WHAT TO LOOK FOR IN AN ULTRAVIOLET SPECTRUM: A PRACTICAL GUIDE Ieivoties dificult oestract a grou! deat of petonuttion trea UV spect ve a UV’ spectrin is atest wee Tis sete a feast a geri lov canbe sppvient Never er garde our use oF LV alata, User seneraligtions ae at red amt NME iat which con. cor instatce. seticety identity eatboard seoups. dest oy sponta cli Iroc By toben oo as gutetelnes binge wit int Inle Bundy, aromatics} toms, nit 2 weer NMR deta she usa unincates rasta Amines, aleethks, ethers. and thinks aze possiblities Livsiagated system, An exception ta this pret te nogioaed coe tins ate ot inctuced sciteraization iy that the a * 7 transite of 68 ghuips | CaN sapped sh this region symp is easily lentil in the i However, ts vst weak tansicn (= Da not negicet tilock for No HLO H.C. O,andS Hibamds an the intiazel spect, 1250) B60 nm, wath ae suonrtant ct ste on eswaily aieates a0 waselengtiy & simple. ar unconie dle generally onic that ovatus an O, Nut § stom, Ex ‘Onev Since the absorp ruphove is undies include 0, © N.N&N. ONO. CDOR, COOH. wr CONT sit NMR spect ples of this shay 1 Thves buna ef cairn intensity = LAND fe 10,000), Both lt yyy, above OEE ne ally tnalicabe the p J del nb Hise Seuctars us tite Tonger-wave ington an tho tiratne dings tare the wnokes abyerptis ty above 10,000, ssetice of an atownatte span, Us arosmaitic systean 1s presen. there ary I had fan nonpolar sofveats ony Vachs tee suistituert tne teases rhe femstt the gottfuested system, i 2000 nna, a band that 1 obsereed Mist polymuelesr eto. Li posyatucess wists stbstann es tts bard aye 7 camatiss eects bebo 20 nie, avhere i cannot A ristie nteasits and ietasbape spectra Het sre stand hetevweyelie eompoundst Hane set Uh Hise-structure) patterns, ata tes mas atten be ideatitied ets enmparisn tavailabig ia the Etevacure. The zevthawks by Fate sand Oxclut seid ay Seott, whick are Th the references at tle etal Bs © re good Sousses of spect 1 MO nm generally represe thy rte fist ws HD. sek the in ted spe, the inp ae Wo A. Kandy of ther aa ee ansaturated het reacet the Temat oF tk the 4 ing obveorved tavele wand Fieser Rules (Section 7.10 oiay he ealeutated a sysents dst ive sary De npr caved eleven pases Mone fae absetpoens. any 2 A Atstort 1 rn fens amenity Fan i 08 > tharabion al shower svete Wish con fe poeaicted hy Winds geal’s Rules Sects lon Fete HE A, OE Eke Fo" Bard anes hh 1 The sale deals vise ove LOGE sath ie an Puy the wether mo fester Ne Sen's Risley ‘Section 7 LS amay be used 9 pre os solic arate cbraraop iene Joa -scnann conqutenl 3 tee Benenson eonrponutals fay Be cwoved thes: Have etoeasls cetpasabiyg substituents, ne tamatcatitiy ews (Us a rienica af fost to tive se nagulod entropies ace require tu puoatice absorp ton the visible region, However Couple tico aea ralene, deaibezo. ply nt, 6 isaeado compass may als yas mnas tronty compounds ith quinoa! retireouoreuuggp op vogeiqA = 9) woreauojep ap uonesCIA {a} vogebvon,p uoteqs mt ( uoRBUQIA op eouenbeuy ye esNjoN|S es}Ue BEnosEyU] USKOW 8] SUP LORE/ELI0D ep Nesiqe | 1722.2 HOW TO APPROACH THE ANAL (OR WHAT YOU CAN AT A GLANCE) When analyzing the spectrum of anv presence Ur abagnces of a fo Ca, CaN, aud NO. if they ate present. Do not try to make almost all compounds have the nent in whi fe your tiest elforts un determi 60, UM, NOH CHO, 0 0, sand give immediate struc st sonspicu fa! infor adetailed U absorptions near 3000 ext pions, Do nol worry about subtleties of the exuct énvive h the functional aroup is found, Following is a majur els aaly sis of ist oF 2 Ianportant goose J. ts a carbonyl gruup present? The C= 1820-1660 cm’ '. The peak is often 1 baniss it, | gisiup gives rise to a strong absorption iu the regio. f¢ strongest itt the spectrm and of medium w7 th, You 2. IFC=O is presemt, check the following types (IF is absent, yo to 3), ACIDS : 18 OH also present? + brad absorption near 34GD-2400 en (usually overlaps coin AMIDES Is NH also present? + Medium absorption near 3400 e145 sometimes a cube peak with equivalent halves, ERS 1s C-O also present? + Strony-tntensity absorptions near 1360-1600 em ANHYDRIDES Two Co-O absweptinns near 1810 snd 1760 cia ALDEHYDE Isaldzhyde CH présent? 0 weak ubsorptiqns near 2850 and 2759 cm”! on sight he wipbatie CH abs KETONES She preceding five choice site of ave been elimin 1 C=Q ig ghsont ALCOUOLS, PHENOLS Chek for uh + Broad ssexption nvity 3400-3300 em! ~Onwar LO TURN em | AMINES, Chee’ for SH 33i0en + Medtiunn absorptiontst ETHERS Cheek for CO near 13RD WGN em* Gaul absence O Hear SOO em 5. Double boudy aneor atinnitie rings + CoC ie weak absorption near 16S! > Meditia tu stony, abserptions iat 1400 1450 ey these often inply sn ssomatic ring uble hon nr uroinatic rans by Contselting cde sie and vinyl C Hphetle CH aceues tthe right of this yaloet iyo beginning stadent showld resist the idea of tying 40 as itn eeoups bons: sections that follow. CoN isa medium, a Ca.C isa weak, sharp absor Cheek alse for Two strofig absorptions at 1600-1 1390-1300 env, p absorption near 2250 ent ny aear 2550 en etylenic C “If near 3300 cnr! 30em fan’ None of the preceding is found Major absorptions are in CH region near 30007F vi uum, You sitnply will not be able to do it, Concentrate first on learning these majar peaks or interpret every peak in t simple spectrum: the only other absorptions appear pear L460 and 1375 env, nd their presence or absence. This is best done by carefully studying de iustrative spec