V = 250 mL

V agitation = 200 rpm t = 30 mn

m d e l'argile pH
0.06 6.04
0.08 6.26
0.1 6.13
0.2 5.75
0.3 6.32
Variation pH=f(MAD)

pH
5

2
0.05 0.1 0.15 0.2 0.25
Masse (g)
riation pH=f(MAD)

0.2 0.25 0.3 0.35

Masse (g)
l = 461 nm e = 0,02199 l= 1cm V = 250 ml mkaolin = 0,1 g

vitesse d'agitation = 200 rpm

[Col1]1 = 20 ppm
[Col1] corrigé = 19,6 ppm Vcorrigé = 255 ml
[Col1]2=40 ppm
[Col1] corrigé = 38,46 ppmVcorrigé = 260 ml
[Col1]3=60 ppm
[Col1] corrigé = 56,6 ppm Vcorrigé = 265 ml

DO Dilué 2CC dans 25CC Ceq

t 20ppm 40ppm 60ppm t 20ppm

0 0 19.6
15 0.211 0.624 15 9.595
30 0.17 0.622 0.083 30 7.731
60 0.18 0.576 0.076 60 8.186
120 0.168 0.489 0.073 120 7.640
180 0.145 180 6.594

téq = 30 min
Argile de Djebel D'begh

Qad

t 20ppm 40ppm 60ppm

0 0.0000 0 0
15 25.512 26.217
30 30.266 26.453 24.962
60 29.107 31.892 35.506
120 30.498 42.179 40.025
180 33.166
40ppm 60ppm
38.46 56.6
28.377 45.0
28.286 47.181
40.0
26.194 43.201
22.237 41.496 35.0
30.0
[C1] = 20
25.0
[C1] = 40
20.0
[C1] = 60
15.0
10.0
5.0
0.0
0 20 40 60 80 100 120 140 160 180 200
 [C1] = 20 ppm
[C1] = 40 ppm
[C1] = 60 ppm

160 180 200

l = 461 nm e = 0,0149 l= 1cm V = 250 ml mkaolin = 0,1 g

vitesse d'agitation = 200 rpm

DO Dilué 2CC dans 25CC Ceq

t 20ppm 40ppm 60ppm t 20ppm

0 0 19.6
15 0.144 0.245 0.385 15 9.664
30 0.138 0.214 0.378 30 9.262
60 0.121 0.225 0.304 60 8.121
120 0.118 0.2 0.361 120 7.919
180 0.12 0.333 180 8.054

Temps d'équilibre C3
Qad (mg/L)

100.0000 [C1] = 20 ppm

80.0000 [C1] = 40 ppm
[C1] = 60 ppm
60.0000

40.0000

20.0000

0.0000
0 20 40 60 80 100 120 140 160 180 200
Temps (min)
 Qad

40ppm 60ppm 20ppm 40ppm 60ppm

38.46 56.6 0.0000 0 0
16.443 25.839 24.839 55.043 76.903
14.362 25.369 25.846 60.244 78.077
15.101 20.403 28.698 58.398 90.493
13.423 24.228 29.201 62.593 80.930
22.349 28.866 40.278

[C1] = 20 ppm téq = 30min

[C1] = 40 ppm
[C1] = 60 ppm

180 200
 C3 C3 C3
m mg A Ce ppm Cad ppm Q ad mg/g
0 19.6 0
6 0.199 13.356 6.244 0.265
10 0.136 9.128 10.472 0.267
50 0.144 9.664 9.936 0.051
100 0.131 8.792 10.808 0.028
150 0.07 4.698 14.902 0.025

m ad C3= 50 mg/255mL

Ce mg/L Cad mg/L Qad mg/g

masse mg A C1 20 ppm

0 19.6 0
10 0.357 16.235 3.365 0.086
50 0.307 13.961 5.639 0.029
100 0.3 13.643 5.957 0.015
150 0.299 13.597 6.003 0.010
mad C1 = 0,1 g/255 mL 200 0.282 12.824 6.776 0.009
250 0.258 11.733 7.867 0.008
V = 250 ML
m = 100 mg
t ag = 30 min
vag = 200 rpm C0 ppm A ce ppm Qad mg/g
0 0 0 0
10 0.189 8.595 3.513
20 0.276 12.551 18.622
30 0.375 17.053 32.367
40 0.703 31.969 20.077
50 0.843 38.336 29.161
60 0.09 51.160 22.101
80 0.113 64.234 39.416
100 0.121 68.781 78.047
120 0.167 94.930 62.676
140 0.21 119.372 51.569
160 0.241 136.994 57.515

C0 ppm ce ppm Qad mg/g

0 0
20 12.551 18.622
30 17.053 32.367
80 64.234 39.416
120 94.930 62.676
140 119.372 51.569
160 136.994 57.515

Isotherme de Langmuir Qe = (Q0.KL.Ce)/(1+KL.Ce)

Linéarisation Ce/Qe = (1/Q0) Ce + 1/Q0.KL

C0 ppm ce ppm Ce/Qe

0
20 12.551 6.74E-01
30 17.053 5.27E-01
80 64.234 1.63E+00
120 94.930 1.51E+00
140 119.372 2.31E+00
160 136.994 2.38E+00

1/Q0 = 1.46E-02 Q0 68.49 mg/g

1/KL.Q0= 4.27E-01 KL 3.4216E-02
Isotherme de Freundlich Qe = Kf Ce (1/n) ln Qe = ln kf + 1/n (lnCe)

C0 ppm Ln Ce Ln Qe

20 2.530 2.924
30 2.836 3.477
80 4.163 3.674
120 4.553 4.138
140 4.782 3.943
160 4.920 4.052

1/n= 0.4062 n 2.46E+00

LnKf= 2.0914 Kf 8.10E+00

Chaleur d'adsorption
V = 250 ML
m = 50 mg
t ag = 60 min
vag = 200 rpm
C0 ppm A ce ppm Qad mg/g
0 0 0 0
20 0.181 12.148 39.262
30 0.302 20.268 48.658
40 0.405 27.181 64.094
50 0.59 39.597 52.013
60 0.529 35.503 122.483
80 0.913 61.275 93.624
100
120
140
160

ce ppm Qad mg/g

0 0 0 0
20 0.147 9.866 50.671
30 0.219 14.698 76.510
40 0.26 17.450 112.752
60 0.427 28.658 156.711
80 0.766 51.409 142.953

Isotherme de Langmuir Qe = (Q0.KL.Ce)/(1+KL.Ce)

Linéarisation Ce/Qe = (1/Q0) Ce + 1/Q0.KL

C0 ppm ce ppm Ce/Qe

20 9.866 1.95E-01
30 14.698 1.92E-01
40 17.450 1.55E-01
60 28.658 1.83E-01
80 51.409 3.60E-01

1/Q0 = 1.70E-03 Q0 588.24 mg/g

1/KL.Q0= 1.66E-01 KL 1.0229E-02
Isotherme de Freundlich Qe = Kf Ce (1/n) ln Qe = ln kf + 1/n (lnCe)

C0 ppm Ln Ce Ln Qe

20 2.289 3.925
30 2.688 4.337
40 2.859 4.725
60 3.355 5.054
80 3.940 4.963

1/n= 2.6575 n 3.76E-01

LnKf= 0.6422 Kf 1.90E+00
 teq = 30 min Qe exp = 30,266 mg/g
mad = 0,1 g
V = 250 mL

t min A C Q (t)
20 ppm 20
1 0.287 13.051 17.372
2 0.237 10.778 23.056
3 0.246 11.187 22.033
4 0.234 10.641 23.397
5 0.235 10.687 23.283
9 0.221 10.050 24.875
12 0.215 9.777 25.557
15 0.193 8.777 28.058

cin pseudo 1 ln (Qe - Qt) =-kad t + ln Qe

t ce C/C0 Qt Qe -Qt ln (Qe-Qt)
0 20 1
1 13.051 0.653 17.372 12.894 2.557
3 11.187 0.559 22.033 8.233 2.108
5 10.687 0.534 23.283 6.983 1.943
9 10.050 0.503 24.875 5.391 1.685
12 9.777 0.489 25.557 4.709 1.549
15 8.777 0.439 28.058 2.208 0.792

kad = 0,1053 min-1 Qecal = 12,95 mg/g

t/qt = 1/kadQe2 + t/qe pseudo ordre 2

t t/qt
1 0.058
3 0.136
5 0.215
9 0.362
12 0.470
15 0.535

kad = 0,033 g.mg-1.min-1 Qecal = 29,15 mg/g

Coef. De diffusion qt = kipt1/2 + C

t1/2 qt
1.000 17.372
1.732 22.033
2.236 23.283
 3.000 24.875
3.464 25.557
3.873 28.058

kip = 3,238 mg.g-1.min-1

 Cinétique d'adsorption

1.2
1.0
C/C0

0.8
0.6
0.4
0.2
0.0
0 2 4 6 8 10 12 14 16
Temsps (minutes)