0.0 0.5 1.0 1.5 2.

0
0
1
2
3
4
5
6
7
8
(a)
(b)
(C)
[I
2
] (mmol.L
-1
)
t (heure)
CHIMIE: (7points)
Exercice n1:( 4 points)
A un instant t=0, on ralis! un s"st#m! $%imi&u! !n mlan'!ant !n mili!u a$i(! un )olum! *1=50 mL (+un! solution
a&u!us! (! ,!ro-"(! (+%"(ro'#n! (!au o-"'n!) .2/2 (! $on$!ntration 01 a)!$ un )olum! *2=50 mL (+un!
solution a&u!us! (+ions tartrat! 04.4/6
2-
(! $on$!ntration 02=0,8 mol.L
-1
. A $! s"st#m!, on a1out! (!s $ristau- (!
$%lorur! (! $o2alt (II) .
A)!$ l! t!m,s, un ('a'!m!nt 'a3!u- ,r!n( naissan$! !t l! s"st#m! !st l! si#'! (+un! ra$tion $%imi&u!
(+&uation 4
5 .2/2 5 04.4/6
2-
5 2 .3/
25
6 10 .2/ 5 4 0/2
La $our2! (! la 7i'ur! $i-$ontr! r!,rs!nt! l!s
)ariations (! la &uantit (! mati#r! (!s ions tartrat!
04.4/6
2-
au $ours (u t!m,s
1 - 0!tt! ra$tion !st-!ll! ra,i(! ou l!nt!8 9usti7i!r
2 - :r!ss!r un ta2l!au (!s$ri,ti7 (+)olution (u s"st#m! .
3 - ;ans 7air! (! $al$ul, ,r$is!r l! ra$ti7 limitant .
4 - a)- <ontr!r &u! l+a)an$!m!nt 7inal (! $!tt! ra$tion
)aut4 =>= 3. 10
-2
mol .
b)- :(uir! la )al!ur (! 01
5 - :7inir l! t!m,s (! (!mi-ra$tion !t (t!rmin!r sa )al!ur .
- ?u!l !st l! r@l! (!s ions $o2alt 0o
2 5
.
Exercice n2:( 3 points)
/n )!ut tu(i!r la $inti&u! (+un! ra$tion l!nt! !ntr! l!s ions io(ur!s I
-
!t l! ,!ro-"(! (+%"(ro'#n! .2/2 !n mili!u
a$i(!. La $on$!ntration (! (iio(! I2 !st (t!rmin! !-,rim!ntal!m!nt ,ar s,!$tro,%otomtri!. Aour $!la, on utilis!
trois mlan'!s ,r,ars (! la 7aBon sui)ant! 4
L!s $our2!s sui)ant!s (onn!nt l!s $on$!ntrations !n (iio(! 7orm !n millimol! ,ar litr!, !n 7on$tion (u t!m,s 4
1
L"$! s!$on(air! !ciences "h#si$ues :at!4 04 -11-200C
(! Da1!rouin! :ur!4 2 .!ur!s
0lass!s4 4 <
2
.

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r
4 .ammami Lot7i Ann!4 200CE2010
L"$! s!$on(air! !ciences "h#si$ues :at!4 04 -11-200C
(! Da1!rouin! :ur!4 2 .!ur!s
0lass!s4 4 <
2
.

<
r
i7toL imamma. 4 4!nnA 0102EC002
9 mL
Eau distille
8 mL
0 81 Lm
01 Lm
2 Lm
1 Lm 01 Lm
01 Lm
euqiruflus edicA (M 1) IK ed noituloS (M 1,0) engyxo uaE (M 1,0)
01 Lm 01 Lm 2 Lm
(1) egnalM
(2) egnalM
egnalM (3)
06 04 02
(nim) t
n )
!
"
!
#
$
%2
( (lom)
0
40,0
1 - ;a$%ant &u! l+&uation (! la ra$tion tu(i! !st4 .2/2 5 2 I
-
5 2 .3/
5
6 I2 5 2 .2/
Ar$is!r l! r@l! (! l+a$i(! sul7uri&u! a1out F $%a&u! mlan'! .
2 - G!m,lir l! ta2l!au sui)ant 4
3 - Attri2u!r $%a&u! $our2! F $%a&u! mlan'! !n 1usti7iant la r,ons! .
4 - L!s ra$tions s! sont-!ll!s t!rmin!s (ans l!s trois mlan'!s 8
5- a)- <ontr!r &u! la )it!ss! (! la ra$tion s+!-,rim! ,ar4 *=
[ ]
dt
I d
V
s
2
. oH *s r!,rs!nt! l! )olum! (u mlan'!.
b)- $al$ul!r la )al!ur (! $!tt! )it!ss! F l+instant t=1 %!ur!. utilisant la $our2! (2)
"h#si$ue: (13 points)
Exercice n1:( 7 points)
A7in (! (t!rmin!r la rsistan$! (! rsistors G1 !t G2, on ralis! un $ir$uit l!$tri&u! $om,ortant G1, G2, un
$on(!nsat!ur (! $a,a$it 0=20 I>, un 'nrat!ur i(al (! t!nsion (! 7.!.m J, un $ommutat!ur (ou2l! ,ositions !t un
2outon ,oussoir (A) (ont l+a,,ui! ,!rm!t un! ($%ar'! instantan! (u $on(!nsat!ur ()oir 7i'ur! sui)ant!)4

Kn! int!r7a$! r!li! F un or(inat!ur ,!rm!t (! r!l!)!r (+un! ,art l+)olution (! la t!nsion K1(t) au- 2orn!s (! G1
lors&u! l! $ommutat!ur !st !n ,osition (1) !t (+autr! ,art la )al!ur instantan! (! la t!nsion K2(t) au- 2orn!s (! G2
lors&u! (L) !st !n ,osition (2).

I- (L) tant !n ,osition (1)4 ;ur l+$ran a,,araMt l+os$illo'ramm! sui)ant4
2
&
2 K 1

E


] H2O2 [ initiale ] I
-
[ initiale !a"ti# limitant
. .
Mlange (1)
Mlange (2)
Mlange (3)

0.0 0.1 0.2 0.3 0.4 0.5 0.6
0
2
4
6
8
10
12
% (&)
t (s)
1- Jn a,,li&uant la loi (!s maill!s, ta2lir l+&uation (i77r!nti!ll! )ri7i! ,ar &(t).
2- ;a$%ant &u! $!tt! &uation (i77r!nti!ll! a(m!t $omm! solution4 &(t)= 0.J (1-
C R
t
e
1

)
a)- :t!rmin!r l+!-,r!ssion (! l+int!nsit (! $ourant i(t) &ui ,ar$ourt l! $ir$uit.
b)- :(uir! l+!-,r!ssion (! la t!nsion K1(t) au- 2orn!s (! G1
c)- Jn utilisant l+os$illo'ramm!, ((uir! la )al!ur (!4
La 7.!.m J (u 'nrat!ur.
La $onstant! (! t!m,s $1 (u (i,@l! $onstitu.
La rsistan$! G1 (u rsistor.
II- /n a,,ui! su l! 2outon ,oussoir (A) !t on 2as$ul! (L) !n ,osition (2)4
A,r#s un! (ur! Nt= 100 ms, l+a77i$%!ur (! l+or(inat!ur in(i&u! un! )al!ur K2=3,7 *.
1- 0om,ar!r K2 F J !t ((uir! la )al!ur (! la $onstant! (! t!m,s $2 (u (i,@l! (ans $! $as.
2- :(uir! la )al!ur (! G2.
3- J-,rim!r !n 7on$tion (! $2 la (ur! (! t!m,s au 2out (! la&u!ll! s!ra $%ar' F 1O ,rs.
Exercice n2:( points)
Kn 'nrat!ur 2ass! 7r&u!n$! (li)rant F s!s 2orn!s un!
t!nsion trian'ulair!. /n asso$i! !n sri! a)!$ $! 'nrat!ur
un! 2o2in! (+in(u$tan$! L=0,24 . !t (! rsistan$! su,,os!
null! $om,ar! F $!ll! (+un rsistor (! rsistan$! G.
:ans l! 2ut (! (t!rmin!r la )al!ur (! G, on ralis! l! $ir$uit
(! la 7i'ur! $i-$ontr!4
1- G!,ro(uir! sur )@tr! $o,i! $! $ir$uit !n ,r$isant l!s 2ran$%!m!nts F !77!$tu!r a)!$ un os$illos$o,! F
mmoir! a7in (! )isualis!r sur sa )oi! (-) la t!nsion au- 2orn!s (u rsistor !t sur sa )oi! (") la t!nsion au-
2orn!s (! la 2o2in!.
2- a)- Ga,,!l!r l!s !-,r!ssions (!s t!nsions KA< !t KP< !n 7on$tion (! i ,
dt
di
, G !t L.
b)- <ontr!r alors &u!4
dt
dU
R
L
U
AM
BM
. =
3- Kn! 7ois l!s s!nsi2ilits (! l+os$illos$o,! sont 7i-!s au- )al!urs sui)ant!s4
*oi! (-)4 5 &' (i)*
*oi! (")4 1 &' (i)*
;!nsi2ilit %ori3ontal!4 5 +s '(i)*
;ur l+$ran, a,,araMt l!s (!u- os$illo'ramm!s (!
la 7i'ur! $i-$ontr!4

a)- <ontr!r &u! l+os$illo'ramm! !n trait $ontinu $orr!s,on( F KP<
b)- :t!rmin!r la )al!ur (! la rsistan$! G (u rsistor.
4- :onn!r l+allur! (! la $our2! (! )ariation (! KA< (t) lors&u+on au'm!nt! la )al!ur (! l+in(u$tan$! (! $!tt!
2o2in!.



%
i
A
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