Potentiometric titration data Potentiomet

Date Titrant Sample Date

5/22/2017 AgNO3 Cl- 5/22/2017
Ct / (mol/L) = 1.00E-02
Titr. No. Ind. electr. Ref. electr. 25 mL Titr. No.
6693 Pt Ag/AgCl 1
EP1 / mL 2.7900
EP2 / mL
EP3/ mL
Pos. Vt / mL E / mV dE/dV Note Pos.

1 0 374.3 0 374.3 1
2 0.01 376.5 31.2 2
3 0.02 378.1 24.9 3
4 0.03 378.5 13.9 4
5 0.046 379.2 7.6 5
6 0.212 381.3 4.1 6
7 0.489 383.9 2.5 7
8 0.787 386 2.4 8
9 1.101 388.7 2.6 9
10 1.404 391.7 3.1 10
11 1.698 395.3 3.7 11
12 1.974 399 4.9 12
13 2.247 404.6 7.3 13
14 2.461 411.6 11.3 14
15 2.615 419.6 17.3 15
16 2.717 428.3 25.4 16
17 2.773 435.9 32 17
18 2.807 443 33.2 18
19 2.83 446.1 31.1 19
20 2.854 449.7 28.6 20
21 2.922 458.8 24.4 21
22 3.007 466.2 18.5 22
23 3.121 473.5 13.1 23
24 3.26 479 9.2 24
25 3.441 484 6.8 25
26 3.655 488.8 5.3 26
27 3.887 492.8 4.3 27
28 4.141 496.3 3.5 28
29 4.413 499.4 2.9 29
30 4.698 501.9 2.5 30
31 5 504.4 2.2 31
32 5.305 506.5 2 32
33 5.62 508.7 1.8 33
34 5.934 510.6 1.6 34
35 6.255 512 1.5 35
36 6.589 513.8 1.4 36
37 6.915 515.3 1.3 37
38 7.247 516.4 1.2 38
39 7.59 517.9 1.1 39
40 7.924 518.9 1 40
41 8.27 519.7 0.9 41
42 8.622 520.8 1 42
43 8.967 521.8 0.9 43
44 9.314 522.8 0 44
45 9.661 523.7 0 45
46 10 524.6 0 46
47 47
48 48
49 49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
 Potentiometric titration data
Titrant Sample
NaOH H3PO4
Ct / (mol/L) = 0.0910
Ind. electr. Ref. electr. 25 mL
pH Ag/AgCl
EP1 / mL 4.8720
EP2 / mL
EP3/ mL
Vt / mL pH dpH/dV Note

0 2,440 0
0.1 2,447 7
0.2 2,454 7
0.3 2,461 7
0.4 2,469 8
0.5 2,476 7
0.6 2,484 8
0.7 2,492 8
0.8 2,499 7
0.9 2,507 8
1 2,513 6
1.1 2,520 7
1.2 2,531 11
1.3 2,539 8
1.4 2,551 12
1.5 2,564 13
1.6 2,579 15
1.7 2,596 17
1.8 2,613 17
1.9 2,635 22
2 2,655 20
2.1 2,675 20
2.2 2,703 28
2.3 2,721 18
2.4 2,747 26
2.5 2,777 30
2.6 2,806 29
2.7 2,836 30
2.8 2,873 37
2.9 2,912 39
3 2,951 39
3.1 3,001 50
3.2 3,052 51
3.3 3,112 60
3.4 3,182 70
3.5 3,260 78
3.6 3,375 115
3.7 3,517 142
3.8 3,725 208
3.9 4,188 463
4 5,060 872
4.1 5,516 456
4.2 5,734 218
4.3 5,869 135
4.4 5,981 112
4.5 6,072 91
4.6 6,148 76
4.7 6,211 63
4.8 6,274 63
4.9 6,332 58
5 6,382 50
5.1 6,436 54
5.2 6,485 49
5.3 6,531 46
5.4 6,581 50
5.5 6,630 49
5.6 6,674 44
5.7 6,720 46
5.8 6,763 43
5.9 6,817 54
6 6,862 45
6.1 6,910 48
6.2 6,961 51
6.3 7,013 52
6.4 7,067 54
6.5 7,124 57
6.6 7,195 71
6.7 7,265 70
6.8 7,343 78
6.9 7,433 90
7 7,556 123
7.1 7,690 134
7.2 7,889 199
7.3 8,099 210
7.4 8,443 344
7.5 8,737 294
7.6 8,932 195
7.7 9,122 190
7.8 9,283 161
7.9 9,401 118
8 9,531 130
8.1 9,630 99
8.2 9,725 95
8.3 9,817 92
8.4 9,907 90
8.5 9,981 74
8.6 10,050 69
8.7 10,113 63
8.8 10,172 59
8.9 10,213 41
9 10,267 54
9.1 10,312 45
9.2 10,348 36
9.3 10,385 37
9.4 10,420 35
9.5 10,450 30
9.6 10,480 30
9.7 10,510 30
9.8 10,534 24
9.9 10,558 24
 10 10,580 22
10.1 10,603 23
10.2 10,622 19
10.3 10,641 19
10.4 10,660 19
10.5 10,679 19
10.6 10,695 16
10.7 10,711 16
10.8 10,726 15
10.9 10,740 14
11 10,755 15
11.1 10,769 14
11.2 10,783 14
11.3 10,797 14
11.4 10,810 13
11.5 10,822 12
11.6 10,835 13
11.7 10,847 12
11.8 10,859 12
11.9 10,869 10
12 10,880 11
12.1 10,891 11
12.2 10,901 10
12.3 10,910 9
12.4 10,921 11
12.5 10,930 9
12.6 10,938 8
12.7 10,948 10
12.8 10,956 8
12.9 10,963 7
13 10,971 8
 NaCl titration
600

500

400
E / mV

300

200

100

0
0 1 2 3 4 5
V / mL
 H3PO4 titration
12,000

10,000

8,000
pH

6,000

4,000

2,000

0
0 2 4 6 8
V / mL
 NaCl titration
35

30

25

20

dE/dV
15

10

0
3 4 5 6 7 8 9 10
V / mL
H3PO4 titration
1000

900

800

700

600

dpH/dV
500

400

300

200

100

0
6 8 10 12 14
V / mL
 35

30

25

20
dE/dV

15

10

0
10
 1000

900

800

700

600
dpH/dV

500

400

300

200

100

0
14