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t hc^* kreL"'
-14
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c ^. = L _ F A o ( r - x ) _ c o o ( r - x ) _ 0 . 0 e 2 ( l - x )
v vo(r+ex) (r-0.::x) (r_0.:rx)

c,- Fu-'^"(t'-I)- 0.046(r-x)

" v v o ( t +e x ) (t-o.r:x)
c.' =&-=-J*\-- ,o'092(x) /
v vo(r+ ex) (r-o.rx)
If the reactionfollow elementaryrate law

-rA=kcAc|,
Rateraw: + -fo=k{o,ogz(r-x)}{.1ru{t41" t
t (r-0.33x)
J l.(1_0.33x)
J
P3-11(d)
Isothelmal,isobaric,catalytic gasphaseteactionin a pBR
C6H6+ 2H2)C6Hrc
A+28)C
Stoichiometrictable:
Species Svmbol Chanse Leaving
Benzene A Fo. -Fo^X Fa=F"o(l-)O
H2 B Fso=2Feo -2FeoX
Fn=Feo(dr -2X)
CeHro C 0 Fo^X Fc=FnoX

o,=Fuo -ZFoo=2
" Foo Foo

- !-- Foo
', ,Av
.^ =l
Fro Foo + Fro 3

€: !eo6:{{r-r-t)=-1

ceo: c'o!eo: = =a'*Ssmot

tdm3
#[*)
Ggffi^-rr^[f
*ol'K
.-'---''
\ )\
FAo.(r-
x) -clo\- x) g91s!-x)
c . =L = =
v vo(r+ex)
(_fl I'_A-

3-12
 ,,=+=ffi=tfr
c- L" = & - = l n o x r - r c o o x . - 0.055x
v vo(r+ex)
[,_3r) \3)
m
If the reaction follow elementaryrate law.
Rate law:
-ro'=kCAC|

"
-fA'=g.ggg7t(-$-If_
(,-1*)'
For a fluidizedCSTR:
tD- AVo n
W =
-r.' A

FooX
W-
-
o.o*ro(t ")'=
(t-?*)'
\3)
mol
k = 5 3 _r________- ar300K
kgcatminatm'
n( r -rJJ-"' (
r_ll=rr"*o[!9g9g
(L_ t)')=,uuro*
't=&exp[o[4
"[s^:ia[loo 4!sl) kgcatminatm3

Fm = Ceo* vo
vo = 5 drn3/min

atX=0.8

W = 0.0024kg of catalyst

3-13