n= 17

ngr= 2

ETAPA 1:

F1: d1= 104 km

F2: d2= 1410 km
F3: d3= 391 km

Puterea instalatiei energetice: P= 468 MW

Durata anuala de functionare a fiecarui grup energetic da= 7978 h/an
Durata de viata a fiecarui grup energetic dv= 60 ani
UF=E= P*da*dv= 2.24E+08 MWh

Etapa 2: Determinarea necesarului de combustibil pentru fiecare filiera si etapa a ciclului de viata analizat

2.1 Compozitia gazului natural

CH4= 0.8172
C2H6= 0.0232
C3H8= 0.03685
C4H10= 0.03885
C5H12= 0.03585
H2S= 0.0006
CO2= 0.04745

2.2 Puterea calorifica inferioara a gazelor naturale

PciCH4= 35774 kJ/m3N MCH4=

PciC2H6= 63669 kJ/m3N MC2H6=
PciC3H8= 91138 kJ/m3N MC3H8=
PciC4H10= 118489 kJ/m3N MC4H10=
PciC5H12= 160000 kJ/m3N MC5H12=
PciH2S= 55000 kJ/m3N MH2S=
MCO2=
PCi= 44442.37 KJ/kg

2.3 Densitatea gazului natural

ρ= 0.997112 Kg/m3

2.4 Compozitia elementala a carbunelui

C= 0.625
H= 0.097
N= 0.001
 S= 0.0238
O= 0.2
W= 0.02
A= 1.9668

2.5 PCi a carbunelui

PCi= 29434.79 KJ/kg

2.6 Randamentele globale pentru fiecare filiera si etapa a ciclurilor de viata analizate

F1 si F3 (carbune) F2 (gaze naturale)

ηex= 0.835 ηex= 0.78 ηTA=

ηtr= 0.936 ηtr= 0.905 ηTG=
ηtp= 0.916 ηtp= 0.899 ηCC=

2.7 Determinarea necesarului de combustibil pentru fiecare filiera si etapa a ciclului de viata analizat

McbF1= 9.65E+10 kg
McbF2= 4.38E+10 m3N
McbF3= 4.01E+10 kg
Cant
MexF1= 1.35E+11 kg Mex
MtrF1= 1.13E+11 kg Mtr
MtpF1= 1.05E+11 kg Mtp
Mcb
MexF2= 6.91E+10 m3N
MtrF2= 5.39E+10 m3N
MtpF2= 4.88E+10 m3N

MexF3= 5.6E+10 kg
MtrF3= 4.67E+10 kg
MtpF3= 4.37E+10 kg

ETAPA 3:

F1 F2
Etapa de extractie [g/kg] Etapa de extractie [g/m3N]
NO2 (ex1) 0.135 NO2 (ex2)
NO(ex1) 0.00994 NO(ex2)
CO2 (ex1) 1.65 CO2 (ex2)
CO (ex1) 0.0064 CO (ex2)
SO2 (ex1) 0.000123 SO2 (ex2)
CH4 (ex1) 0.91 CH4 (ex2)
N2O (ex1) 0.00012 N2O (ex2)
Praf (ex1) 0.002251 Praf (ex2)

Etapa de tratare [g/kg] Etapa de tratare [g/m3N]

NO2 (tr1) 0.09 NO2 (tr2)
NO(tr1) 0.00894 NO(tr2)
CO2 (tr1) 2.745 CO2 (tr2)
CO (tr1) 0.0216 CO (tr2)
SO2 (tr1) 0.02137 SO2 (tr2)
CH4 (tr1) 0.00751 CH4 (tr2)
N2O (tr1) 0.000125 N2O (tr2)
Praf (tr1) 0.001236 Praf (tr2)

Etapa de transport [g/kg] Etapa de transport[g/m3N]

NO2 (tp1) 0.5616 NO2 (tp2)
NO(tp1) 0.21736 NO(tp2)
CO2 (tp1) 10.4208 CO2 (tp2)
CO (tp1) 0.17628 CO (tp2)
SO2 (tp1) 0.000194 SO2 (tp2)
CH4 (tp1) 1.13568 CH4 (tp2)
N2O (tp1) 0.000155 N2O (tp2)
Praf (tp1) 0.014425 Praf (tp2)

ETAPA 4: Recalcularea emisiilor tinand cont de unitatea functionala (etapele extractie, tratare, transport)

F1 F2
Etapa de extractie [g/kg] Etapa de extractie [g/m3N]
NO2(r) (ex1) 1.82E+10 NO2(r)(ex2)
NO(r)(ex1) 1.34E+09 NO(r)(ex2)
CO2(r) (ex1) 2.22E+11 CO2(r) (ex2)
CO(r)(ex1) 2.91E+09 CO(r) (ex2)
SO2(r) (ex1) 16561836 SO2 (r)(ex2)
CH4(r)(ex1) 1.23E+11 CH4(r)(ex2)
N2O(r)(ex1) 16211464 N2O(r)(ex2)
Praf(r)(ex1) 3.03E+08 Praf(r)(ex2)

Etapa de tratare [g/kg] Etapa de tratare [g/m3N]

NO2 (tr1) 1.01E+10 NO2(r) (tr2)
NO(tr1) 1.01E+09 NO(r)(tr2)
CO2 (tr1) 3.09E+11 CO2 (r)(tr2)
CO (tr1) 2.43E+09 CO(r) (tr2)
SO2 (tr1) 2.4E+09 SO2(r) (tr2)
CH4 (tr1) 8.45E+08 CH4(r) (tr2)
N2O (tr1) 14023799 N2O(r) (tr2)
Praf (tr1) 1.39E+08 Praf(r) (tr2)
Etapa de transport [g/kg] Etapa de transport[g/m3N]
NO2(r) (tp1) 5.91E+10 NO2(r) (tp2)
NO(r)(tp1) 2.29E+10 NO(r)(tp2)
CO2(r) (tp1) 1.1E+12 CO2(r) (tp2)
CO(r) (tp1) 1.86E+10 CO(r)(tp2)
SO2(r) (tp1) 20483015 SO2 (r)(tp2)
CH4(r)(tp1) 1.2E+11 CH4(r) (tp2)
N2O(r) (tp1) 16320691 N2O(r)(tp2)
Praf(r)(tp1) 1.52E+09 Praf (r)(tp2)

Etapa 5. Emisiile rezultate in urma arderii complete

5.1, Determinarea emisiilor de CO2

F1 CO2 2.23E+11 kg
F3 CO2 9.25E+10 kg
F2 C 306.3507 kg
Mase molare
CH4 13.0752
C2H6 0.696
C3H8 1.6214
C4H10 2.2533
C5H12 2.5812
H2S 0.0204
CO2 2.0878
Masa amestecului 22.3353 kg/kmol
GKCH4 58.54052
GKC2H6 3.116144
GKC3H8 7.259361
GKC4H10 10.08851
GKHC5H12 11.55659
GKCO2 9.347535
GK TOTAL 99.90866

5.2. Determinarea emisiilor de particule solide

Combustibili solizi
ηd-randamentul instalatiei de d 0.995
A-cantitatea de cenusa 0.033
q4-pierderile de caldura 0.004
Hi-Pci carbune 29434.79
aa=fractia de cenusa antrenata 0.05
Mps1 28657.71 kg
Mps2 2E+12 kg
 5.3. Determinarea cantitatilor de SOx

η'-fractia de oxizi de sulf eliminata in insta 0.02

η"-fratia de oxizi de sulf absorbita in part 0.15
MSOx1 3.87E+12 kg
MSOx2 1.61E+12 kg

5.4. Determinarea cantitatii de NOX

5.4.1. Determinarea NOx -combustibili gazosi

β1 coeficient care tine cont de 0.85

k-coeficient de sarcina 10
Mcb1-Mcb2
Hi-Pci a gazului natural 44442.37
β2-coeficient care tine cont de 0.025
r-gradul de recalculare a gazelo 0.25
β3-coeficient care tine cont de t 1
q4 0.004
MNOx1 1.23E+15 kg
MNOx2 6.58E+14 kg

5.4.2 Determinarea NOx - combustibili gazosi

10.17683 kg/GJ

ẞw- factor de infuenta care tine 2.624

ẞp-factor de infuenta care tine 0.826
ẞo-factor de infuenta care tine 0.925
ẞr-factor de infuenta care tine 0.731
ẞλ-factor de infuenta care tine 0.992

6.Stabilirea si determinarea indicatorilor de impact

GwP-global warning protection

GwP CO2 1 kg echivalenteCO2/poluant
GwP CH4 21 kg echivalenteCH4/poluant
GwP N2O 310 kg echivalenteN2O/poluant

F1extractie 20.79729 kg echiv C F1 tratare 3.31E+11 kg echiv CO2

F2extractie 26.60323 kg echiv C F2 tratare 1.25E+11 kg echiv CO2
F3extractie 1.13E+12 kg echiv C F3 tratare 1.4E+11 kg echiv CO2

GwPex GwPTr GwPtp GwPcb

F1 trasport 3.61E+12 kg echiv C F1 20.79729 3.31E+11 3.61E+12 2.23E+11
F2 transport 2.96E+13 kg echiv C F2 26.60323 1.25E+11 2.96E+13 306.3507
F3 transport 5.82E+12 kg echiv C F3 1.13E+12 1.4E+11 5.82E+12 9.25E+10

GwPcb1 2.23E+11 kg echiv

GwPcb2 306.3507 kg echiv
GwPcb3 9.25E+10 kg echiv

6.2 Potentialul de acidificare

APNH3 1.6 kgechivSO2/kgpol

APNOX 0.5 kgechivSO2/kgpol
APSOX 1.2 kgechivSO2/kgpol

F1 extracti 9.79E+09 kgechivSO2F1 transpo 4.1E+10 kgechivSO2/kgpol

F2 extracti 4.06E+09 kgechivSO2F2 transpo 1.79E+11 kgechivSO2/kgpol APNex
F3 extracti 4.35E+09 kgechivSO2F3 transpo 4.98E+10 kgechivSO2/kgpol f1 9.79E+09
f2 4.06E+09
f3 4.35E+09
F1 tratare 8.45E+09 kgechivSO2APNcb1 6.2E+14 kgechivSO2/kgpol
F2 tratare 3.24E+09 kgechivSO2APNcb2 3.31E+14 kgechivSO2/kgpol
F3 tratare 3.13E+09 kgechivSO2APNcb3 9.9E+26 kgechivSO2/kgpol

6.3 Potentialul de eutrofizare

EpNo2 0.13 kg echivPO4/kgPoluant

EpNo2 0.15 kg echivPO4/kgPoluant

F1 extracti 2.57E+09 kg echivPOf1Transport1.11E+10 kgechivPO4/Kgpoluant

F2 extracti 1.07E+09 kg echivPOf2transpor 4.86E+10 kgechivPO4/Kgpoluant F1
F3 extracti 1.14E+09 kg echivPOf3Transpor 1.37E+10 kgechivPO4/Kgpoluant F2
F3
F1tratare 1.47E+09 kg echivPOF1cb 1.6E+14 kgechivPO4/Kgpoluant
F2tratare 5.97E+08 kg echivPOF2cb 8.56E+13 kgechivPO4/Kgpoluant
F3tratare 5.16E+08 kg echivPOF3cb 1.85E+14 kgechivPO4/Kgpoluant

6.4 Potentialul de toxicitate uman

HTPNOx 1.2 kgechivDCB/kgpoluant
HTPSOx 0.096 kgechivDCB/kgpoluant
HTPpraf 0.82 kgechivDCB/kgpoluant

F1 extracti 2.37E+10 kgechivDCF1 transpo 1E+11 kgechivDCB/kgpoluant

F2 extracti 9.85E+09 kgechivDCF2 transpo 4.37E+11 kgechivDCB/kgpoluant F1
F3 extracti 1.11E+10 kgechivDCF3 transpo 1.21E+11 kgechivDCB/kgpoluant F2
F3
F1 tratare 1.37E+10 kgechivDCF1cb 1.48E+15 kgechivDCB/kgpoluant
F2 tratare 4.39E+11 kgechivDCF2cb 7.9E+14 kgechivDCB/kgpoluant
F3 tratare 1.21E+11 kgechivDCF3cb 1.48E+15 kgechivDCB/kgpoluant

6.5 Potentialul de poluare fotochimica

POCPCCH4 1.2 kgechivC2H6/kgpot

POCPNOx 0.096 kgechivC2H6/kgpot
POCPCO 0.027 kgechivC2H6/kgpot

F1 extracti 1.49E+11 kgechivC2 F1 transpo 1.52E+11 kgechivC2H6/kgpot

F2 extracti 9.94E+10 kgechivC2 F2 transpo 1.18E+12 kgechivC2H6/kgpot
F3 extracti 5.99E+10 kgechivC2 F3 transpo 2.52E+11 kgechivC2H6/kgpot F1
F2
F1 Tratare 2.15E+09 kgechivC2 F1cb 1.18E+14 kgechivC2H6/kgpot F3
F2 Tratare 8.66E+08 kgechivC2 F2cb 1.78E+13 kgechivC2H6/kgpot
F3 Tratare 7.54E+08 kgechivC2 F3cb 6.32E+13 kgechivC2H6/kgpot

6.6 Consumul de resusrse neregenerabile

ADP carbu 0.0667 kgechivalent/kgpotential

ADP gaza n 0.0187 kgechivalent/kgpotential

ADPex ADPtotal
F1 8.99E+09 8.99E+09
F2 1.29E+09 1.29E+09
F3 3.73E+09 3.73E+09
16 g/mol
30 g/mol
44 g/mol
58 g/mol
72 g/mol
34 g/mol
44 g/mol
 0.284
0.414
0.684

de viata analizat

F1[kg] F2[m3N] F3[kg]

1.35E+11 6.91E+10 5.6E+10
1.13E+11 5.39E+10 4.67E+10
1.05E+11 4.88E+10 4.37E+10
9.65E+10 4.38E+10 4.01E+10

F3
extractie [g/m3N] Etapa de extractie [g/kg]
0.109 NO2 (ex3) 0.145
0.0085 NO(ex3) 0.0101
1.57 CO2 (ex3) 1.68
0.0074 CO (ex3) 0.0074
7.03E-05 SO2 (ex3) 0.000125
1.19 CH4 (ex3) 0.88
0.000139 N2O (ex3) 0.00012
 0.001865 Praf (ex3) 0.0153

tratare [g/m3N] Etapa de tratare [g/kg]

0.0696 NO2 (tr3) 0.074
0.0136 NO(tr3) 0.0095
2.14 CO2 (tr3) 2.82
0.0179 CO (tr3) 0.0189
0.01546 SO2 (tr3) 0.02106
0.00634 CH4 (tr3) 0.00634
0.000143 N2O (tr3) 0.00013
0.001294 Praf (tr3) 0.001254

transport[g/m3N] Etapa de transport [g/kg]

5.2593 NO2 (tp3) 1.45843
2.0868 NO(tp3) 0.81719
195.99 CO2 (tp3) 35.9329
1.7625 CO (tp3) 0.68425
0.002105 SO2 (tp3) 0.000742
19.458 CH4 (tp3) 4.6138
0.006373 N2O (tp3) 0.000594
0.188094 Praf (tp3) 0.055287

ele extractie, tratare, transport)

F3
extractie [g/m3N] Etapa de extractie [g/kg]
7.53E+09 NO2(r) (ex3) 8.11E+09
5.87E+08 NO(r)(ex3) 5.65E+08
1.08E+11 CO2(r) (ex3) 9.4E+10
5.11E+08 CO(r) (ex3) 4.14E+08
4852901 SO2(r)(ex3) 7008600
8.22E+10 CH4(r) (ex3) 4.92E+10
9632586 N2O(r) (ex3) 6740028
1.29E+08 Praf(r)(ex3) 8.56E+08

tratare [g/m3N] Etapa de tratare [g/kg]

3.75E+09 NO2(r) (tr3) 3.46E+09
7.33E+08 NO(r)(tr3) 4.44E+08
1.15E+11 CO2(r) (tr3) 1.32E+11
9.64E+08 CO(r) (tr3) 8.83E+08
8.33E+08 SO2(r) (tr3) 9.84E+08
3.42E+08 CH4(r)(tr3) 2.96E+08
7707368 N2O(r)(tr3) 6067094
69714341 Praf(r) (tr3) 58587215
transport[g/m3N] Etapa de transport [g/kg]
2.56E+11 NO2(r) (tp3) 6.38E+10
1.02E+11 NO(r)(tp3) 3.57E+10
9.56E+12 CO2(r) (tp3) 1.57E+12
8.59E+10 CO(r)(tp3) 2.99E+10
1.03E+08 SO2(r) (tp3) 32435848
9.49E+11 CH4(r)(tp3) 2.02E+11
3.11E+08 N2O(r)(tp3) 25989715
9.17E+09 Praf(r) (tp3) 2.42E+09
Gwptotal
4.17E+12
2.97E+13
7.18E+12

APNtr APNtp APNcb APNtotal

8.45E+09 4.1E+10 6.2E+14 6.2E+14
3.24E+09 1.79E+11 3.31E+14 3.31E+14
3.13E+09 4.98E+10 9.9E+26 9.9E+26

EpNex EpNtp EpNtr EpNcb EpNtotal

2.57E+09 1.11E+10 1.47E+09 1.6E+14 1.6E+14
1.07E+09 4.86E+10 5.97E+08 8.56E+13 8.56E+13
1.14E+09 1.37E+10 5.16E+08 1.85E+14 1.85E+14
HTPex HTPtr HTPtp HTPcb HTPtotal
2.37E+10 1.37E+10 1E+11 1.48E+15 1.48E+15
9.85E+09 4.39E+11 4.37E+11 7.9E+14 7.91E+14
1.11E+10 1.21E+11 1.21E+11 1.48E+15 1.48E+15

POCPex POCPtr POCPtp POCBcb POCBtotal

1.49E+11 1.52E+11 2.15E+09 1.18E+14 1.19E+14
9.94E+10 1.18E+12 8.66E+08 1.78E+13 1.9E+13
5.99E+10 2.52E+11 7.54E+08 6.32E+13 6.35E+13