__________________________________________________________________________________________

sec e++ DATE:20.03.2024

TIME: 3 HRS MAX.MARKS:300
GTM-8_KEY
MATHEMATICS

1 C 2 D 3 C 4 D 5 C
6 B 7 C 8 C 9 C 10 A
11 B 12 D 13 A 14 C 15 A
16 B 17 C 18 C 19 C 20 B
21 16 22 27 23 529 24 7 25 24
26 26664 27 11 28 24 29 6 30 5
PHYSICS

31 B 32 D 33 D 34 B 35 B
36 C 37 D 38 C 39 B 40 D
41 B 42 D 43 B 44 A 45 C
46 C 47 D 48 B 49 A 50 A
51 44 52 2 53 3668 54 8 55 48
56 3 57 20 58 34 59 3 60 80
CHEMISTRY

61 A 62 B 63 A 64 A 65 A
66 B 67 D 68 A 69 D 70 B
71 A 72 A 73 B 74 B 75 C
76 D 77 D 78 D 79 B 80 A
81 1or 3 82 3 83 1 84 66 85 2
86 1 87 4 88 4 89 4 90 40535
SR.IIT-*CO-SC Page 1
MATHS
1.
Ans: C
Sol.
t2
  f  x  x  dx  43 t , t  0.
2 3

0
Diff. w.r.to t

 f t   t  2t  4t
2 4 2

2  4   3 
f  x   2 x  x  f          1  
2

 4   16   16 
2.
Ans: D
Sol:
 x  1 p 1  x q
Coefficient of x   p C0 .q C1  p C1.q C0
4  q  p
Coefficient of x2  p C0qC2  p C2qC0  p C1qC1
q  q  1 p  p  1
5    pq
2 2
10  q 2  q  p 2  p  2 pq

10  p 2  q 2  2 pq   p  q  
10   p  q    p  q 
2

10  42   p  q 
p  q  16  10  26
 2 p  26  4
 p  15
 q  11
2 p  3q  2 15   3 11
 30  33
 63
3.
Ans: C
Sol :
 5! 6! 7!
1 
A 6! 7! 8!
5! 6! 7!  
7! 8! 9!
| 2 A |4  212  | A |4
1 6 42 1 6 42
A  1 7 56  0 1 14 | A | 2
1 8 72 0 1 16
| 2 A |4  212  | A |4  212  24  216
4.
Ans: D
Sol :
Let A 1,2,0  , B 1,4,1 , C  0,5,1
x 1 y  2 z
eq. plane is 0 2 1 0
1 3 1
 x  y  2z  3  0
image of 1,2,6  in the plane x  y  2 z  3  0 is  ,  ,  
 1   2   6 1  2  12  3 
  
 2  2 2
1 1 2  1  1  22 
   5,   6,   2
 2   2   2  25  36  4  65
5.
Ans: C (NTA key is B, key change)
8!
Sol : Divide 8 persons in 3 groups of 3,3 and 2 persons   280
 3! 2
 2! 2!
number of ways in which they can be transported is 280  3!  1680
6.
Ans: B
Sol :
 91tan x  9tan x  10 let 9tan x  t
2 2 2

9
  t  10  9  t 2  10t
t
 t 2  10t  9  0   t  1 t  9   0
t  1 or t  9
2 2
9tan x
 1 or 9tan x
9
 tan 2 x  0 or tan 2 x  1
 tan x  0 or tan x  1
 
x  0, , 
4 4
 x     
  tan 2    tan 2 0  tan 2    tan 2  
3  12   12 
 
 
2
 0  2 tan 2    2 tan 2 150  2 2  3  14  8 3
 12 
883
1 1
 
2
    14   8 3 
2
 32
6 6 6
7.
Ans: C
Sol :
Sn  4  11  21  34  ...  an
Sn  0  4  11  21  ..  ..  an
0   4  7  10  13  ...  ....  an
n n 3n 2  5n
an   2  4    n  1 3  3n  5 
2 2 2
3 5 3 29  30  59  5 29  30 
 S29   n 2   n  .  .
2 2 2 6 2 2
29 10  29  30 
 59  5  64  29  30 16 
4 4
3 9 10 19  5 9 10  9 10 
 S9  .  .  19  5  9 10  6 
2 6 2 2 4
 S29  S9  29  30 16   9 10  6    30  2  29 8   9   60  223
1 1
  S29  S9    60  223  223
60 60
8.
Ans: C
Sol : A1,2 , B  4cos ,4sin 
 P divides the lines segment AB in the ratio 3: 2
2 1,2   3  4cos ,4sin  
P  x, y  
3 2
 5 x  2  12cos ,5 y  4  12sin 
2 2
 2  4  144
locus of P is  x     y    , a circle
 5  5 25
2 4 3 5
 C   ,   AC 
5 5 5
9.
Ans: C
Sol :
x 6 y z 8 x 5 y 7 z  2
Point of intersection of lines   and  
1 2 5 4 3 1
x y 6 z 8 x 5 y 7 z  2
    and   k
1 2 5 4 3 1
x    4k  5 | y  2  6  3k  7 | z  5  8  k  2
 k  1,   1 and A  1,4, 3
x 6 y z 8 x 3 3 y z 6
Point of intersection of lines   and  
1 2 5 6 3 1
x y 6 z 8 x 3 y 3 z 6
    and   k
1 2 5 6 3 1
x    6k  3| y  2  6  3k  3| z  5  8  k  6
 k  1,   3 and B   3,0,7 
Midpoint C   2,2,2
4  4  2  14
Distance of C from the plane 2 x  2 y  z  14 is 4
4  4 1
10.
Ans: A
1 1
Sol : Probability of getting odd  Probability of getting even 
2 2
n
 n  1 
probability of getting odd numbers seven times =    
 7  2 
n
 n  1 
probability of getting odd number nine times =    
 9  2 
n n
 n  1   n  1 
Given           n  7  9  16
 7  2   9  2 
NARAYANA IIT Academy, India Jee Mains-SPL.GTM-6_08.03.2024
16 16
16  1 16 15  1 
probability of getting even number twice     
60
   16
 2  2  2  2 2
11.
Ans: B
Sol :
g  x   f  x   f 1  x 
g 1  x   f 1  x   f 1 1  x 
1
x
2
1 1 1
g1    f 1    f 1    0
2 2 2
1
g1    0
2
g 11  x   f 11  x   f 11 1  x   0
Concave upwards
1
 
2
tan 1  tan 1  2   tan 1  3
1

  5 
    tan 1  
4  1 6 
 
   
4 4
12.
Ans: D
Sol :
1  21   2022 
2022 22

 
3  1 divisible by '3'
  1
1  21   2023  1
2022 22

 1  7    7  1
  2

α2  β 2  1  22  5
13.
Ans: A
Sol :
 a1  2,3,4
b2   8,12  9,12 8,12 
 a1, b2   3  2  6
similarly,  a2 , b1   6
Total  36
14.
Ans: C
Sol :
 fi  62
 3k 2  4k  2  62
16
 k  4  or 
3

 2 2
  fi x 2
 fi

 0  6   1  8   2
2 2 2
      
 15  32  15  42  17  52  1
62
8
15.
Ans: A
Sol :
 pv   p  q   
 pv  p q  
p pq
16.
Ans: B
Sol :
 d  t ab  

 t 35i  13 j  21k 
i j k
a  b  2 7 1
3 0 5
 35i  13 j  21k
c.d  12
35t  13t  42t  12
t  2
1 1 1
 ^ ^ ^
 

  i  j  k  . c  d  1 1  2  44
70 26 42

17.
Ans: C
Sol :
A a

Q P
B C

c
D
b 

Let p be the origin

bc
PD 
2
PA  PB  PC  a  b  c
PQ  a  b  c

PA  PB  PC  PQ
18.
Ans: C
2x
 x
Sol : Let   t
e
 2 x  ln x  1  ln t
1
dx  dt
2t
 1 1
I  t  
 t  2t
1  1
 t    c
2 t 
2x 2x
1 x 1 e 
I        c
2 e  2 x 
   2,   2,   2,   2
  2  3  4  4
19.
Ans: C
Sol :
2 z  3i
is real
4 z  2i
2 x  i  2 y  3 4 x  i  4 y  2 

4x  i  4 y  2 4x  i  4 y  2
imaginary part  0
2 x  4 y  2   4 x  2 y  3  1 
0   4 x 2   4 y  2 2  0, x  0, y  
 4x 2
  4 y  2
2
 2 

20.
Ans: B
Sol :
a 2  19, b 2  15  a  b 

Let y  mx  19m2  15 bea Tangent to the ellipse

 19m2  15
4
1  m2
3m2  1
1
m  
3
30 ,150
0 0
with major axis 
Therefore, angle with minor axis is 600
21.
Ans: 16
a  2d a  d
Sol. Let terms be 2
, , a ,  a  d  r ,  a  2d  r 2
r r
a2
2  2d 2  d 49
  2   2  d  2   2  2d  4 
4 2 2
d  1
a4   2  2  4  16
22.
Ans: 27
Sol. X2 2 Y  X

 2 1 2 2
As shown in figure find point of intersection

For x  0, 2  2  x2  x  x  1

For x   2,   x2  2  x  x  2
2 2
Area    x  2  x  dx    x  x  2dx
2 2

1 2
2
x2 x3 2 x 2 x3
  2x     2x
2 3 1 2 3 2

9 8 2
 
  6 A  16 2  27
23.
Ans: 529
Sol. point of intersection of two given sides is  1, 7  which does not lie of AC.
C  3, 2 
D
5 x  4 y  23 M
3x  7 y  23

B  1, 7  A  4, 5 
2 x  3 y  23  0
Solve for A & C
A 4, 5 C  3,2
 1 7
Mid point M   , 
 2 2
BM y  7  7  x  1
7x  y  0
28  5 23
d 
50 50
50d 2  529
24.
Ans: 7
Sol.
A  4, 3,1

B  5,  ,  
 3, 4,  1
N

x  y  2z  3  0
x  4 y  3 z 1
   1
1 1 2
3, 4, 1
Length AN 
 4  3  2  3  6
6
1
Area   6  BN  3 2
2
 BN  2 3
B lies on plane 5    2   3  0
  2  8    1
BN 2  12 i.e.  5  3    4     1  12
2 2 2

3
  3, 
5
  z   3,   2
 2   2    4  9  6  7
25.
Ans: 24
Sol.
6 3 3
2 6 4  0
3 2 3
108 3  84  24  0
1 2
  1,  , 
3 3
For each  equations will have no solution.
 1 2
12 1     24
 3 3
26.
Ans: 26664
Sol. Units place 2 appears 6 times
1 appears 3 times
3 appears 3 times
Units place sum  6  2  1 3  3 3
 12  3  9  24
Total sum  24 1  10  100  1000 
 24  1111
 26664
27.
Ans: 11
Sol. y  ax2  bx  c
a b  c  0
a  b  c 1
1 1
ac  ,b 
2 2
 dy
 2ax  b at x  1
dx
2a  b  1
1 1 1
a  , b  , c 
4 2 4
Now  ,   1 satisfies it
2 
1
 1   
4 2 4
   3 (in 1st quadrant)
dy
2
dx
1
mN  
2
1
y  4    x  3
2
2 y  8  x  3
x  2 y 11  0
y  0  x  11
28.
Ans: 24
 2x 
Sol. y  sec1  
 5x  3 
2x
 1
5x  3
7x  3
0
5x  3
 3 3
x   ,  
 5 7
2x
1
5x  3
3x  3
0
5x  3
 3
x  1,  
 5
 3   3 3
 x  1,      ,  
 5  5 7
3  10       21  24
29.
Ans: 6

Sol. 1   2 
2
E
x tan  2
2
C D
x tan 1 x tan 1
1
A x B
3BE  4 AB
3 x  tan 1  tan  2   4 x
4
tan 1  tan  2     1
3

Also 1   2 
2
 tan 1.tan 2  1
4
They are roots of x 2  x 1 0
3
1
 x  3 or
3
1
tan  2  3 tan 1 
3
Area of CAB  2 3  3
x 2 tan 1
  2 3 3
2
 x  3 3
perimeter  x  x tan 2  x sec2  6
30.
Ans: 5 (NTA key is 6, key change)
2
 dx 
Sol. PA  y 1   
 dy 
2
 dy 
PB  x 1   
 dx 
 B p

A
k 0
PA  y dx  1
  
PB  x dy  k
dy dx
y   k x
k
ln y  ln x  ln c
k
 ln c x
k
yc x
Satisfying points c  1, k  2
1 dy
y  log  2 x  1
x2 dx
 2 x  1 log 2 x  1  1  c
dy
dx
 log 2 x  1  y 
2
   
5
y  0  2  c 
2
4 y 1  6log3  6  10
 6log3  4
4 y 1  5log3e  4  log3e  5.09
Answer will be 5

PHYSICS
31.
Ans: B
Sol. The speed of electromagnetic wave in vaccum is
E0
c
B0
E0 CB0 3 108 6 10 7
180 Vm 1

32.
Ans: D
Total displacement x1 x2
Sol : Average velocity v
Total time of journey t1 t2
 x1 x2 x x
V
x1 x2 x x
V1 V2 V1 V2
2 1 1
V V1 V2
33.
Ans: D
Sol :
D1
I4
25 125

D3

I2 25 125
I1

 
25
5V
Diodes D1 , D2 conduct current while D2 doesn’t conduct current.
I1
I2 I4
2
I1
2
I2
34.
Ans: B
Sol : Zero error is positive
e 6 L.C 6 0.01 cm 0.06 cm
Measured Reading =M.S.R+ n L.C
D 3.20 4 0.01 3.24 cm
Correct Reading = Measured reading + correction
3.24 0.06
=3.18 cm
35.
Ans: B
Sol : Intensity at any point on screen in YDSE
I I max cos 2 / 2 where = phase difference between waves
 Ip cos 2 /6 3/ 4 3
IQ cos 2 /4 1/ 2 2
36.
Ans: C
f
Sol : Internal energy of n moles of gas is U nRT where f= degrees of freedom
2
T= temperature of gas
For mono atomic gas f=3
For diatomic gas f=5
Total internal energy of mixture of O2 and Ne gases is
f1 f2
U n1 RT n2 RT
2 2
5 3
U 2 RT 4 RT
2 2
U 11RT
37.
Ans: D
Sol : Acceleration due to gravity (g) depends on rotation of earth as
g g R 2cos 2 where = latitude, anguler speed of rotation of earth
At poles 900 g g
At equator 00 g g R 2

At poles acceleration due to gravity is independent on rotation of earth.

38.
Ans: C
Sol : According to Einestein’s photo electric equation
E Kmax
Where work function h 0

Kmax maximum K.E of ejected photo electrons = eV0

E= energy of incident photon = h
h eV0
h
V0 v
e e
From graph at v v0 5 1014 Hz , V0 0V
34
6.63 10 5 1014 J
6.63 10 34 5 1014
eV
1.6 10 19
2.07eV
39.
Ans: B
 Y sin t cos t
Sol : Y 2 sin t cos 450 cos t sin 450
Y 2 sin t 450
amplitude A 2
40.
Ans: D
Sol : According to lenz’s law, there is an opposition for motion of magnet when flux associated
with tube changes with time. Due to change in flux, eddy currents are developed in tube
which offers retarding force on magnet. After some time, speed of magnet increases due to
which eddy currents increases so more opposition for magnet.
Finally at some instant retarding force balance the weight of magnet so it moves with
constant speed.
41.
Ans: B
Sol : For adiabatic process dQ  0
dU  dW  0
dU  dW
Adiabatic compression leads to raise in temperature of gas.
Hence internal energy decreases.
42.
Ans: D
Sol : Under applied electric field electrons drift opposite to field direction.
i.e, from low to high potential
As electrons move they undergo collision with lattice, hence they wont move in straight
line.
43.
Ans: B
I
Sol : χ 
H
For diamagnetic I developed is very less and directed opposite to applied H.
Hence 1  χ  0
44.
Ans: A
2π 3/2 2π
Sol : T  r   R  h 3/2
GM GM
Here h  R, GM  gR2
2π 2π
T   2R  
3/2
8R3/2  32R
gR 2 πR
Sol : Even after external supply is withdrawn fan continues to be in it’s previous state of motion
due to it’s property of inertia.
46.
Ans: C
Sol :

A
47.
Ans: D
Sol :

metal plate

0 A 3 0 A
C2
d d
0 A
C1 3
d
C2
3
d 2d C1
d
3 3
48.
Ans: B
FL
Sol : y1 1 A1 1
e
y2 4 , A2 3, AY
e1 A2 Y2
F1 F2 F, 3 4 12
e2 A1 Y1
L1 L2 L , e1 : e2 12 :1
49.
Ans: A
2
u 2 sin 2 30 1
H1 2g 2 1
Sol :
H2 u sin 2 60
2
3
2
3
g 2
50.
Ans: A
51.
Ans: 44
Sol. Let say i=2.5 sin700t
  a 2 0 ni
d di
ind   a 2 0 n
dt dt
as a  2.0cm, n  50 turns / cm  5000Turns / m
So ind   0.02  4 107  5000  2.5  700cos 700t
2

ind max  44 104 volt

 x  44
52.
Ans: 2
Sol. Magnetic field at the center ‘O’ will be only due to curved wire. So
μ0i 4π  107  14
Bnet  
4r 4  2.2  102
 Bnet  2  104 Tesla
53.
0
Ans: 3668 A
Sol. Lowest wavelength in Lyman series will be
1 1 1 
λL
 RZ 2    ...... i 
 12  2 
and in Balmer series
1  1 1 
λB
 RZ 2    .... ii 
 22  2 
on dividing , equation  i  /  ii 
λB 0 0
 4  λB  4  917 A  3668 A
λL

54.
Ans: 8
Sol.
 +

+ e
mv 2
+ eE r
+
+
+

For Circular motion

mv 2
eE 
r
λ mv 2
 e. 
2π 0 r r

eλ 1.6  1019  2  108  2  9  109

v 
2π 0 m 9  1031
v  8  106 m / sec
55.
Ans: 48
Sol. Net force exerted by string on elevator.
T   600  800  10  2000
T  16000 N
Power delivered by motor
P  T .v  16000  3  48000watt
P  48KW
56.
Ans: 3
Sol.
y  axis

x  axis

 2, 3
 
r   0   2iˆ  3 ˆj 
r  2iˆ  3 ˆj
F   Pkˆ
T r F
  
 2iˆ  3 ˆj   Pkˆ 
 2 Pjˆ  3Piˆ
Hence a  3P and b  2P
a 3 x
So  
b 2 2
 x 3
57.
Ans: 20
Sol. In SHM
F  mω2 x
Fmax  mω2 A
2
2 2π 
Fmax  mω A  5     1  20 N
 3.14 
58.
Ans: 34
Sol. For L1,
u  6cm, f  24cm
1 1 1
   Lens formula 
v 6 24
1 1 1
   v  8cm
v 24 6
for L2 , u   10  8  18cm
f  9cm
1 1 1 1 1 1
    
v 18 9 v 9 18
 v  18cm
Hence final image is formed at the distance of 18cm from L2.
OI  6cm  10cm  18cm  34cm
59.
Ans: 3
 ρl
Sol. As R 
A
3  107  1 102
R  3
4
100  10
60.
Ans: 80
Sol. From equation of continuity
A1v1  A2v2
2cm2  4cm / sec  10mm2  v2
2
v2  4cm / sec  80cm / sec
10  102

CHEMISTRY
61.
Ans: A
Sol.
OCH 3 OCH 3 OCH 3
anh AlCl3

NO2
 H
NO2
NO2
Cl

62.
Ans: B
Sol :
O

H 2 NC
(i) LiAlH 4
H2 N
O (ii) H 3O  OH

63.
Ans: A
Na2CO3 .10 H 2O  washing soda 
Sol :
Na2CO3  Soda ash
64.
Ans: C
Sol :
C6 H 5 C6 H 5
Na
CH 2 CH  CH CH 2  CH CH 2  CH 2  CH CH  CH 2  CH  CH 2  n

65.
Ans: A
Sol : Reductive Ozonolysis of alkene gives carbonyl compounds.
Oxidative ozonolysis of alkene gives carbonyl compounds and corboxylic acid.
66.
Ans: B
Sol :
OH
OH OH

O  O  O  CH 3OH  CH  C  OH
3 3

NO2 OCH3

(-M) (+M) (+I.E)

Acidic strength decreases

67.
Ans: A
Sol : Respiration
68.
Ans: C
Sol : Physical property of isotopes of hydrogens are different due to different mass number.
Mass difference between isotopes of hydrogen is very high.
69.
Ans: D
Sol : According to Elingam diagram “C” can reduced FeO .
70.
Ans: B
Sol : H 2C2O4 .2 H 2O  Molecular weight  126 
wt 1000
M 
mol.wt volume (ml )

3.15 1000
M   0.1 .
126 250
71.
Ans: A
Sol : Mg 2 has high charged density than Mg 
Hence High energy is required to conversion of Mg to Mg 2
72.
Ans: A
Sol : Metalic character increases from top to bottom and decreases from left to right
73.
Ans: B
3
 Fe F6   Co F6   Cr  oxalate 3    Fe (CN )6    Ni  CO 4 
3 3 3
Sol :
74.
Ans: C
Sol :
O

CH 2  O  C  C17 H 35
O
OH
CH  O  C  C17 H 35  3NaOH  3C17 H 35COONa  OH
O
OH
CH 2  O  C  C17 H 35
75.
Ans: C
Sol : a  2 2r & 4r  3a

76.
Ans: D
Sol : 1-II, 2-IV, 3-I, 4-III.
77.
Ans: A
Sol : FeCl3 is a positive sol.
78.
Ans: D
Sol : Higher the stability of carbocation lower will be hybride affinity.

79.
Ans: B
Sol : CFSE  0.4 t2 g ( x)  0.6eg ( y)  0
80.
Ans: A
Sol : Addition of BaCl2 gives white precipitate of BaSO4 .Among the gives compounds only
Methionine has sulphur atoms.
81.
Ans: 1or 3
Sol. In strong Alkaline medium
MnO4 changes to MnO42
Change in oxidation state is 1
 no.of e gained=1

In weak Alkaline medium

MnO4 changes to MnO2
Change in oxidation state is 3
 no.of e gained=3
82.
Ans: 3
Sol.
A g  2B g   C g 
450mm 0 0
450  x 2 x x
450  2 x  720
2 x  720  450
2 x  270
x  135
 0.3  3 101
135
Fraction of ‘A’ decomposed
450
83.
Ans: 1
Sol. e in nth orbit
Jumped nth to  n  1 orbit of Li 2 by absorppivity 1.47 1017 J
th
  1 1 
En 1  En  13.6  Z 2    ev
 n2  n  12 
 
 1 
19  1   1.47  1017
13.6  9  1.6  10 
n 2
 n  1 
2

1 1 3
 
n 2
 n  1 2 4

n  1
84.
Ans: 66
Sol.
K L  5  105 scm1
M  0.0025M
1000
m  k 
m
5  105  103
m 
0.0025

m  400
cm 20
   0.05

m
400

cα 2
Ka   66
1 α
85.
Ans: 2
Sol. XeF4  H 2O  Xe  XeO3
Both compounds are XeF4 and give same product.
Change in oxidation state =2
86.
Ans: 1
Sol. Statements A, B & D are correct
Molecularity never be fractional
87.
Ans: 4
Sol.
 I 2  2 I , H  ve
HCl  H  Cl , H  ve
H 2O l   H 2O g ; H ve
C  O2  CO2 H  ve
NH 4Cl  H 2O  so ln, H  ve

88.
Ans: 4
Sol. μ  4.90

no.of unpaired e  4

89.
Ans: 4
Sol. H 2O, N2 , CO, XeF4 has two lone pairs on each

90.
Ans: 40535
Sol. V  300ml
wt  0.63g
π  1.29mbar
π  CST
1.29  103 
0.63 1000
  0.083  300
M 300
M  40534.8
M  40535