1.0 C a r i n e _ A M _ 1 6 - 1 9 _ 2 _ 1 H .

e s p
0.9
0.8

Normalized Intensity

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0.02
9

5
4
Chemical Shift (ppm)

0.04 0.03 0.08 0.23 0.68

3

-1

31.90

10

0.01

C a r in e _ A M _ 1 6 - 1 9 _ 2 _ 1 3 C . e s p
1.0
0.9

18.77
11.98
11.85

31.65

42.30
37.26

36.14
28.23
24.29
19.03 19.39

12.23

0.2

129.27

0.3

56.87
55.96

140.75

0.4

56.76
56.06
50.13
45.84

0.5

71.79

77.26
77.00
76.75
121.69

0.6

138.29

Normalized Intensity

0.7

21.08

0.8

0.1
0
220

200

180

160

140

120
100
80
Chemical Shift (ppm)

60

40

20

-20

2
4
6

F1 Chemical Shift (ppm)

21.67

19.82
11.99 18.79
11.87

40.49

19.40

36.15

56.88
55.97
51.25

138.30

0.5

129.29

C a r in e _ A M _ 1 6 - 1 9 _ 2 _ D E P T . e s p

-0.5

21.10

28.25
33.96
31.67
37.27
42.30

-1.0

220

200

180

160

140

120
100
80
Chemical Shift (ppm)

60

40

20

-20

50

100

5
4
F2 Chemical Shift (ppm)

F1 Chemical Shift (ppm)

Normalized Intensity

5
4
F2 Chemical Shift (ppm)

31.91
31.88

56.78
56.07
45.85

71.80

121.71

50

100

150

200
9

5
4
F2 Chemical Shift (ppm)

F1 Chemical Shift (ppm)