LIQUID1 LIQUID1

MOLEFRAC TOTAL KVL TOTAL KVL

PRES TOTAL TEMP GAMMA GAMMA TOTAL BETA
WATER WATER ACETI-01 WATER ACETI-01
kPa C
26,664 0 79.3512 173,037 1 1 1 1
26,664 0.02 78.9788 170,436 1 1 1 1
26,664 0.04 78.6137 167,917 1 1 1 1
26,664 0.06 78.2557 165,478 1 1 1 1
26,664 0.08 77.9044 163,114 1 1 1 1
26,664 0.1 77.5598 160,821 1 1 1 1
26,664 0.12 77.2214 158,597 1 1 1 1
26,664 0.14 76.8891 156,438 1 1 1 1
26,664 0.16 76.5627 154,342 1 1 1 1
26,664 0.18 76.2419 152,305 1 1 1 1
26,664 0.2 75.9267 150,326 1 1 1 1
26,664 0.22 75.6168 1,484 1 1 1 1
26,664 0.24 75.3121 146,528 1 1 1 1
26,664 0.26 75.0123 144,705 1 1 1 1
26,664 0.28 74.7174 14,293 1 1 1 1
26,664 0.3 74.4272 141,202 1 1 1 1
26,664 0.32 74.1414 139,517 1 1 1 1
26,664 0.34 73.8602 137,876 1 1 1 1
26,664 0.36 73.5832 136,275 1 1 1 1
26,664 0.38 73.3103 134,714 1 1 1 1
26,664 0.4 73.0415 13,319 1 1 1 1
26,664 0.42 72.7766 131,703 1 1 1 1
26,664 0.44 72.5156 130,251 1 1 1 1
26,664 0.46 72.2582 128,833 1 1 1 1
26,664 0.48 72.0044 127,448 1 1 1 1
26,664 0.5 71.7542 126,094 1 1 1 1
26,664 0.52 71.5074 124,771 1 1 1 1
26,664 0.54 71.2639 123,477 1 1 1 1
26,664 0.56 71.0237 122,212 1 1 1 1
26,664 0.58 70.7867 120,974 1 1 1 1
26,664 0.6 70.5527 119,762 1 1 1 1
26,664 0.62 70.3218 118,576 1 1 1 1
26,664 0.64 70.0938 117,415 1 1 1 1
26,664 0.66 69.8686 116,278 1 1 1 1
26,664 0.68 69.6463 115,165 1 1 1 1
26,664 0.7 69.4267 114,073 1 1 1 1
26,664 0.72 69.2098 113,004 1 1 1 1
26,664 0.74 68.9954 111,956 1 1 1 1
26,664 0.76 68.7837 110,929 1 1 1 1
26,664 0.78 68.5743 109,921 1 1 1 1
26,664 0.8 68.3675 108,933 1 1 1 1
26,664 0.82 68.163 107,963 1 1 1 1
26,664 0.84 67.9609 107,012 1 1 1 1
26,664 0.86 67.761 106,079 1 1 1 1
26,664 0.88 67.5634 105,162 1 1 1 1
26,664 0.9 67.3679 104,263 1 1 1 1
26,664 0.92 67.1746 103,379 1 1 1 1
26,664 0.94 66.9834 102,512 1 1 1 1
26,664 0.96 66.7943 10,166 1 1 1 1
26,664 0.98 66.6071 100,823 1 1 1 1
26,664 1 66.4219 1 1 1 1 1
 VAPOR VAPOR LIQUID1 LIQUID1
MOLEFRAC MOLEFRAC ACETI- MOLEFRAC MOLEFRAC ACETI-
WATER 01 WATER 01

0 1 0 1
0.0340871 0.965913 0.02 0.98
0.0671668 0.932833 0.04 0.96
0.0992866 0.900713 0.06 0.94
0.130491 0.869509 0.08 0.92
0.160821 0.839179 0.1 0.9
0.190317 0.809683 0.12 0.88
0.219014 0.780986 0.14 0.86
0.246947 0.753053 0.16 0.84
0.27415 0.725851 0.18 0.82
0.300651 0.699349 0.2 0.8
0.326481 0.673519 0.22 0.78
0.351666 0.648334 0.24 0.76
0.376232 0.623768 0.26 0.74
0.400204 0.599796 0.28 0.72
0.423605 0.576395 0.3 0.7
0.446455 0.553545 0.32 0.68
0.468777 0.531223 0.34 0.66
0.49059 0.509411 0.36 0.64
0.511911 0.488089 0.38 0.62
0.53276 0.46724 0.4 0.6
0.553153 0.446847 0.42 0.58
0.573105 0.426895 0.44 0.56
0.592633 0.407367 0.46 0.54
0.61175 0.38825 0.48 0.52
0.630471 0.369529 0.5 0.5
0.648809 0.351191 0.52 0.48
0.666776 0.333224 0.54 0.46
0.684385 0.315615 0.56 0.44
0.701646 0.298354 0.58 0.42
0.718572 0.281428 0.6 0.4
0.735172 0.264828 0.62 0.38
0.751457 0.248543 0.64 0.36
0.767436 0.232564 0.66 0.34
0.783119 0.216882 0.68 0.32
0.798514 0.201487 0.7 0.3
0.81363 0.186371 0.72 0.28
0.828475 0.171525 0.74 0.26
0.843057 0.156943 0.76 0.24
0.857383 0.142617 0.78 0.22
0.871462 0.128538 0.8 0.2
0.885299 0.114701 0.82 0.18
0.898901 0.101099 0.84 0.16
0.912275 0.0877246 0.86 0.14
0.925428 0.0745723 0.88 0.12
0.938364 0.0616359 0.9 0.1
0.95109 0.0489098 0.92 0.08
0.963612 0.0363884 0.94 0.06
0.975934 0.0240664 0.96 0.04
0.988061 0.0119386 0.98 0.02
1 0 1 0
Grafica Txy a 26,664 KPa
Pa
 2,6664 KPa
water Acid
T [K] x1 [mol/mo y1 [mol/mol x2 [mol/mo y2 [mol/mo
l] ] l] l]
303.15 0 0 1 1
298.35 0.3002 0.374 0.6998 0.626
297.35 0.4576 0.5237 0.5424 0.4763
296.85 0.6392 0.7019 0.3608 0.2981
296.25 0.7742 0.8161 0.2258 0.1839
295.95 0.8588 0.8923 0.1412 0.1077
295.55 0.928 0.9493 0.072 0.0507
295.25 0.9667 0.9809 0.0333 0.0191
295.25 0.9674 0.9799 0.0326 0.0201
295.25 0.9883 0.9945 0.0117 0.0055
295.25 0.993 0.997 0.007 0.003
 26,664 KPa
water Acid
T [K] x1 [mol/mo y1 [mol/mol x2 [mol/mo y2 [mol/mo
l] ] l] l]
353.05 0 0 1 1
344.45 0.3084 0.404 0.6916 0.596
343.05 0.4546 0.573 0.5454 0.427
341.45 0.633 0.7337 0.367 0.2663
340.65 0.7699 0.8396 0.2301 0.1604
340.05 0.8578 0.8992 0.1422 0.1008
339.85 0.927 0.9493 0.073 0.0507
339.55 0.967 0.9779 0.033 0.0221
339.55 1 1 0 0
 1

0.9
x=y

y (mole fraction of water in vapor)

0.8
x y
0 0 0.7
0.1 0.1 0.6
0.2 0.2
0.5
0.3 0.3
0.4 0.4 0.4

0.5 0.5 0.3

0.6 0.6 0.2
0.7 0.7
0.1
0.8 0.8
0.9 0.9 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.
1 1
x (mole fraction of water in liquid)

T-xy Water - Acetic Acid

85

80

75
Temperature ºC

70

65

60

55
0 0.1 0.2 0.3 0.4 0.5 0.6
Vapor/Liquid Mole fraction of wate
 Equilibrium L-
V
Auxiliar line
(x=y)
Experimental

0.6 0.7 0.8 0.9 1

water in liquid)

ater - Acetic Acid

0.4 0.5 0.6 0.7 0.8 0.9 1

Liquid Mole fraction of water