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Sodium tetrahydroborate is a stronger reducing agent and the reaction rate is faster than with tin(I1)
chloride. The concentration of 64 Chapter 2 used NaBH, solution is usually between 0.1-O.5%
(wh) compared to 1-10% (wh) when tin(I1) chloride is used. Typically, SnCl, only reduces
inorganic mercury compound whereas NaBH, also reduces most of the organically bound mercury.
Tin(I1) chloride is more sensitive to the acid matrix of the samples (acid type and concentration)
than NaBH,. A drawback of NaBH, is its ability to reduce transition metals to elemental states as
mentioned earlier. Reduced mercury may be adsorbed by the precipitated metal resulting in
systematic errors. Hypophosphoric acid, hydrazine, or Cr(I1) also be used as reductants for
mercury. By selective reductions of inorganic mercury(I1) compounds and organomercury
compounds, it is possible to determine successively the inorganic and organic mercury fraction in
the same sample. Inorganic forms of mercury are reduced with Sn(I1) chloride and then the organic
forms are reduced with Sn(I1) chloride - Cd(I1) chloride solution.
Enrichment of Mercury. Due often to very low mercury contents of the samples to be analysed,
enrichment procedures are required. Mercury can be extracted with PDDC into MIBK or with
dithiazone into chloroform. It can also be electrolysed on the copper or silver cathode. The mercury
vapour can be collected in several traps such as various solution traps, gold trap, and active carbon.
Adsorption solutions may be nitric acid, bromine water-nitric acid, or potassium permanganate
solutions.