Chemistry May 2022

D D
F2 E4DD9AA96 69D C6 46D 57B BDF FAAA0B

E 6 4
2E 4D 9A9 9669 9DC C64 6D5 57B DFAAA0 0BF FA5
4D 9A 6 D 6 6D 7 DF A B A D
4D 9A 966 69D C64 46D 57B BDF AA 0B FA5 5D7 7CF
9 C 5 F 2
D9 9A9 669 9DC 646 6D5 7BDDFAAA0 0BF A5DD7C CF2 E4D
A9 669 DC 64 D5 7B FA A0 BF A5 7C F2 E4D 9A
9A 66 D 6 6D 7B DF A B A D7 F E4 9 9
4 5 6
A9 9669 9DC C64 6D5 57B DFAAA0 0BF FA5 D7C CF2 2E4DD9AA96 69D
6 6 7 D A D E 6 C
96 69DDC6 646DD57 BD FAAA0B BFA 5D 7CF F2E 4D9 9A9 9669 9DC 646
69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 66 D 64 D
69 DC 646 D5 7BD FA A0 BFA 5D 7C F2E 4D 9A 966 9D C64 6D 57B
D 6 7 B 9 C 5
I.
9D C6 46DD57 BDF FAAA0B FA 5D7 7CF F2E4 4D9 9A9 669 9DC 646 6D5 7BDDFA
C 46 57 BD A 0 FA 5D C 2E D A 66 DC 64 D 7B F A
DC 64 D5 B F A BF 5 7C F2 4D 9A 96 9D 6 6D 57 D AA 0B
6.
5.
4.
3.
2.
1.
64 6D5 7B DF AA 0BF A5 D7 F2 E4 9A 96 69D C6 46D 57 BD FAA 0B FA
Q1.
6D 7B DF AA 0B A D7 CF E4 D9 9 69 C 46 5 BD FA 0 FA 5D
DATE: 05/07/2022
57 D AA 0B FA 5D CF 2E D9 A9 669 DC 646 D5 7BD FA A0 BF 5D 7C
Option C:
Option B:
Option C:
Option B:
Option C:
Option B:
Option C:
Option B:
Option C:
Option B:
Option A:
Option A:
Option A:
Option A:
Option A:
Option D:
Option D:
Option D:
Option D:
Option D:
BD FA 0 F 5D 7C 2E 4D A 66 D 64 D 7B F A B A5 7 F2
Time: 2hour
FA A0 BF A5D 7C F2E 4D 9A 966 9D C64 6D 57B DF AA 0B FA5 D7 CF E4
A0 BF A5D 7C F2 4D 9A 966 9D C64 6D 57B DF AA 0B FA D7 CF 2E4 D9
BF A5 7C F2 E4D 9A 96 9D C6 6D 57 D AA 0B FA 5D CF 2E D9 A9
A5 D7 F2 E4 9A 96 69D C6 46D 57 BD FA 0B FA 5D 7CF 2E 4D A9 669
D7 CF E4 D9 96 69 C 46 57 BD FA A0 FA 5D 7C 2E 4D 9A 66 DC
CF 2E D9 A9 69 DC 646 D5 BD FA A0 BF 5D 7C F2 4D 9A 966 9D 64
2E 4D A9 669 DC 64 D5 7B FA A0 BF A5 7C F2 E4D 9A 96 9D C6 6D
4D 9A 66 D 64 6D 7B DF A B A5 D7 F E4 9 96 69D C6 46D 57
0.008 V.
0.594 V.
Course Code: FEC203
9A 966 9D C6 6D 57B DF AA 0B FA D7 CF 2E4 D9 A9 69 C 46 57 BD
- 0.008 V.
- 0.594 V.
96 9D C6 46D 57 D AA 0B FA 5D CF 2E D9 A9 669 DC 646 D5 BD FA
69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 66 D 64 D 7B F A
Galvanizing.
Option C: Solar energy.
Sherardizing.
DC 64 D5 7B F A BF 5 7C F2 4D 9A 96 9D C6 6D 57 D AA 0B
Anodic coating.
8805.80kcal/kg.
8205.80 kcal/kg.
8877.80 kcal/kg.
8277.80 kcal/kg.
Cathodic coating.
Option B: Electronic energy.

Option A: Ultrasonic energy.
Porous stable film.

Volatile oxide film.

Synthesis of Indigo.
Unstable oxide film.

Option D: Geo-thermal energy.
present in a molecule:
Synthesis of Carbaryl.
Multiple Choice Questions:
Non-porous oxide film.

Synthesis of adipic acid.

NOTE: All Questions are Compulsory.
Synthesis of Benzimidazole.
Energy efficient chemical synthesis.

All Programs

Atomic Weights: C = 12, H = 1, O = 16, N = 14, S = 32
are compulsory and carry 2 marks each.

University of Mumbai
A0BFA5D7CF2E4D9A9669DC646D57BDFA
Examination: FE Semester II_FH2022
Coating of tin on iron is an example of ………………

Curriculum Scheme: Rev2019 (‘C’ Scheme)

BD FA 0 F 5D 7C 2E 4D A 66 D 64 D 7B F A B A5 7 F
FA A0 BF A5D 7C F2E 4D 9A 966 9D C64 6D 57B DF AA 0B FA5 D7 CF
A0 BF A5D 7C F2 4D 9A 966 9D C64 6D 57B DF AA 0B FA D7 CF 2E
BF A5 7C F2 E4D 9A 96 9D C6 6D 57 D AA 0B FA 5D CF 2E
A5 D7 F2 E4 9A 96 69D C6 46D 57 BD FA 0B FA 5D 7CF 2E 4
D7 CF E4 D9 96 69 C 46 57 BD FA A0 FA 5D 7C 2E 4D
CF 2E D9 A9 69 DC 646 D5 BD FA A0 BF 5D 7C F2 4D
potential of the cell is -------. Given E0Ni = - 0.257 V and E0Cu = 0.337 V
Nobel metals do not undergo oxidation corrosion because it forms_______
%, N = 3 %, S = 2%, Ash = 7 %. Calculate H.C.V. using Dulong’s formula

2E 4D A9 669 DC 64 D5 7B FA A0 BF A5 7C F2 E4D 9
Max. Marks: 60
4D 9A 66 D 64 6D 7B DF A B A5 D7 F E4 9
QP CODE: 95145
9A 966 9D C6 6D 57B DF AA 0B FA D7 CF 2E4 D9 A

Choose the correct option for following questions. All the Questions
Course Name: Engineering Chemistry- II
96 9D C6 46D 57 D AA 0B FA 5D CF 2E D9 A9
A sample of coal has following composition by mass C =70 %, O = 8 %, H = 10

69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 6
A cell is constructed from Ni+ 2 / Ni and Cu+2/Cu half cells. The standard
====================================================================
One of the following is an example, explaining principle of green chemistry of

As per the principle of spectroscopy one of the following is the type of energy
DC 64 D5 7B F A BF 5 7C F2 4D 9A 96
=====================================================================
64 6D5 7B DF AA 0BF A5 D7 F2 E4 9A 96 6
6D 7B DF AA 0B A D7 CF E4 D9 9 69
1T01832 - F.E.(SEM II)(ALL BRANCHES) (Rev - 2019-20) 'C' Scheme) / 29713 - Engineering Chemistry - II
57 D AA 0B FA 5D CF 2E D9 A9 669
BD FA 0 F 5D 7C 2E 4D A 66 D
FA A0 BF A5D 7C F2E 4D 9A 966 9D
A0 BF A5D 7C F2 4D 9A 966 9D C6
D D
E 6 4
4D 9A 6 D 6 6D 7 DF A B A D
9 C 5 F 2
9A 66 D 6 6D 7B DF A B A D7 F E4 9 9
4 5 6
6 6 7 D A D E 6 C
69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 66 D 64 D
D 6 7 B 9 C 5
C 46 57 BD A 0 FA 5D C 2E D A 66 DC 64 D 7B F A II.
F
F
E
B
E
B
D
C
A
D
C
A
Q3
Q2
transitions.
Descriptive Questions:
cinnamaldehyde.
C6H5CHO + CH3CHO
Explain by giving examples.

→
suitable diagram and representation.

Solve any Four Questions out of Six:

the green chemistry principles involved.

is the standard potential of Ag electrode?
Cu(s)/ Cu+2 (aq)(1M)// Ag+(aq)(1M)/ Ag(s)
Given Atomic Weights: C = 12, H = 1, O = 16.
The standard emf of the following cell is 0.462 V.
protection? Discuss any one with the help of a suitable diagram.
Explain Differential aeration corrosion with diagram and reactions.

Explain how corrosion of iron article takes place in acidic medium.
C6H5CH-CHCHO + H2O
was absorbed in 40 ml of 0.5 N H2SO4. After absorption, the excess
1.0%, N= 1.5% and ash= rest. (Molecular weight of air = 28.94 gm).
subjected to ultimate analysis 2.45 g of coal on combustion in a Bomb-

Define Spectroscopy. Also explain the origin of spectrum with diagram.
What is a Reference electrode? Explain any one Reference electrode with

4 Marks each
4 Marks each
Calculate the minimum weight and volume of air required for the complete
H2SO4 required 18.5 ml of 0.5N KOH for neutralization. A coal sample was
4D 9A 66 D 64 6D 7B DF A B A5 D7 F E4 9
What is the principle of cathodic protection? What are the two types of cathodic
Explain the conventional and green route of manufacturing indigo dye. Mention
combustion of 1 kg of fuel containing C= 80%, H= 6%, O=8%, S= 1.5%, H2O=

Write the cell reaction. If the standard potential of Cu electrode is 0.337 V, what
By Kjeldahl’s method 3 gm of coal sample was analyzed. The ammonia evolved
Colorimeter gave 0.67 of BaSO4. Calculate percentage of Nitrogen and Sulphur.

69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 6
What are ‘oxygenates’ used in the fuel industry? Where and why are they added?
Calculate the percentage atom economy for the following reaction with respect to
Give the classification of spectroscopy on atomic and molecular basis (Tree

Diagram). Explain the selection rule no.2. Δl = + - 1 of spectroscopy for electron
DC 64 D5 7B F A BF 5 7C F2 4D 9A 96
64 6D5 7B DF AA 0BF A5 D7 F2 E4 9A 96 6
6D 7B DF AA 0B A D7 CF E4 D9 9 69
57 D AA 0B FA 5D CF 2E D9 A9 669
BD FA 0 F 5D 7C 2E 4D A 66 D
A0 BF A5D 7C F2 4D 9A 966 9D C6
D D
E 6 4
4D 9A 6 D 6 6D 7 DF A B A D
9 C 5 F 2
9A 66 D 6 6D 7B DF A B A D7 F E4 9 9
4 5 6
6 6 7 D A D E 6 C
69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 66 D 64 D
D 6 7 B 9 C 5
C 46 57 BD A 0 FA 5D C 2E D A 66 DC 64 D 7B F A
F
E
B
D
C
A
Q4
reactions and diagram.
(ii) Position of metal in galvanic series.
2.5 %, H2 = 35%, CO2 = 2%, O2 = 2.5%

Biodiesel and two advantages of biodiesel.
(i) Relative areas of anodic to cathodic part

spectroscopy and corresponding energy changes.
Differentiate between Electrolytic and Galvanic cell.
Given Atomic Weights: C = 12, H = 1, O = 16, N = 14.

How do the following factors affect the rate of corrosion?
Explain the working Catalytic converter with the help of any two chemical
4D 9A 66 D 64 6D 7B DF A B A5 D7 F E4 9
4 Marks each
Give in tabular form the relation between electromagnetic spectrum, types of
What is Biodiesel? Give the trans-esterification reaction of the preparation of

Calculate the volume of air required for complete combustion of 1m3 of gaseous
69 C 46 5 BD FA 0 FA 5D 7C 2E 4D A 6
fuel having the following composition: CO = 5%, C2H4 = 10%, CH4 = 40%, N2 =
DC 64 D5 7B F A BF 5 7C F2 4D 9A 96
64 6D5 7B DF AA 0BF A5 D7 F2 E4 9A 96 6
6D 7B DF AA 0B A D7 CF E4 D9 9 69
57 D AA 0B FA 5D CF 2E D9 A9 669
BD FA 0 F 5D 7C 2E 4D A 66 D
A0 BF A5D 7C F2 4D 9A 966 9D C6

Chemistry May 2022

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D D

F2 E4DD9AA96 69D C6 46D 57B BDF FAAA0B

57 D AA 0B FA 5D CF 2E D9 A9 669 DC 646 D5 7BD FA A0 BF 5D 7C

9A 966 9D C6 6D 57B DF AA 0B FA D7 CF 2E4 D9 A9 69 C 46 57 BD

Option B: Electronic energy.

Porous stable film.

Volatile oxide film.

Unstable oxide film.

A0 BF A5D 7C F2 4D 9A 966 9D C64 6D 57B DF AA 0B FA D7 CF 2E4 D9

Non-porous oxide film.

Synthesis of adipic acid.

Energy efficient chemical synthesis.

57 D AA 0B FA 5D CF 2E D9 A9 669 DC 646 D5 7BD FA A0 BF 5D 7C

A0 BF A5D 7C F2 4D 9A 966 9D C64 6D 57B DF AA 0B FA D7 CF 2E4 D9

Coating of tin on iron is an example of ………………

96 9D C6 46D 57 D AA 0B FA 5D CF 2E D9 A9 669 DC 646 D5 BD FA

Nobel metals do not undergo oxidation corrosion because it forms_______

%, N = 3 %, S = 2%, Ash = 7 %. Calculate H.C.V. using Dulong’s formula

9A 966 9D C6 6D 57B DF AA 0B FA D7 CF 2E4 D9 A

A sample of coal has following composition by mass C =70 %, O = 8 %, H = 10

One of the following is an example, explaining principle of green chemistry of

Explain by giving examples.

suitable diagram and representation.

Solve any Four Questions out of Six:

the green chemistry principles involved.

Explain Differential aeration corrosion with diagram and reactions.

A0 BF A5D 7C F2 4D 9A 966 9D C64 6D 57B DF AA 0B FA D7 CF 2E

was absorbed in 40 ml of 0.5 N H2SO4. After absorption, the excess

subjected to ultimate analysis 2.45 g of coal on combustion in a Bomb-

What is a Reference electrode? Explain any one Reference electrode with

combustion of 1 kg of fuel containing C= 80%, H= 6%, O=8%, S= 1.5%, H2O=

By Kjeldahl’s method 3 gm of coal sample was analyzed. The ammonia evolved

Colorimeter gave 0.67 of BaSO4. Calculate percentage of Nitrogen and Sulphur.

Give the classification of spectroscopy on atomic and molecular basis (Tree

2.5 %, H2 = 35%, CO2 = 2%, O2 = 2.5%

FA A0 BF A5D 7C F2E 4D 9A 966 9D C64 6D 57B DF AA 0B FA5 D7 CF E4

96 9D C6 46D 57 D AA 0B FA 5D CF 2E D9 A9 669 DC 646 D5 BD FA

Give in tabular form the relation between electromagnetic spectrum, types of

What is Biodiesel? Give the trans-esterification reaction of the preparation of

9A 966 9D C6 6D 57B DF AA 0B FA D7 CF 2E4 D9 A

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