3 = -1.56273E-08
A(4,2) = 1
CO3 9.88E-04 1%
H= 7.37E-09
H2CO3 -1.88E-08
HCO3 = 1.22E-05
CO3= 9.88E-04
A(1,5) = 5.29E-06
A(2,1) = 8.10E+01
A(3,1) = -1.85E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -5.06966E-09
A(4,2) = 1
CO3 9.84E-04 0%
H= 2.30E-09
H2CO3 -3.23E-08
HCO3 = 1.59E-05
CO3= 9.84E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.63E-06
A(2,1) = 6.17E+01
A(3,1) = -1.90E+03
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.55143E-09
A(4,2) = 1
CO3 9.79E-04 1%
H= 7.44E-10
H2CO3 -6.74E-08
HCO3 = 2.10E-05
CO3= 9.79E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = 7.33E-07
A(2,1) = 4.66E+01
A(3,1) = -1.81E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -3.0549E-10
A(3,4) = 2 ΔH2CO3 = -2.24273E-07
A(4,2) = 1
CO3 9.67E-04 1%
H= 4.39E-10
H2CO3 -2.92E-07
HCO3 = 3.31E-05
CO3= 9.67E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = 5.51E-07
A(2,1) = 2.92E+01
A(3,1) = -5.20E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.72813E-10
A(4,2) = 1
A(4,3) = 1 H 2.66E-10 9.575484084 39%
CO3 9.51E-04 2%
H= 2.66E-10
H2CO3 -3.57E-06
HCO3 = 5.25E-05
CO3= 9.51E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = 5.05E-07
A(2,1) = 1.81E+01
A(3,1) = -1.42E+05
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 3.122221E-09
A(4,2) = 1
Pcb = 3 pH = 9.6E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 4 c= 1.00E-04 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
H= 1.00E-09 1.00E-08
A(1,4) = 0 0 1 1 1 9.97E-04
A(1,5) = 5.00E-07
A(2,1) = 1.00E+00
A(2,2) = 0 0.083326389 8.3E-02 -8.3E-05 8.332639E-05
A(3,1) = -1.00E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 3.523233E-08
A(4,2) = 1
H= 3.62E-08
H2CO3 3.54E-05
HCO3 = 5.00E-04
CO3= 4.64E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.06E-08
A(2,1) = 9.28E-01
A(3,1) = -8.62E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 8.801539E-09
A(3,4) = 2 ΔH2CO3 = 2.942236E-05
A(4,2) = 1
A(4,3) = 1 H 4.50E-08 7.346460735 24%
H= 4.50E-08
H2CO3 6.48E-05
HCO3 = 7.84E-04
CO3= 1.51E-04
A(1,4) = 0 0 1 1 1 0
A(1,5) = -4.33E-08
A(2,1) = 1.93E-01
A(3,1) = -5.93E+00
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -3.08157E-08
A(3,4) = 2 ΔH2CO3 = -3.36346E-05
A(4,2) = 1
H= 1.42E-08
H2CO3 3.12E-05
HCO3 = 8.52E-04
CO3= 1.17E-04
A(1,5) = 1.13E-07
A(2,1) = 1.38E-01
A(3,1) = -5.05E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -9.44622E-09
A(4,2) = 1
H= 4.77E-09
H2CO3 3.43E-06
HCO3 = 9.08E-04
CO3= 8.87E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -7.63E-07
A(2,1) = 9.77E-02
A(3,1) = -4.40E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.04618E-09
A(4,2) = 1
CO3 8.51E-05 4%
H= 7.26E-10
H2CO3 2.61E-06
HCO3 = 9.12E-04
CO3= 8.51E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.47E-07
A(2,1) = 9.33E-02
A(3,1) = -1.90E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -5.87983E-11
A(3,4) = 2 ΔH2CO3 = -2.69846E-06
A(4,2) = 1
H= 6.67E-10
H2CO3 -9.27E-08
HCO3 = 9.29E-04
CO3= 7.14E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 7.19E-06
A(2,1) = 7.69E-02
A(3,1) = -2.25E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.08469E-11
A(4,2) = 1
A(4,3) = 1 H 6.56E-10 9.183011348 2%
CO3 7.10E-05 1%
H= 6.56E-10
H2CO3 -1.91E-07
HCO3 = 9.29E-04
CO3= 7.10E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 3.70E-06
A(2,1) = 7.64E-02
A(3,1) = -2.32E+04
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 1.886797E-12
A(4,2) = 1
CO3 7.08E-05 0%
Pcb = 4 pH = 9.2E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 5 c= 1.00E-05 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
H= 1.00E-08
H2CO3 1.00E-05
HCO3 = 1.00E-04
CO3= 1.00E-06
A(1,4) = 0 0 1 1 1 8.89E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-02
A(2,2) = 0 0.081462491 9.6E+00 -8.9E-04 0.000814625
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -3.56176E-08
A(4,2) = 1
H= -2.56E-08
H2CO3 2.09E-05
HCO3 = 9.66E-04
CO3= 1.27E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.69E-06
A(2,1) = 1.32E-02
A(3,1) = -1.62E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 3.801946E-08
A(3,4) = 2 ΔH2CO3 = -1.33707E-06
A(4,2) = 1
A(4,3) = 1 H 1.24E-08 7.906513967 148%
H= 1.24E-08
H2CO3 1.96E-05
HCO3 = 9.63E-04
CO3= 1.70E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = -1.10E-07
A(2,1) = 1.76E-02
A(3,1) = -6.60E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.9243E-09
A(3,4) = 2 ΔH2CO3 = -4.05093E-06
A(4,2) = 1
H= 7.48E-09
H2CO3 1.55E-05
HCO3 = 9.74E-04
CO3= 1.08E-05
A(1,5) = 3.19E-08
A(2,1) = 1.11E-02
A(3,1) = -1.80E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -8.22965E-10
A(4,2) = 1
H= 6.65E-09
H2CO3 1.28E-05
HCO3 = 9.79E-04
CO3= 7.78E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -6.26E-09
A(2,1) = 7.94E-03
A(3,1) = -2.27E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.63761E-10
A(4,2) = 1
CO3 7.57E-06 3%
H= 6.49E-09
H2CO3 1.27E-05
HCO3 = 9.80E-04
CO3= 7.57E-06
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 8.01E-11
A(2,1) = 7.73E-03
A(3,1) = -2.38E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -7.40801E-13
A(3,4) = 2 ΔH2CO3 = -3.37458E-09
A(4,2) = 1
CO3 7.57E-06 0%
H= 6.49E-09
H2CO3 1.27E-05
HCO3 = 9.80E-04
CO3= 7.57E-06
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -2.08E-14
A(2,1) = 7.72E-03
A(3,1) = -2.38E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -3.16802E-16
A(4,2) = 1
A(4,3) = 1 H 6.49E-09 8.187750339 0%
CO3 7.57E-06 0%
H= 6.49E-09
H2CO3 1.27E-05
HCO3 = 9.80E-04
CO3= 7.57E-06
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 2.12E-22
A(2,1) = 7.72E-03
A(3,1) = -2.38E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 6.2968E-23
A(4,2) = 1
CO3 7.57E-06 0%
Pcb = 5 pH = 8.2E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 6 c= 1.00E-06 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
H= 1.00E-08
H2CO3 1.00E-05
HCO3 = 1.00E-04
CO3= 1.00E-06
A(1,4) = 0 0 1 1 1 8.89E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-02
A(2,2) = 0 0.081462491 9.6E+00 -8.9E-04 0.000814625
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.76391E-08
A(4,2) = 1
H= -1.76E-08
H2CO3 2.82E-05
HCO3 = 9.60E-04
CO3= 1.19E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.10E-06
A(2,1) = 1.24E-02
A(3,1) = -3.31E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 3.152545E-08
A(3,4) = 2 ΔH2CO3 = 1.142345E-06
A(4,2) = 1
A(4,3) = 1 H 1.39E-08 7.857411534 179%
H= 1.39E-08
H2CO3 2.94E-05
HCO3 = 9.52E-04
CO3= 1.84E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 5.10E-08
A(2,1) = 1.93E-02
A(3,1) = -5.29E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.73179E-09
A(3,4) = 2 ΔH2CO3 = -8.50864E-06
A(4,2) = 1
H= 1.12E-08
H2CO3 2.09E-05
HCO3 = 9.72E-04
CO3= 7.43E-06
A(1,5) = -1.83E-08
A(2,1) = 7.65E-03
A(3,1) = -8.14E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.45782E-09
A(4,2) = 1
H= 9.70E-09
H2CO3 1.90E-05
HCO3 = 9.76E-04
CO3= 5.37E-06
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 2.14E-09
A(2,1) = 5.50E-03
A(3,1) = -1.07E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -8.88749E-11
A(4,2) = 1
CO3 5.09E-06 5%
H= 9.61E-09
H2CO3 1.87E-05
HCO3 = 9.76E-04
CO3= 5.09E-06
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = -2.56E-11
A(2,1) = 5.22E-03
A(3,1) = -1.09E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.39607E-12
A(3,4) = 2 ΔH2CO3 = -1.69299E-09
A(4,2) = 1
CO3 5.09E-06 0%
H= 9.61E-09
H2CO3 1.87E-05
HCO3 = 9.76E-04
CO3= 5.09E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.59E-15
A(2,1) = 5.22E-03
A(3,1) = -1.09E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -6.91505E-17
A(4,2) = 1
A(4,3) = 1 H 9.61E-09 8.017435532 0%
CO3 5.09E-06 0%
H= 9.61E-09
H2CO3 1.87E-05
HCO3 = 9.76E-04
CO3= 5.09E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 0.00E+00
A(2,1) = 5.22E-03
A(3,1) = -1.09E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -7.77618E-25
A(4,2) = 1
CO3 5.09E-06 0%
Pcb = 6 pH = 8.0E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 7 c= 1.00E-07 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+|𝐻_2 〖𝐶𝑂|𝐻^+
𝐾_(𝑎,1) 〗 _3^∗ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
H= 1.00E-08
H2CO3 1.00E-05
HCO3 = 1.00E-04
CO3= 1.00E-06
A(1,4) = 0 0 1 1 1 8.89E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-02
A(2,2) = 0 0.081462491 9.6E+00 -8.9E-04 0.000814625
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.68412E-08
A(4,2) = 1
H= -1.68E-08
H2CO3 2.90E-05
HCO3 = 9.59E-04
CO3= 1.18E-05
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 1.06E-06
A(2,1) = 1.23E-02
A(3,1) = -3.63E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 3.095003E-08
A(3,4) = 2 ΔH2CO3 = 1.508819E-06
A(4,2) = 1
A(4,3) = 1 H 1.41E-08 7.850510064 184%
H= 1.41E-08
H2CO3 3.05E-05
HCO3 = 9.51E-04
CO3= 1.87E-05
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 6.10E-08
A(2,1) = 1.97E-02
A(3,1) = -5.12E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.53111E-09
A(3,4) = 2 ΔH2CO3 = -9.02876E-06
A(4,2) = 1
H= 1.16E-08
H2CO3 2.14E-05
HCO3 = 9.71E-04
CO3= 7.13E-06
A(1,5) = -2.32E-08
A(2,1) = 7.34E-03
A(3,1) = -7.56E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.53587E-09
A(4,2) = 1
H= 1.00E-08
H2CO3 1.96E-05
HCO3 = 9.75E-04
CO3= 5.18E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.44E-09
A(2,1) = 5.31E-03
A(3,1) = -1.00E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -8.01874E-11
A(4,2) = 1
CO3 4.91E-06 5%
H= 9.96E-09
H2CO3 1.94E-05
HCO3 = 9.76E-04
CO3= 4.91E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -2.84E-11
A(2,1) = 5.03E-03
A(3,1) = -1.02E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.33896E-12
A(3,4) = 2 ΔH2CO3 = -1.44667E-09
A(4,2) = 1
CO3 4.91E-06 0%
H= 9.96E-09
H2CO3 1.94E-05
HCO3 = 9.76E-04
CO3= 4.91E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.33E-15
A(2,1) = 5.03E-03
A(3,1) = -1.02E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.96093E-17
A(4,2) = 1
A(4,3) = 1 H 9.96E-09 8.001728253 0%
CO3 4.91E-06 0%
H= 9.96E-09
H2CO3 1.94E-05
HCO3 = 9.76E-04
CO3= 4.91E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 0.00E+00
A(2,1) = 5.03E-03
A(3,1) = -1.02E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 8.55232E-23
A(4,2) = 1
CO3 4.91E-06 0%
Pcb = 7 pH = 8.0E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10 𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦
0 0 Ka,1 = 1
Kw= 1E-14
pC = 3 c= 1.00E-03 M
Cb = 8 c= 1.00E-08 M
〗 _3^∗
𝐻^+ |𝐻^+=|^2
|+|/𝐶_𝑇 |𝐻^+ |𝐻 〖𝐶𝑂𝐾_(𝑎,2)+
) |^2/(𝐾_(𝑎,1) 𝐾_(𝑎,1)
〗 _3^− |/𝐶_𝑇 |𝐻^+ ||+
= (|𝐻^+ |𝐻^+ |^2 )
𝐾_(𝑎,1))/(𝐾_(𝑎,1) 𝐾_(𝑎,2)+ 𝐾_(𝑎,1) |𝐻^+ |+ |𝐻^+ |^2
Funciones
𝑓(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ ||
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2 𝐶𝑂 〗
^∗ 〗 _3 | − 𝐾_(𝑎,1)
𝑔(𝑥,𝑦,𝑧,𝑤)= |𝐻^+ || 〖〖𝐶𝑂〗 ^= 〗 _3 |/| 〖〖𝐻
𝐶𝑂〗 ^− 〗 _3 | − 𝐾_(𝑎,2)
h(x,y,z,w) = | 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + 2|
〖〖𝐶𝑂〗 ^= 〗 _3 | + | 〖𝑂𝐻〗 ^− | - |𝐻^+ | - BC2
i(𝑥,𝑦,𝑧,𝑤)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ | 〖〖𝐻𝐶
𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Variables
x, y, z, w
H, H2CO3, HCO3 CO3
f(x,y,z,w) g(x,y,z,w) h(x,y,z,w) i(x,y,z,w)
H= 1.00E-08
H2CO3 1.00E-05
HCO3 = 1.00E-04
CO3= 1.00E-06
A(1,4) = 0 0 1 1 1 8.89E-04
A(1,5) = 4.01E-07
A(2,1) = 1.00E-02
A(2,2) = 0 0.081462491 9.6E+00 -8.9E-04 0.000814625
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.67614E-08
A(4,2) = 1
H= -1.68E-08
H2CO3 2.90E-05
HCO3 = 9.59E-04
CO3= 1.18E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 1.05E-06
A(2,1) = 1.23E-02
A(3,1) = -3.66E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = 3.089313E-08
A(3,4) = 2 ΔH2CO3 = 1.54711E-06
A(4,2) = 1
A(4,3) = 1 H 1.41E-08 7.84980622 184%
H= 1.41E-08
H2CO3 3.06E-05
HCO3 = 9.51E-04
CO3= 1.87E-05
A(1,4) = 0 0 1 1 1 0
A(1,5) = 6.19E-08
A(2,1) = 1.97E-02
A(3,1) = -5.11E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -2.51108E-09
A(3,4) = 2 ΔH2CO3 = -9.082E-06
A(4,2) = 1
H= 1.16E-08
H2CO3 2.15E-05
HCO3 = 9.71E-04
CO3= 7.11E-06
A(1,5) = -2.37E-08
A(2,1) = 7.31E-03
A(3,1) = -7.51E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.54392E-09
A(4,2) = 1
H= 1.01E-08
H2CO3 1.97E-05
HCO3 = 9.75E-04
CO3= 5.16E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = 2.46E-09
A(2,1) = 5.29E-03
A(3,1) = -9.95E+01
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -7.93283E-11
A(4,2) = 1
CO3 4.89E-06 5%
H= 1.00E-08
H2CO3 1.95E-05
HCO3 = 9.76E-04
CO3= 4.89E-06
A(1,4) = 0 0 1 1 1 0
A(1,5) = -2.86E-11
A(2,1) = 5.02E-03
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -1.33243E-12
A(3,4) = 2 ΔH2CO3 = -1.42294E-09
A(4,2) = 1
CO3 4.89E-06 0%
H= 1.00E-08
H2CO3 1.95E-05
HCO3 = 9.76E-04
CO3= 4.89E-06
A(1,4) = 0 0 1 1 1 2.168404E-19
A(1,5) = 2.30E-15
A(2,1) = 5.01E-03
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -4.79101E-17
A(4,2) = 1
A(4,3) = 1 H 1.00E-08 8.000172672 0%
CO3 4.89E-06 0%
H= 1.00E-08
H2CO3 1.95E-05
HCO3 = 9.76E-04
CO3= 4.89E-06
A(1,4) = 0 0 1 1 1 -2.1684E-19
A(1,5) = 0.00E+00
A(2,1) = 5.01E-03
A(3,1) = -1.01E+02
A(3,2) = 0 Resultados
A(3,3) = 1 ΔH = -8.54413E-23
A(4,2) = 1
CO3 4.89E-06 0%
Pcb = 8 pH = 8.0E+00
𝑓(𝑥,𝑦)=𝑥^2+𝑥𝑦−10
𝑔(𝑥,𝑦)=𝑦+ 3𝑥𝑦^2−57
𝐻^+ |+ |𝐻^+ |^2 )
Estudiante: Sanchez Apaza Ramiro Numero:12
Indice de Langelier
Carrera: Ing Ambiental 25/4/2020
Ca+2 30
HCO3(-1) 95
pH = 8.7
T (oC) = 10
Determinar si el agua se encuentra en equilibrio con el carbonato de calcio
IL es mayor a cero esta sobresaturado y tiende a precipitar puede formarse incrustaciones de calcio.
Estudiante: Sanchez Apaza Ramiro Numero:12
Indice de Langelier
Carrera: Ing Ambiental 25/4/2020
T=
pKa,1 1.99 Ka,1 = 0.01023293
pKa,2 2.67 Ka,2= 0.00213796
Kw= 1E-14
pC = 3 0.001
Sistema cerrado
pH Column B Column C Column D Column E Column F
Column G
1 2 3 4 5 6 7 8 9 10 11 12 13 14
0
2
H2CO3
CT CO2,ac
C
p
8
4
10
12
14
Variables
H2CO3, HCO3 , CO3
Funciones
𝑓(𝑥,𝑦,𝑧)= |𝐻^+ || 〖〖𝐻𝐶𝑂〗 ^− 〗 _3 |/| 〖〖𝐻 _2
𝐶𝑂 〗 ^∗ 〗 _3 | − 𝐾_(𝑎,1)
ℎ(𝑥,𝑦,𝑧)= | 〖〖𝐻 _2 𝐶𝑂 〗 ^∗ 〗 _3 |+ |
〖〖𝐻𝐶𝑂〗 ^− 〗 _3 | + | 〖〖𝐶𝑂〗 ^= 〗 _3 | -Ct
Ka,1 = 0.01023293
Ka,2= 0.00213796
CT = 0.001
H= 0.04
H2CO3 0.001
HCO3 = 3.16228E-07
CO3= 1E-15
Matriz
A(1,1) = -0.01264911 -0.012649111 40 0 0.010220281
A(1,2) = 40 0 -0.0004 126491.1064 0.002137962
A(1,3) = 0 1 1 1 -3.16228E-07
A(1,4) = 0.01022028
A(2,1) = 0 Minversa
A(2,2) = -0.0004 -2.5E-02 -7.9E-06 1.0E+00
A(2,3)= 126491.106 2.5E-02 -2.5E-09 3.2E-04
A(2,4) = 0.00213796 7.9E-11 7.9E-06 1.0E-12
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = -0.000255759
A(3,4) = -3.1623E-07 ΔHCO3 = 0.000255426
ΔCO3 = 1.690288E-08
H2CO3 0.000744241 E1 = 0.343651272
HCO3 0.000255742 E2 = 0.998763491
CO3 1.690288E-08 E3 = 0.999999941
H2CO3 0.00074424
HCO3 = 0.00025574
CO3= 1.69029E-08
Matriz
A(1,1) = -18.4686781 -18.46867811 53.74605089 0 -0.003512213
A(1,2) = 53.7460509 0 -0.010337497 156.4074033 0.002135318
A(1,3) = 0 1 1 1 2.168404E-19
A(1,4) = -0.00351221
A(2,1) = 0 Minversa
A(2,2) = -0.0103375 -1.4E-02 -4.8E-03 7.4E-01
A(2,3)= 156.407403 1.4E-02 -1.6E-03 2.6E-01
A(2,4) = 0.00213532 9.2E-07 6.4E-03 1.7E-05
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 3.847749E-05
A(3,4) = 2.1684E-19 ΔHCO3 = -5.21263E-05
ΔCO3 = 1.364884E-05
H2CO3 0.000782718 E1 = 0.049158799
HCO3 0.000203616 E2 = 0.25600304
CO3 1.366574E-05 E3 = 0.99876312
H2CO3 0.00078272
HCO3 = 0.00020362
CO3= 1.36657E-05
Matriz
A(1,1) = -13.2941663 -13.29416625 51.1039596 0 -0.000172656
A(1,2) = 51.1039596 0 -13.18466871 196.4481741 -0.000546648
A(1,3) = 0 1 1 1 0
A(1,4) = -0.00017266
A(2,1) = 0 Minversa
A(2,2) = -13.1846687 -1.6E-02 -4.0E-03 7.8E-01
A(2,3)= 196.448174 1.5E-02 -1.0E-03 2.0E-01
A(2,4) = -0.00054665 1.0E-03 5.0E-03 1.4E-02
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 4.999954E-06
A(3,4) = 0 ΔHCO3 = -2.07784E-06
ΔCO3 = -2.92211E-06
H2CO3 0.000787718 E1 = 0.006347389
HCO3 0.000201538 E2 = 0.010309914
CO3 1.074363E-05 E3 = 0.271985583
H2CO3 0.00078772
HCO3 = 0.00020154
CO3= 1.07436E-05
Matriz
A(1,1) = -12.9919891 -12.99198908 50.77958287 0 -1.09592E-06
A(1,2) = 50.7795829 0 -10.5802581 198.4735379 5.635894E-06
A(1,3) = 0 1 1 1 -2.1684E-19
A(1,4) = -1.0959E-06
A(2,1) = 0 Minversa
A(2,2) = -10.5802581 -1.6E-02 -4.0E-03 7.9E-01
A(2,3)= 198.473538 1.6E-02 -1.0E-03 2.0E-01
A(2,4) = 5.63589E-06 8.3E-04 5.0E-03 1.1E-02
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = -4.46155E-09
A(3,4) = -2.1684E-19 ΔHCO3 = -2.27233E-08
ΔCO3 = 2.718486E-08
H2CO3 0.000787714 E1 = 5.663923E-06
HCO3 0.000201515 E2 = 0.000112762
CO3 1.077081E-05 E3 = 0.002523937
H2CO3 0.00078771
HCO3 = 0.00020152
CO3= 1.07708E-05
Matriz
A(1,1) = -12.9906714 -12.9906714 50.77987048 0 6.207184E-12
A(1,2) = 50.7798705 0 -10.60942185 198.4959182 -6.35515E-10
A(1,3) = 0 1 1 1 0
A(1,4) = 6.20718E-12
A(2,1) = 0 Minversa
A(2,2) = -10.6094219 -1.6E-02 -4.0E-03 7.9E-01
A(2,3)= 198.495918 1.6E-02 -1.0E-03 2.0E-01
A(2,4) = -6.3552E-10 8.3E-04 5.0E-03 1.1E-02
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 2.420552E-12
A(3,4) = 0 ΔHCO3 = 7.414707E-13
ΔCO3 = -3.16202E-12
H2CO3 0.000787714 E1 = 3.072883E-09
HCO3 0.000201515 E2 = 3.679472E-09
CO3 1.077081E-05 E3 = 2.935733E-07
H2CO3 0.00078771
HCO3 = 0.00020152
CO3= 1.07708E-05
Matriz
A(1,1) = -12.9906714 -12.99067136 50.77987033 0 0
A(1,2) = 50.7798703 0 -10.60941866 198.4959174 -2.1684E-18
A(1,3) = 0 1 1 1 2.168404E-19
A(1,4) = 0
A(2,1) = 0 Minversa
A(2,2) = -10.6094187 -1.6E-02 -4.0E-03 7.9E-01
A(2,3)= 198.495917 1.6E-02 -1.0E-03 2.0E-01
A(2,4) = -2.1684E-18 8.3E-04 5.0E-03 1.1E-02
A(3,1) = 1
A(3,2) = 1 Resultados
A(3,3) = 1 ΔH = 1.794133E-19
A(3,4) = 2.1684E-19 ΔHCO3 = 4.589809E-20
ΔCO3 = -8.47097E-21
H2CO3 0.000787714 E1 = 2.752782E-16
HCO3 0.000201515 E2 = 0
CO3 1.077081E-05 E3 = 0
umn F
13 14
H = 10 ^ (-pH)
H2CO3 = 10 ^ -15
HCO3 = 10 ^ -6.5
CO3 = 10 ^ -3
CT = 10 ^ -2
A(1, 1) = -H * HCO3 / H2CO3 ^ 2
A(1, 2) = H / H2CO3
A(1, 3) = 0
A(1, 4) = -(H * HCO3 / H2CO3 - K1)
A(2, 1) = 0
A(2, 2) = -H * CO3 / HCO3 ^ 2
A(2, 3) = H / HCO3
A(2, 4) = -(H * CO3 / HCO3 - K2)
A(3, 1) = 1
A(3, 2) = 1
A(3, 3) = 1
A(3, 4) = -(H2CO3 + HCO3 + CO3 - CT)