1 AITS-PT-I-PCM (Sol.

)-JEE(Main)/19

FIITJEE JEE(Main)-2019
ANSWERS, HINTS & SOLUTIONS
PART TEST – I
(Main)

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

ALL INDIA TEST SERIES

1. A 31. B 61. B
2. A 32. C 62. C
3. A 33. B 63. A
4. D 34. B 64. B
5. A 35. B 65. A
6. A 36. C 66. B
7. B 37. D 67. D
8. D 38. B 68. B
9. D 39. C 69. C
10. C 40. D 70. A
11. A 41. B 71. D
12. C 42. A 72. C
13. B 43. C 73. C
14. D 44. D 74. B
15. D 45. B 75. D
16. B 46. B 76. B
17. C 47. C 77. D
18. B 48. C 78. A
19. A 49. B 79. A
20. B 50. B 80. D
21. A 51. C 81. C
22. C 52. A 82. C
23. A 53. D 83. B
24. A 54. C 84. B
25. A 55. D 85. C
26. C 56. B 86. C
27. A 57. D 87. B
28. D 58. C 88. B
29. B 59. D 89. B
30. C 60. C 90. A

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 2

Physics PART – I

SECTION – A
  
1. vrm  vr  vm
 
 v rm dt   vr dt 
 v m dt

 dt  dt  dt
 vrm   v r  0 .

m  x   4m   x   5m   x   8m  x 
2. x cm  0
m  4m  5m  8m
m  x   4m  x   5m  x   8m   x 
y cm 
18m
8mx 4 4  4R  16R
  x   
18m 9 9  3  27
y

4m(–x, x)
m(x, x)

cm
x 45°
x (x, –x)
x
m(–x, –x) 8m

3. Vector along the normal of plane is

ˆi  ˆj 1  b 
Coefficient of k̂ is zero always also it becomes î when b = 1.

4. I0  Kmb2
2
b
I  K.  m .  
2
1

I  Kmb2
4

I0
 I  .
4

v 3 4 80
5.  50   v 
2 5 3
Now using conservation of mechanical energy
 80 2 2
  50   2 gh
3
6400  7500
  2 gh
3

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 3 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

1100  55 
  h  h   m
3  10  2  3 

6. v 2  x  10
2va  v  0
1
 a   ms2
2

7. p1  p2
V1  V2
p2
E
2m
 E1  E2

8. I = k . ma2
2kma2 . a
I 
a
2I. a

a

9. Basic concept of FBD and equilibrium

10. Basic concept of pseudo force

1 1
11. KE  mv 2   5  104  102  2.5  105 J .
2 2
10% of this is stored in the spring.
1 2
kx  2.5  104
2
x=1m
k = 5 × 104 N/m.

12. Basic concept of projectile

Ln  2 n  1 3L
13. Xcm  .  .
 n  2  Ln1 4
n1 3

n2 4
n=2

14. With equal initial kinetic energy, one can write for these rotating disks that KE = ½ I2 = L2/2I. As
a result L = 2I(KE) which means LX < Ly as object Y has more mass. By applying the same
force on the outside of each disk, the torque from the centre of each disk is the same. From the
angular impulse momentum theorem, ()t = L and since the torques and times are equal, the
change in angular momentum is the same for each. Consequently, LX < LY after the push as well.
The kinetic energy depends on the total distance through which each force acted. Since disk X is
rotating at a higher rate than disk Y and the applied force will increase the angular speed of each
disk, there will be a greater angle swept out by a disk X compared to disk Y. As a result, the
kinetic energy change for disk X is greater than for disk Y meaning that after the pus, KX > KY.

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 4


 Fnet
15. aCM 
mi

 gcos  ˆ y
16. aBg  gsin  ˆi  j  Acceleration of box with x
2
respect to ground

aPg  g sin  ˆi  gcos  ˆj  Acceleration of particle
with respect to ground gcos 
 gsin 2
gcos  ˆ
aPB   j  Acceleration of particle with
2
respect to Box x

u  ucos 45 ˆi  usin 45 ˆj  Initial velocity of
PB
g
particle with respect to Box
2usin 45 2 2u gsin
Time of flight =  y
gcos  gcos  
2 O

17. A P  22  1  5. 1m A 1m
P
 h   5 1  O
2 kg

From work energy theorem : 1m
1 1
2g  1  1 gh  2v 2A   1 v B2
2 2 vB
B
2 vA
Where vB  v A cos ; cos  
5 h
A
On solving :
7 B
7.5  v 2A  v A  2.3 m / sec.
5 1 kg

18. Bird has to fly away from wind direction as shown so N

Wind
as to reach P. P
 VBird  Vwind
If t is time taken;
5 1 5 km
  t …(i) Bird  45°
2 15cos 
5 S E
 5  15 sin   t  …(ii) W O
2
Solving for t we get
 34  2 
8t 2  2t  1  0  t    hrs.
 16
  S

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 5 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

x
19.  tan 
R
x = R tan  R
dx d
  R sec 2   R sec 2 
dt dt x
2
 v = R sec 
v
dv  d 
  R 2sec  .sec  tan   .
dt  dt 
 a  2R2 sec 2  tan 
v  R  2  sec 2 60  2R  4   8R
a  2  R  4  4   3   32 3R

v
20. Let frog takes off at  angle with v speed from ground frame
mv cos  v cos 
vP   
3m 3
u
   v cos  4
  v f /P  x  v f  v P  v cos    v cos 
3 3
4
2   v cos v sin 

 v f /p y  v sin   Rf /P   3  g 

3 3
 v 2 sin 2  g  vmin  g
4 4

2iˆ  3ˆj  4kˆ

21. v̂ i 
29
3i  6 j  2kˆ
ˆ ˆ
p̂ 
7

ˆv f  v i  2  vˆ i .pˆ  pˆ


2iˆ  3ˆj  4kˆ


2  6  18  8  3iˆ  6ˆj  2kˆ 
4  9  16 29  49
 9 4 ˆi  2 3 7 ˆj  6 8 kˆ
=
49 29

2  10
22. Time of flight =  2s;
10
Range = 2 × 15 = 30 m

1
23. Area =  0.10  120 = 6 Ns
2
Change in momentum = 6 – 400  10 3  10  0.10 Due to Gravitation  = 6 – 0.4 = 5.6 Ns
mv = 5.6  v = 14 m/s
v2
H  9.8 m
2g

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 6

v0
24. r = v0R, and z 
OO
OO = R cot  z

  Zkˆ  r ( ˆi ) A
    ˆ  R(k)
ˆ 
 v A    rA    Rcot (i)  rA
R
 v 0 ˆ v0 ˆ  
= k i  R cot  ˆi  Rkˆ   C
 R cot  R   O x

 v A  (v 0  v 0 )iˆ  2v 0 ˆi v A = 2v0
  
Similarly, vB    rB

Where, r  Rcot  ˆi  Rjˆ
B
 v
 v B   v 0kˆ  0 ˆi  v 0 ˆj
cot 
v 20
 vB  v 02   v 02 = v0 2  tan2 
cot 2 

F0  F 
25. a1  sin t   0 2  2 sin t  2R sin t
m  m 
F  F 
a 2  0 cos t   0 2  2 cos t  2R cos t
m  m 
F0
Here R 
m2
F0 F
v1  1  cos t  & v 2  0 sin t  x1  R  t  sin t  & y 2  R 1  cos t 
m m
F0
 v1  , and  v 2  0
m

26. No external force is acting along horizontal direction

27. E = U + K, for a given E, k will be maximum where U will be minimum.


28. Taking torque about A mg cos   fs  sin   N2  cos 
2
F1 N2
fs
F
N1
F2
A
FBD of Rod-1
N2

mg
fs B

FBD of Rod-2
mg
 N2 
2 1   tan  

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 7 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

mg 0.5  3  10
F  fs  Fmin  fsmax  N2  Fmin  F2    5N
2 1   tan   2 1  0.5  1

29. mg  K  2     K
K  L    cos   mg 
L
mg L2  r 2
L     mg
K L   
 L
L
 L2  r 2  C m
L
2
2  L  2
 L   r mg
L   
 2  2
L2  1  r
  L   2 
 
 L2  2L 
r 2  L2  
  L   2 
 
L
 r L  L  2 
L

mv 2
30.  mgcos  …(1)
R
1 R
M  m  v 2  mg 1  cos   R  Mg …(2)
2 4
1 Mg
M  m gcos   mg 1  cos   
2 4

  M  m  cos   2m 1  cos    M
2

Chemistry PART – II

SECTION – A

31. O
124o
S O
F o
96 F

sp3 but not ideal tetrahedral.

O
109o28'
S
O O
O
Ideal tetrahedral

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 8

O F
F
S S
O O F
Trigonal planer F
See-saw

33. * 2p z LUMO 
*2px , *2py HOMO 

2p 2p

2px , 2py
2pZ
* 2s

2s 2s

2s
* 1s

1s 1s

1s
35. 

S 8  g 
 4S2  g 
C 0
C  C 4C
V.Dinitial  moles  eqm

V.Deqm  moles initial
 32  8  / 2 C  C  4C

96 C
4
  1  3
3
1

9
1
% decomposition  100  11.11%
9
36. ‘Hf’ form interstitial hydride, e.g. HfH1.98
 KH is an ionic hydride
 SiH4 is a covalent hydride
 ‘Co’ don’t form hydride (hydride gap)
37. Actual boiling point order
H2S < H2Se < H2Te < H2O

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 9 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

38. On heating
 1
Na2 O2   Na2 O  O2
2
 Na2O 2  O22   it is diamagnetic in nature.
 Na2 O2  CO2 
 Na2CO3 (Suitable for use in air purification)
 Na2 O2 is good oxidizing agent.

4 6
41. S  S  2e  Oxidation half reaction 
Cr 6  3e  Cr 3 Re duction half reaction 
 Na2 CrO4 is oxidizing agent
 Eq. wt. of Na2CrO4 (oxidizing agent) = M/3

42. 

2CH4  g   4H2O  g  
 2CO2  g   8H2  g  … (i)


CO  g   H2 O  g 
 CO2  g  H2  g … (ii)
Equation (i) – 2 × Equation (ii)


2CH4  g   2H2 O  g  
 2CO  g   6H2  g  … (iii)
K1
Equilibrium constant for Equation (iii) 
K 22
1
By multiplying Eq. (iii) by we get
2


CH4  g   4H2O  g  
 CO  g   3H2  g 
1/ 2
K  K1
 Equilibrium constant   12  
 K2  K2

43. Possible value of quantum number of 3d orbital.

n = 3,   2 , m = -2, - 1, 0, +1, +2
s = +1/2, - 1/2

44. O

P n 1 pK a  9  7  1  2
HO OH
OH
O

Cl n3 pK a  9  7  3  12
O O
OH
H  O  Cl n0 pK a  9  7  0  9
O

S n 1 pK a  9  7  1  2
HO OH

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 10

45. n P
D 1 1
O18 10 8
H 0 1
x = 11 y = 10
x–y=1

7 2 5 2
46. MnO 4  M2   MO3  Mn2 
n-Factor of Mn = 5
n-Factor of M = 3
Number of equivalent of MnO 4 = Number of M2+
5 × mole of MnO 4 = 3 × 2
6
 Mole of MnO 4   1.2
5

47. CH3 COONa  HCl  CH3 COOH  NaCl

400  0.05 100  0.2
20 meq. 20 meq. 0 0
0 0 20 meq. 20 meq.
20
 CH3 COOH   0.04 M
500
1 1
pH   pK a  logC    4.75  log  0.04  
2 2
1  1 
  4.75  log  
2  25  
1

2
 4.75  log  25  
1
  4.75  1.4   3.075
2

48. Uncertainty in velocity

0.2  200
v   0.4 ms 1
100
h
x.p 
4
h
x 
4  m    v
6.4  1034

4  50  10 3  0.4  3.2
1034
  2.5  1033
40  10 3

2.303 A 
49. k log  0 
t  At 
A  k.t 4.606  105  4  3600
log  0   
 A t  2.303 2.303

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 11 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

= 2 × 4 × 3600 × 10-5
= 0.288
 A0 
  = Anti log (2.88)
 At 
= 1.94
At 1
Fraction remain  
A 0 1.94
1
Fraction decomposed  1 
1.94
0.4845  .48



NH4 SH  s  
 NH3  g  H2 S  g 
50. At eqm P P
Ptotal  2P
2
KP = P
When H2S is added


NH4 SH  s  
 NH3  g  H2 S  g 
 P   P 
NH3 H2 S

According to question
3 3
PH2 S   Ptotal   2P  3P
2 2
KP  PH2S .PNH
3
P 2  PNH
 .3P
3

P
 3 
 PNH
3
P
 3
PNH
  3  1: 3
PNH3 P

51. Na 2CO3  HCl  NaHCO3  NaCl


2.12
m.eq. initial  1000 20  0.5 0 0
106
20 m.eq. 10 m.eq.
m.eq. after mixing 10 m.eq. 0 10 m.eq. 10 m.eq.
Now,
Mixture contains Na2CO3 and NaHCO3 so it will acts as buffer.

 pH  pK a  log
Na2CO3 
NaHCO3 
= 10.25 + log10/10 = 10.25

0.34
52. Moles of CaSO4 in 200 ml solution   0.25  102
136
0.25  10 2
 Molarity   1000
200
-2
= 1.25 × 10 mol/lit.

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 12

K sp  Ca 2  SO42  
2

 1.25  102 
-4
= 1.5625 × 10

2.303  A 0  2.303 A
53. t 2 /3 rd  t1/3 rd  log   log 0
K  1/ 3A 0  K 2
A
3 0
2.303
 log2
K
0.693
 100 min   half life
K
 Time taken for completion of 75%  2t1/ 2   2  100  200 min

54. Cr  x   3.87
n  n  2  3.87
–
 n  3 (unpaired e )
 Cr 3  x  3 
 y  4 Mn4 
n  n  2  3.87
–
 n  3 (unpaired e )
 Mn4
x  3 y  4
x–y=-1

A 4  10 2
55. Rate of disappearance of ‘A’     10 3 mol L1 s 1
t 40
We know
1   A  1  B 1   C 
  
2 t 2 t 4 t
 Rate of appearance of ‘C’
 C   A 
  2
t t
= 2 × 10-3 mol L-1 s-1

56. Here n  ve

 By adding inert gas backward reaction favoured
 By adding D(g) backward reaction takes place.

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 13 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

57.
H
O

Cl
Cl
Cl P 0 0
Cl
Cl
O
H

F
Cl
Cl P 0
Cl
F
F
Cl
F P 0
Cl
F

58. Mass of 12 H = Mass of 11H + mass of neutron

= 1.0086 + 1.0078
= 2.0164 amu
Actual mass = 2.0064 amu
 mass defect = 2.0164 – 2.0064
= 0.01 amu.
 Bond Energy = 0.01 × 931.5 Mev
= 9.315 Mev.

59. Diamond Graphite

Resistivity 1011 1.375 × 10-5
Standard molar entropy 2.377 5.740
Density 3.513 2.260

60. O
O
C
C Cl Cl
F F 111o
o
108
O
O
S
S Br Br
F F 96o
o
93

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 14

Mathematics PART – III

SECTION – A

61. If lim f  x    and lim g  x   m  lim f  x   g  x    m

x a x a x a

2
62. Volume = ·3 ·2·3 = 54

63. (p  q)  (r  q) is equivalent to [~(p  q)  (r  q)]  [~(r  q)  (p  q)]

64. y = x  f(x + x2) + 1 + 2x = f(x) + f(x2) + 2x f(x)

y = –x  f(x + x2) + 1 + 2x = f(x) + f(x 2) + 2x f(–x)
 f(x) = f(–x)

x18  1 dx 1 12x11  12x 7 dx

65.  
1/6
12  x12  3  2x 6 1/6

x7 x12  3  2x 6   
5/6 5/6

=
12

1 x  3  2x
6
  c  x 18
 3x 6  2
c
12 5/6 10x 5
 P(x) = x + 3x6 + 2
18

f  x  eh  f  h ex  2xhe x eh  f  x 
66. f   x   lim
h 0 h
 f(x) = f(x) + 2xex  f(x) = x2ex

67. One of them has to be maxima and other minima

68. There are only 2 points where f(x) has local minima

x1 x2
1000 1000
69. Area =  tan x  x dx  x  tan x dx
0 x1

70. Circle is circumcircle of the triangle

71. an + 1 = an + an – 1
a a
 lim n1  1  lim n1
n  a n a
n n
an1
Let lim 
n an
 2    1  0
1 5
 
2
–1
72. f (x) = g(x)  h(x) = x

73. 3x 4
 2xydx  x dy   2y 2
2  xdy  ydx 
2
 x2   x2 
 3   d   2
d  xy 
y2 xy  y   y  xy

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 15 AITS-PT-I-PCM (Sol.)-JEE(Main)/19

74. Apply chain rule

75. f(x) is constant function

76. cot  > 0

dy
77.  1  y + x = 0, y – x = 0
dx

d2 y
78. 4
dx 2

79. Substitute x = r sec . y = r tan 

rdr 1
 2  cos  sin   cos2 
r sec d 2
1 nc
 n r  sin  sin   
2 2
y
 
 n x 2  y 2  sin    nc
x

  /2
m  2/  n  1/n
80.
m

lim   f  x    f 1  x 

n
dx 
  
n 1  /6
  3/  n 
 2  3
m  n n  
 2 3   
= lim          = 2   6  = 
m 
n 1  2    6  2 3   2 2  6
1 1
 

81. h(x) is a constant function and is always periodic

2
 sin 2x x  x 1
a  xx  
2x 2x  9
82. lim  
x 0  n 1  2x   4
 
 2x 
2
 1
a 2  9
   a=2
 1  4
 

83. e
x2  x
 4x 3

 4x 2  5x  1 dx = e
x2  x
2x  1  2x 2
 
 x  4x  1 dx = e x
2
x
 2x 2

x c

84. For lim f  x  to exist, lim f   x  must be 0

x  x 

2018 2019
 r
  1  x 
r1
85. lim 2019
 2018
x   r
  1  x 
r 1

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AITS-PT-I-PCM (Sol.)-JEE(Main)/19 16

86. x = 2020, 2 are points of non-differentiability

1
87. x is point of global minima
e
1 1
 1   b = 2
b e


tan1 x
88. Let I    x  12 dx
0

1 cot 1 t
Let x   I   t  12 dt
t 0

1 1 
 I  2
dx 
2 2 0  x  1 4

89. If f(x) is differentiable, then f(x) should have a unique value at that point

90. If n(P  M  C) = 100  n(M  C)  0  n(M  C) = 0

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