Diprotic Acid

Ka1= 8.20E-05 pKa1 4.0863796

Ka2= 7.29E-06 pKa2 5.1373977 Titration Curve
14
12
Kw= 1.00E-14 Mass Acid= 1.5401 10
Ca= #NAME? Molar Mass #NAME? 8
Cb= 0.08267 6
Va= 100 4

pH
Veq= 56.00942 2
0
0 0 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2
E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0
Sresid2= #NAME? 00 00 40 10 80 50 20 90 60 30 00 70 40 10 80 05 1 2 19 2 6 33 40
0. 7. 1. 2. 2. 3. 4. 4. 5. 6. 7. 7. 8. 9. 9. 1. 1. 1. 1. 1. 1.
Vb/Va
pHexp H OH F Vb/Va(calc) Vexp/Va resid resid2 m

2.78 1.66E-03 6.03E-12 4.75E-02 #NAME? #NAME? #NAME? #NAME? #NAME?

2.83 1.48E-03 6.76E-12 5.30E-02 #NAME? #NAME? #NAME? #NAME? #NAME?
2.9 1.26E-03 7.94E-12 6.18E-02 #NAME? #NAME? #NAME? #NAME? #NAME?
3.05 8.91E-04 1.12E-11 8.55E-02 #NAME? #NAME? #NAME? #NAME? #NAME?
3.13 7.41E-04 1.35E-11 1.01E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.26 5.50E-04 1.82E-11 1.33E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.31 4.90E-04 2.04E-11 1.47E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.36 4.37E-04 2.29E-11 1.63E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.42 3.80E-04 2.63E-11 1.84E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.47 3.39E-04 2.95E-11 2.02E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.52 3.02E-04 3.31E-11 2.23E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.56 2.75E-04 3.63E-11 2.40E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.6 2.51E-04 3.98E-11 2.58E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.64 2.29E-04 4.37E-11 2.78E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.68 2.09E-04 4.79E-11 2.98E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.71 1.95E-04 5.13E-11 3.15E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.74 1.82E-04 5.50E-11 3.31E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.79 1.62E-04 6.17E-11 3.60E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.81 1.55E-04 6.46E-11 3.73E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.83 1.48E-04 6.76E-11 3.85E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.87 1.35E-04 7.41E-11 4.10E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.89 1.29E-04 7.76E-11 4.24E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
3.95 1.12E-04 8.91E-11 4.64E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4 1.00E-04 1.00E-10 5.00E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.05E+00 8.91E-05 1.12E-10 5.36E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.10E+00 7.94E-05 1.26E-10 5.74E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.14E+00 7.24E-05 1.38E-10 6.05E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.19E+00 6.46E-05 1.55E-10 6.45E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.23E+00 5.89E-05 1.70E-10 6.77E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.28E+00 5.25E-05 1.91E-10 7.18E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.32E+00 4.79E-05 2.09E-10 7.51E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.36E+00 4.37E-05 2.29E-10 7.85E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.41E+00 3.89E-05 2.57E-10 8.27E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.45E+00 3.55E-05 2.82E-10 8.61E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.49E+00 3.24E-05 3.09E-10 8.95E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.53E+00 2.95E-05 3.39E-10 9.30E-01 #NAME? #NAME? #NAME? #NAME? #NAME?

Page 1
 Diprotic Acid

4.57E+00 2.69E-05 3.72E-10 9.64E-01 #NAME? #NAME? #NAME? #NAME? #NAME?

4.61E+00 2.45E-05 4.07E-10 9.98E-01 #NAME? #NAME? #NAME? #NAME? #NAME?
4.65E+00 2.24E-05 4.47E-10 1.03E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.70E+00 2.00E-05 5.01E-10 1.08E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.73 1.86E-05 5.37E-10 1.10E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.78 1.66E-05 6.03E-10 1.14E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.81 1.55E-05 6.46E-10 1.17E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.86 1.38E-05 7.24E-10 1.21E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.9 1.26E-05 7.94E-10 1.25E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.91 1.23E-05 8.13E-10 1.25E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
4.98 1.05E-05 9.55E-10 1.31E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.03 9.33E-06 1.07E-09 1.35E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.07 8.51E-06 1.17E-09 1.38E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.11 7.76E-06 1.29E-09 1.42E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.16 6.92E-06 1.45E-09 1.45E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.21 6.17E-06 1.62E-09 1.49E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.25 5.62E-06 1.78E-09 1.52E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.3 5.01E-06 2.00E-09 1.55E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.35 4.47E-06 2.24E-09 1.59E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.41 3.89E-06 2.57E-09 1.63E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.47 3.39E-06 2.95E-09 1.66E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.53 2.95E-06 3.39E-09 1.69E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.53 2.95E-06 3.39E-09 1.69E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.6 2.51E-06 3.98E-09 1.73E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.63 2.34E-06 4.27E-09 1.74E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.67 2.14E-06 4.68E-09 1.76E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.76 1.74E-06 5.75E-09 1.80E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.82 1.51E-06 6.61E-09 1.82E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.84 1.45E-06 6.92E-09 1.83E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.87 1.35E-06 7.41E-09 1.84E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.89 1.29E-06 7.76E-09 1.85E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.92 1.20E-06 8.32E-09 1.85E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
5.99 1.02E-06 9.77E-09 1.87E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.07 8.51E-07 1.17E-08 1.89E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.16 6.92E-07 1.45E-08 1.91E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.25 5.62E-07 1.78E-08 1.93E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.32 4.79E-07 2.09E-08 1.94E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.39 4.07E-07 2.45E-08 1.95E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.48 3.31E-07 3.02E-08 1.96E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.54 2.88E-07 3.47E-08 1.96E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.56 2.75E-07 3.63E-08 1.96E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.62 2.40E-07 4.17E-08 1.97E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.7 2.00E-07 5.01E-08 1.97E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.77 1.70E-07 5.89E-08 1.98E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.88 1.32E-07 7.59E-08 1.98E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.92 1.20E-07 8.32E-08 1.98E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
6.97 1.07E-07 9.33E-08 1.99E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
7.02 9.55E-08 1.05E-07 1.99E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
7.08 8.32E-08 1.20E-07 1.99E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
7.2 6.31E-08 1.58E-07 1.99E+00 #NAME? #NAME? #NAME? #NAME? #NAME?

Page 2
 Diprotic Acid

7.3 5.01E-08 2.00E-07 1.99E+00 #NAME? #NAME? #NAME? #NAME? #NAME?

7.52 3.02E-08 3.31E-07 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
7.73 1.86E-08 5.37E-07 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
8.08 8.32E-09 1.20E-06 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
8.85 1.41E-09 7.08E-06 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
9.41 3.89E-10 2.57E-05 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
9.72 1.91E-10 5.25E-05 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.05 8.91E-11 1.12E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.24 5.75E-11 1.74E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.32 4.79E-11 2.09E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.39 4.07E-11 2.45E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.5 3.16E-11 3.16E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.56 2.75E-11 3.63E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.6 2.51E-11 3.98E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.69 2.04E-11 4.90E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.72 1.91E-11 5.25E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.82 1.51E-11 6.61E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.84 1.45E-11 6.92E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
10.97 1.07E-11 9.33E-04 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11 1.00E-11 1.00E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.07 8.51E-12 1.17E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.13 7.41E-12 1.35E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.21 6.17E-12 1.62E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.24 5.75E-12 1.74E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.27 5.37E-12 1.86E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.32 4.79E-12 2.09E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.37 4.27E-12 2.34E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.42 3.80E-12 2.63E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.45 3.55E-12 2.82E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.51 3.09E-12 3.24E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.56 2.75E-12 3.63E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.6 2.51E-12 3.98E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.63 2.34E-12 4.27E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.66 2.19E-12 4.57E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.69 2.04E-12 4.90E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.72 1.91E-12 5.25E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.74 1.82E-12 5.50E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.79 1.62E-12 6.17E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.83 1.48E-12 6.76E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.86 1.38E-12 7.24E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.89 1.29E-12 7.76E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.92 1.20E-12 8.32E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.95 1.12E-12 8.91E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.98 1.05E-12 9.55E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
11.99 1.02E-12 9.77E-03 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.02 9.55E-13 1.05E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.07 8.51E-13 1.17E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.08 8.32E-13 1.20E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.14 7.24E-13 1.38E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.15 7.08E-13 1.41E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?

Page 3
 Diprotic Acid

12.16 6.92E-13 1.45E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?

12.18 6.61E-13 1.51E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.19 6.46E-13 1.55E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.2 6.31E-13 1.58E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.21 6.17E-13 1.62E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?
12.23 5.89E-13 1.70E-02 2.00E+00 #NAME? #NAME? #NAME? #NAME? #NAME?

Page 4
 Diprotic Acid

4.5
4
3.5
3
2.5
2
1.5
pH

1
0.5
0
1 1 1 2 2 2 2 2 2
+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0 E+0
0

01

01
+0

E+

E+
0E

10 80 05 1 2 19 2 6 33 40
00

00
9. 9. 1. 1. 1. 1. 1. 1.
0
0.

2.

4.

Residual
g(Davies) g(Paste Special/Values) Vexp

#NAME? 1 0.00E+00
#NAME? 1 8.10E-01
#NAME? 1 1.21E+00
#NAME? 1 2.16E+00
#NAME? 1 2.71E+00
#NAME? 1 3.71E+00
#NAME? 1 4.12E+00
#NAME? 1 4.69E+00
#NAME? 1 5.16E+00
#NAME? 1 5.65E+00
#NAME? 1 6.16E+00
#NAME? 1 6.71E+00
#NAME? 1 7.21E+00
#NAME? 1 7.71E+00
#NAME? 1 8.20E+00
#NAME? 1 8.66E+00
#NAME? 1 9.21E+00
#NAME? 1 9.71E+00
#NAME? 1 1.02E+01
#NAME? 1 1.07E+01
#NAME? 1 1.12E+01
#NAME? 1 1.17E+01
#NAME? 1 1.28E+01
#NAME? 1 1.38E+01
#NAME? 1 1.48E+01
#NAME? 1 1.57E+01
#NAME? 1 1.67E+01
#NAME? 1 1.77E+01
#NAME? 1 1.87E+01
#NAME? 1 1.97E+01
#NAME? 1 2.07E+01
#NAME? 1 2.17E+01
#NAME? 1 2.27E+01
#NAME? 1 2.37E+01
#NAME? 1 2.48E+01
#NAME? 1 2.57E+01

Page 5
 Diprotic Acid

#NAME? 1 2.68E+01
#NAME? 1 2.77E+01
#NAME? 1 2.87E+01
#NAME? 1 2.98E+01
#NAME? 1 3.07E+01
#NAME? 1 3.17E+01
#NAME? 1 3.27E+01
#NAME? 1 3.38E+01
#NAME? 1 3.47E+01
#NAME? 1 3.57E+01
#NAME? 1 3.67E+01
#NAME? 1 3.78E+01
#NAME? 1 3.87E+01
#NAME? 1 3.98E+01
#NAME? 1 4.07E+01
#NAME? 1 4.17E+01
#NAME? 1 4.27E+01
#NAME? 1 4.37E+01
#NAME? 1 4.47E+01
#NAME? 1 4.59E+01
#NAME? 1 4.67E+01
#NAME? 1 4.77E+01
#NAME? 1 4.77E+01
#NAME? 1 4.87E+01
#NAME? 1 4.91E+01
#NAME? 1 4.96E+01
#NAME? 1 5.06E+01
#NAME? 1 5.11E+01
#NAME? 1 5.14E+01
#NAME? 1 5.16E+01
#NAME? 1 5.18E+01
#NAME? 1 5.21E+01
#NAME? 1 5.26E+01
#NAME? 1 5.31E+01
#NAME? 1 5.36E+01
#NAME? 1 5.40E+01
#NAME? 1 5.43E+01
#NAME? 1 5.46E+01
#NAME? 1 5.49E+01
#NAME? 1 5.51E+01
#NAME? 1 5.51E+01
#NAME? 1 5.53E+01
#NAME? 1 5.54E+01
#NAME? 1 5.55E+01
#NAME? 1 5.57E+01
#NAME? 1 5.58E+01
#NAME? 1 5.58E+01
#NAME? 1 5.59E+01
#NAME? 1 5.59E+01
#NAME? 1 5.60E+01

Page 6
 Diprotic Acid

#NAME? 1 5.61E+01
#NAME? 1 5.62E+01
#NAME? 1 5.62E+01
#NAME? 1 5.63E+01
#NAME? 1 5.63E+01
#NAME? 1 5.64E+01
#NAME? 1 5.64E+01
#NAME? 1 5.65E+01
#NAME? 1 5.66E+01
#NAME? 1 5.67E+01
#NAME? 1 5.67E+01
#NAME? 1 5.68E+01
#NAME? 1 5.69E+01
#NAME? 1 5.69E+01
#NAME? 1 5.71E+01
#NAME? 1 5.71E+01
#NAME? 1 5.73E+01
#NAME? 1 5.73E+01
#NAME? 1 5.77E+01
#NAME? 1 5.77E+01
#NAME? 1 5.79E+01
#NAME? 1 5.82E+01
#NAME? 1 5.85E+01
#NAME? 1 5.86E+01
#NAME? 1 5.89E+01
#NAME? 1 5.90E+01
#NAME? 1 5.94E+01
#NAME? 1 5.98E+01
#NAME? 1 6.00E+01
#NAME? 1 6.06E+01
#NAME? 1 6.12E+01
#NAME? 1 6.17E+01
#NAME? 1 6.21E+01
#NAME? 1 6.26E+01
#NAME? 1 6.31E+01
#NAME? 1 6.36E+01
#NAME? 1 6.41E+01
#NAME? 1 6.51E+01
#NAME? 1 6.61E+01
#NAME? 1 6.71E+01
#NAME? 1 6.81E+01
#NAME? 1 6.91E+01
#NAME? 1 7.01E+01
#NAME? 1 7.12E+01
#NAME? 1 7.21E+01
#NAME? 1 7.31E+01
#NAME? 1 7.71E+01
#NAME? 1 7.82E+01
#NAME? 1 8.26E+01
#NAME? 1 8.45E+01

Page 7
 Diprotic Acid

#NAME? 1 8.63E+01
#NAME? 1 8.93E+01
#NAME? 1 9.07E+01
#NAME? 1 9.24E+01
#NAME? 1 9.46E+01
#NAME? 1 9.56E+01

Page 8
 Triprotic Acid

Ka1= 2.21E-03 pKa1 2.66

Ka2= 3.70E-05 pKa2 4.43 Titration Curve
Ka3= 8.28E-07 pKa3 6.08 1.40E+01

Kw= 1.00E-14 Mass Acid= 0.1955 1.20E+01

Ca= 0.0022059 Molar Mas 177.3 1.00E+01
Cb= 0.08267 8.00E+00
Va= 100

pH
6.00E+00
Veq= 8.005
4.00E+00
2.00E+00
0.00E+00
Sresid2= 6.386E-06
0.00E+00 5.00E-02 1.00E-01 1.50E-01
Vb/Va
pHexp H OH F Vb/Va(calc) Vexp/Va resid resid2 m

2.83E+00 1.48E-03 6.76E-12 6.20E-01 -1.33E-03 0.00E+00 1.33E-03 1.78E-06 1.48E-03

2.98E+00 1.05E-03 9.55E-12 7.09E-01 6.19E-03 6.70E-03 5.15E-04 2.65E-07 1.60E-03
3.05E+00 8.91E-04 1.12E-11 7.50E-01 9.12E-03 9.50E-03 3.78E-04 1.43E-07 1.67E-03
3.18E+00 6.61E-04 1.51E-11 8.21E-01 1.38E-02 1.36E-02 -1.98E-04 3.91E-08 1.77E-03
3.23E+00 5.89E-04 1.70E-11 8.47E-01 1.54E-02 1.52E-02 -1.66E-04 2.75E-08 1.83E-03
3.29E+00 5.13E-04 1.95E-11 8.77E-01 1.71E-02 1.67E-02 -4.05E-04 1.64E-07 1.87E-03
3.35E+00 4.47E-04 2.24E-11 9.07E-01 1.87E-02 1.85E-02 -2.07E-04 4.27E-08 1.95E-03
3.42E+00 3.80E-04 2.63E-11 9.41E-01 2.04E-02 2.00E-02 -4.27E-04 1.82E-07 2.00E-03
3.50E+00 3.16E-04 3.16E-11 9.80E-01 2.22E-02 2.17E-02 -5.32E-04 2.83E-07 2.07E-03
3.57E+00 2.69E-04 3.72E-11 1.01E+00 2.37E-02 2.36E-02 -9.82E-05 9.65E-09 2.18E-03
3.65E+00 2.24E-04 4.47E-11 1.05E+00 2.53E-02 2.53E-02 2.27E-05 5.14E-10 2.26E-03
3.77E+00 1.70E-04 5.89E-11 1.11E+00 2.75E-02 2.74E-02 -1.18E-04 1.39E-08 2.37E-03
3.83E+00 1.48E-04 6.76E-11 1.14E+00 2.86E-02 2.85E-02 -1.05E-04 1.1E-08 2.44E-03
3.89E+00 1.29E-04 7.76E-11 1.17E+00 2.97E-02 2.95E-02 -1.83E-04 3.33E-08 2.50E-03
3.95E+00 1.12E-04 8.91E-11 1.21E+00 3.08E-02 3.06E-02 -1.58E-04 2.5E-08 2.57E-03
4.02E+00 9.55E-05 1.05E-10 1.24E+00 3.20E-02 3.17E-02 -3.18E-04 1.01E-07 2.64E-03
4.08E+00 8.32E-05 1.20E-10 1.28E+00 3.31E-02 3.28E-02 -3.07E-04 9.42E-08 2.71E-03
4.14E+00 7.24E-05 1.38E-10 1.32E+00 3.42E-02 3.40E-02 -2.06E-04 4.25E-08 2.79E-03
4.20E+00 6.31E-05 1.58E-10 1.35E+00 3.53E-02 3.50E-02 -3.16E-04 1E-07 2.86E-03
4.26E+00 5.50E-05 1.82E-10 1.39E+00 3.64E-02 3.62E-02 -2.36E-04 5.56E-08 2.94E-03
4.35E+00 4.47E-05 2.24E-10 1.45E+00 3.81E-02 3.77E-02 -4.27E-04 1.83E-07 3.05E-03
4.41E+00 3.89E-05 2.57E-10 1.49E+00 3.93E-02 3.89E-02 -3.57E-04 1.27E-07 3.13E-03
4.47E+00 3.39E-05 2.95E-10 1.53E+00 4.04E-02 4.03E-02 -8.27E-05 6.84E-09 3.24E-03
4.53E+00 2.95E-05 3.39E-10 1.57E+00 4.15E-02 4.13E-02 -1.99E-04 3.98E-08 3.31E-03
4.62E+00 2.40E-05 4.17E-10 1.63E+00 4.31E-02 4.27E-02 -4.46E-04 1.99E-07 3.41E-03
4.68E+00 2.09E-05 4.79E-10 1.67E+00 4.42E-02 4.40E-02 -2.19E-04 4.79E-08 3.51E-03
4.74E+00 1.82E-05 5.50E-10 1.71E+00 4.53E-02 4.51E-02 -1.67E-04 2.8E-08 3.59E-03
4.80E+00 1.58E-05 6.31E-10 1.74E+00 4.63E-02 4.72E-02 9.11E-04 8.3E-07 3.74E-03
4.87E+00 1.35E-05 7.41E-10 1.78E+00 4.74E-02 4.84E-02 9.55E-04 9.11E-07 3.83E-03
4.97E+00 1.07E-05 9.33E-10 1.84E+00 4.90E-02 4.91E-02 6.65E-05 4.43E-09 3.88E-03
5.03E+00 9.33E-06 1.07E-09 1.88E+00 5.00E-02 5.02E-02 2.47E-04 6.09E-08 3.96E-03
5.10E+00 7.94E-06 1.26E-09 1.92E+00 5.10E-02 5.14E-02 4.00E-04 1.6E-07 4.05E-03
5.18E+00 6.61E-06 1.51E-09 1.96E+00 5.22E-02 5.25E-02 3.29E-04 1.08E-07 4.13E-03
5.25E+00 5.62E-06 1.78E-09 2.00E+00 5.32E-02 5.36E-02 4.18E-04 1.75E-07 4.21E-03
5.31E+00 4.90E-06 2.04E-09 2.03E+00 5.40E-02 5.42E-02 1.56E-04 2.43E-08 4.26E-03
5.37E+00 4.27E-06 2.34E-09 2.06E+00 5.49E-02 5.47E-02 -2.09E-04 4.38E-08 4.29E-03

Page 9
 Triprotic Acid

5.43E+00 3.72E-06 2.69E-09 2.09E+00 5.58E-02 5.57E-02 -8.19E-05 6.7E-09 4.37E-03

5.49E+00 3.24E-06 3.09E-09 2.13E+00 5.67E-02 5.66E-02 -6.63E-05 4.4E-09 4.43E-03
5.56E+00 2.75E-06 3.63E-09 2.16E+00 5.77E-02 5.76E-02 -1.18E-04 1.4E-08 4.51E-03
5.62E+00 2.40E-06 4.17E-09 2.20E+00 5.86E-02 5.86E-02 -3.99E-05 1.59E-09 4.58E-03
5.69 2.04E-06 4.90E-09 2.24E+00 5.97E-02 5.97E-02 -4.05E-05 1.64E-09 4.66E-03
5.75 1.78E-06 5.62E-09 2.28E+00 6.07E-02 6.07E-02 -5.32E-06 2.83E-11 4.73E-03
5.82 1.51E-06 6.61E-09 2.32E+00 6.19E-02 6.17E-02 -1.54E-04 2.36E-08 4.81E-03
5.89 1.29E-06 7.76E-09 2.36E+00 6.30E-02 6.28E-02 -2.22E-04 4.91E-08 4.89E-03
5.94 1.15E-06 8.71E-09 2.39E+00 6.39E-02 6.37E-02 -1.64E-04 2.68E-08 4.95E-03
5.99 1.02E-06 9.77E-09 2.43E+00 6.47E-02 6.47E-02 -8.82E-06 7.78E-11 5.02E-03
6.06 8.71E-07 1.15E-08 2.47E+00 6.59E-02 6.57E-02 -1.89E-04 3.58E-08 5.10E-03
6.12 7.59E-07 1.32E-08 2.51E+00 6.69E-02 6.71E-02 2.09E-04 4.37E-08 5.20E-03
6.19 6.46E-07 1.55E-08 2.55E+00 6.80E-02 6.81E-02 6.23E-05 3.89E-09 5.27E-03
6.26 5.50E-07 1.82E-08 2.59E+00 6.91E-02 6.90E-02 -1.50E-04 2.24E-08 5.34E-03
6.33 4.68E-07 2.14E-08 2.63E+00 7.02E-02 7.02E-02 -1.62E-05 2.61E-10 5.42E-03
6.4 3.98E-07 2.51E-08 2.67E+00 7.12E-02 7.11E-02 -1.28E-04 1.65E-08 5.49E-03
6.48 3.31E-07 3.02E-08 2.71E+00 7.23E-02 7.20E-02 -3.09E-04 9.56E-08 5.55E-03
6.56 2.75E-07 3.63E-08 2.75E+00 7.33E-02 7.33E-02 -2.22E-06 4.93E-12 5.65E-03
6.65 2.24E-07 4.47E-08 2.78E+00 7.43E-02 7.41E-02 -2.09E-04 4.38E-08 5.70E-03
6.76 1.74E-07 5.75E-08 2.83E+00 7.54E-02 7.53E-02 -8.18E-05 6.69E-09 5.79E-03
6.81 1.55E-07 6.46E-08 2.84E+00 7.58E-02 7.56E-02 -2.13E-04 4.55E-08 5.81E-03
6.87 1.35E-07 7.41E-08 2.86E+00 7.63E-02 7.60E-02 -2.87E-04 8.25E-08 5.84E-03
6.93 1.17E-07 8.51E-08 2.88E+00 7.67E-02 7.65E-02 -2.15E-04 4.64E-08 5.88E-03
7 1.00E-07 1.00E-07 2.89E+00 7.72E-02 7.68E-02 -3.61E-04 1.3E-07 5.90E-03
7.09 8.13E-08 1.23E-07 2.91E+00 7.77E-02 7.75E-02 -1.56E-04 2.44E-08 5.95E-03
7.19 6.46E-08 1.55E-07 2.93E+00 7.81E-02 7.77E-02 -4.15E-04 1.73E-07 5.96E-03
7.31 4.90E-08 2.04E-07 2.94E+00 7.86E-02 7.84E-02 -1.59E-04 2.52E-08 6.01E-03
7.47 3.39E-08 2.95E-07 2.96E+00 7.90E-02 7.87E-02 -3.03E-04 9.18E-08 6.03E-03
7.69 2.04E-08 4.90E-07 2.98E+00 7.94E-02 7.95E-02 8.64E-05 7.47E-09 6.09E-03
8.09 8.13E-09 1.23E-06 2.99E+00 7.98E-02 7.98E-02 -6.57E-06 4.32E-11 6.11E-03
8.96 1.10E-09 9.12E-06 3.00E+00 8.01E-02 8.03E-02 1.66E-04 2.76E-08 6.15E-03
9.5 3.16E-10 3.16E-05 3.00E+00 8.05E-02 8.07E-02 2.47E-04 6.1E-08 6.20E-03
9.76 1.74E-10 5.75E-05 3.00E+00 8.08E-02 8.12E-02 4.03E-04 1.63E-07 6.27E-03
9.93 1.17E-10 8.51E-05 3.00E+00 8.12E-02 8.16E-02 4.41E-04 1.94E-07 6.32E-03
10.16 6.92E-11 1.45E-04 3.00E+00 8.19E-02 8.26E-02 6.61E-04 4.36E-07 6.45E-03
10.25 5.62E-11 1.78E-04 3.00E+00 8.24E-02 8.30E-02 6.24E-04 3.89E-07 6.51E-03
10.32 4.79E-11 2.09E-04 3.00E+00 8.28E-02 8.36E-02 8.15E-04 6.64E-07 6.59E-03
10.38 4.17E-11 2.40E-04 3.00E+00 8.32E-02 8.40E-02 8.08E-04 6.53E-07 6.65E-03
10.44 3.63E-11 2.75E-04 3.00E+00 8.37E-02 8.46E-02 9.41E-04 8.85E-07 6.72E-03
10.49 3.24E-11 3.09E-04 3.00E+00 8.41E-02 8.49E-02 7.99E-04 6.38E-07 6.78E-03
10.54 2.88E-11 3.47E-04 3.00E+00 8.46E-02 8.55E-02 9.02E-04 8.13E-07 6.86E-03
10.58 2.63E-11 3.80E-04 3.00E+00 8.50E-02 8.60E-02 9.61E-04 9.23E-07 6.93E-03
10.62 2.40E-11 4.17E-04 3.00E+00 8.55E-02 8.66E-02 1.08E-03 1.16E-06 7.01E-03
10.66 2.19E-11 4.57E-04 3.00E+00 8.61E-02 8.69E-02 8.46E-04 7.15E-07 7.07E-03
10.69 2.04E-11 4.90E-04 3.00E+00 8.65E-02 8.76E-02 1.11E-03 1.24E-06 7.15E-03
10.72 1.91E-11 5.25E-04 3.00E+00 8.69E-02 8.78E-02 8.50E-04 7.23E-07 7.20E-03
10.77 1.70E-11 5.89E-04 3.00E+00 8.78E-02 8.89E-02 1.10E-03 1.22E-06 7.34E-03
10.83 1.48E-11 6.76E-04 3.00E+00 8.90E-02 9.01E-02 1.14E-03 1.31E-06 7.51E-03
10.88 1.32E-11 7.59E-04 3.00E+00 9.01E-02 9.10E-02 9.48E-04 8.99E-07 7.65E-03
10.92 1.20E-11 8.32E-04 3.00E+00 9.10E-02 9.22E-02 1.17E-03 1.38E-06 7.81E-03

Page 10
 Triprotic Acid

10.96 1.10E-11 9.12E-04 3.00E+00 9.21E-02 9.31E-02 1.00E-03 1E-06 7.95E-03

11.01 9.77E-12 1.02E-03 3.00E+00 9.36E-02 9.46E-02 1.01E-03 1.03E-06 8.17E-03
11.06 8.71E-12 1.15E-03 3.00E+00 9.53E-02 9.62E-02 9.39E-04 8.81E-07 8.40E-03
11.09 8.13E-12 1.23E-03 3.00E+00 9.64E-02 9.74E-02 1.03E-03 1.07E-06 8.57E-03
11.14 7.24E-12 1.38E-03 3.00E+00 9.84E-02 9.94E-02 1.01E-03 1.02E-06 8.85E-03
11.19 6.46E-12 1.55E-03 3.00E+00 1.01E-01 1.02E-01 9.29E-04 8.63E-07 9.17E-03
11.24 5.75E-12 1.74E-03 3.00E+00 1.03E-01 1.04E-01 3.59E-04 1.29E-07 9.50E-03
11.27 5.37E-12 1.86E-03 3.00E+00 1.05E-01 1.06E-01 7.62E-04 5.81E-07 9.76E-03
11.32 4.79E-12 2.09E-03 3.00E+00 1.08E-01 1.09E-01 4.47E-04 1.99E-07 1.02E-02
11.36 4.37E-12 2.29E-03 3.00E+00 1.11E-01 1.11E-01 1.68E-04 2.82E-08 1.06E-02
11.4 3.98E-12 2.51E-03 3.00E+00 1.14E-01 1.14E-01 -1.95E-04 3.8E-08 1.10E-02
11.44 3.63E-12 2.75E-03 3.00E+00 1.17E-01 1.17E-01 -7.29E-05 5.31E-09 1.14E-02
11.48 3.31E-12 3.02E-03 3.00E+00 1.21E-01 1.21E-01 -5.00E-04 2.5E-07 1.19E-02
11.52 3.02E-12 3.31E-03 3.00E+00 1.25E-01 1.24E-01 -1.52E-03 2.3E-06 1.24E-02
11.55 2.82E-12 3.55E-03 3.00E+00 1.28E-01 1.27E-01 -1.68E-03 2.83E-06 1.29E-02
11.58 2.63E-12 3.80E-03 3.00E+00 1.32E-01 1.31E-01 -1.51E-03 2.29E-06 1.34E-02
11.62 2.40E-12 4.17E-03 3.00E+00 1.37E-01 1.35E-01 -2.30E-03 5.31E-06 1.40E-02
11.66 2.19E-12 4.57E-03 3.00E+00 1.43E-01 1.41E-01 -2.56E-03 6.56E-06 1.48E-02
11.7 2.00E-12 5.01E-03 3.00E+00 1.50E-01 1.47E-01 -2.65E-03 7.04E-06 1.56E-02

Page 11
 Triprotic Acid

ation Curve
5
4.5
4
3.5
3
2.5

pH
2
1.5
1
0.5
0
1.00E-01 1.50E-01 2.00E-01 0.00E+00 5.00E+01
Vb/Va Residual
g(Davies) g(Paste Special/Values) Vexp

0.95728 1 0.00E+00
0.955665 1 6.70E-01
0.954713 1 9.50E-01
0.953417 1 1.36E+00
0.952705 1 1.52E+00
0.952158 1 1.67E+00
0.951215 1 1.85E+00
0.950583 1 2.00E+00
0.94975 1 2.17
0.948565 1 2.36
0.947571 1 2.53
0.946357 1 2.74
0.945668 1 2.85
0.945043 1 2.95
0.944321 1 3.06
0.943612 1 3.17
0.942871 1 3.28
0.94205 1 3.4
0.941382 1 3.5
0.940563 1 3.62
0.939561 1 3.77
0.938753 1 3.89
0.937811 1 4.03
0.937157 1 4.13
0.936252 1 4.27
0.935408 1 4.4
0.934707 1 4.51
0.933372 1 4.72
0.932633 1 4.84
0.932219 1 4.91
0.931551 1 5.02
0.930832 1 5.14
0.930181 1 5.25
0.929537 1 5.36
0.92919 1 5.42
0.928903 1 5.47

Page 12
 Triprotic Acid

0.928329 1 5.57
0.927817 1 5.66
0.927254 1 5.76
0.926697 1 5.86
0.92609 1 5.97
0.925544 1 6.07
0.925003 1 6.17
0.924415 1 6.28
0.923938 1 6.37
0.923413 1 6.47
0.922893 1 6.57
0.922173 1 6.71
0.921665 1 6.81
0.921212 1 6.9
0.920613 1 7.02
0.920169 1 7.11
0.919728 1 7.2
0.919097 1 7.33
0.918713 1 7.41
0.918141 1 7.53
0.917999 1 7.56
0.91781 1 7.6
0.917575 1 7.65
0.917434 1 7.68
0.917108 1 7.75
0.917014 1 7.77
0.91669 1 7.84
0.916551 1 7.87
0.916183 1 7.95
0.916041 1 7.98
0.915763 1 8.03
0.915438 1 8.07
0.915048 1 8.12
0.914694 1 8.16
0.913878 1 8.26
0.913495 1 8.3
0.913041 1 8.36
0.912677 1 8.4
0.912201 1 8.46
0.911868 1 8.49
0.911385 1 8.55
0.910973 1 8.6
0.910502 1 8.66
0.910138 1 8.69
0.909656 1 8.76
0.909367 1 8.78
0.908545 1 8.89
0.90756 1 9.01
0.906733 1 9.1
0.90585 1 9.22

Page 13
 Triprotic Acid

0.905055 1 9.31
0.903871 1 9.46
0.902596 1 9.62
0.901716 1 9.74
0.900202 1 9.94
0.898555 1 10.16
0.896908 1 10.36
0.895581 1 10.57
0.89355 1 10.85
0.891787 1 11.1
0.88991 1 11.37
0.88774 1 11.72
0.885582 1 12.05
0.883425 1 12.36
0.881525 1 12.68
0.879437 1 13.06
0.876763 1 13.51
0.87376 1 14.07
0.870521 1 14.71

Page 14
 Differentiate

V, mL pH DV DpH DpH/DV V(ave) D(DpH)/DV2

2.00E+00 3 2.29E+00 3.3333E-01 1.45E-01 3.149157 -0.017681
4.30E+00 3.333333 3.56E+00 3.3333E-01 9.36E-02 6.075378 -0.005221
7.86E+00 3.666667 4.61E+00 3.3333E-01 7.23E-02 10.1598 4.672E-05
1.60E+00
1.25E+01 4 4.60E+00 3.3333E-01 7.25E-02 14.76219 0.005535
1.71E+01 4.333333 3.51E+00 3.3333E-01 9.50E-02 18.81501 0.020444 1.40E+00
2.06E+01 4.666667 2.18E+00 3.3333E-01 1.53E-01 21.65866 0.074604
2.27E+01 5 1.20E+00 3.3333E-01 2.79E-01 23.34486 0.258863 1.20E+00
2.39E+01 5.333333 6.45E-01 3.3333E-01 5.17E-01 24.2648 0.551199
1.00E+00
2.46E+01 5.666667 4.12E-01 3.3333E-01 8.08E-01 24.79333 0.001425

DpH/ DV
2.50E+01 6 4.12E-01 3.3333E-01 8.09E-01 25.20553 -0.551401 8.00E-01
2.54E+01 6.333333 6.44E-01 3.3333E-01 5.18E-01 25.73338 -0.259673
2.61E+01 6.666667 1.19E+00 3.3333E-01 2.79E-01 26.65158 -0.074896 6.00E-01
2.72E+01 7 2.17E+00 3.3333E-01 1.53E-01 28.3341 -0.020528
2.94E+01 7.333333 3.50E+00 3.3333E-01 9.52E-02 31.1705 -0.005548 4.00E-01
3.29E+01 7.666667 4.58E+00 3.3333E-01 7.28E-02 35.20975 4.362E-06 2.00E-01
3.75E+01 8 4.58E+00 3.3333E-01 7.28E-02 39.78711 0.005576
4.21E+01 8.333333 3.50E+00 3.3333E-01 9.53E-02 43.8236 0.020775 0.00E+00
4.56E+01 8.666667 2.16E+00 3.3333E-01 1.54E-01 46.65311 0.078059 0
4.77E+01 9 1.17E+00 3.3333E-01 2.84E-01 48.32075 0.305658
4.89E+01 9.333333 6.00E-01 3.3333E-01 5.55E-01 49.20716 1.057307
4.95E+01 9.666667 3.20E-01 3.3333E-01 1.04E+00 49.66732 1.785944
4.98E+01 10 2.19E-01 3.3333E-01 1.52E+00 49.93674 -0.799686
5.00E+01 10.33333 2.50E-01 3.3333E-01 1.34E+00 50.17096 -1.667688
5.03E+01 10.66667 4.37E-01 3.3333E-01 7.63E-01 50.51405 -0.589439 2
5.07E+01 1.10E+01 9.07E-01 3.3333E-01 3.67E-01 51.18595 -0.138166
5.16E+01 1.13E+01 2.01E+00 3.3333E-01 1.66E-01 52.64227 -0.028419 1.5
5.36E+01 1.17E+01 4.69E+00 3.3333E-01 7.11E-02 55.98777 -0.005187
5.83E+01 1.20E+01 1.23E+01 3.3333E-01 2.72E-02 64.46224 -0.000695 1
7.06E+01 1.23E+01 4.44E+01 3.3333E-01 7.51E-03 92.77989 -0.002909

D(DpH)/ DV^2
1.15E+02 1.27E+01 -1.15E+02 -1.2667E+01 1.10E-01 57.48293 0.001917 0.5

0
0 1
Titration Curve -0.5

14 -1

12 -1.5

10 -2

8
pH

0
0.00E+00 1.00E+01 2.00E+01 3.00E+01 4.00E+01 5.00E+01 6.00E+01 7.00E+01 8.00E+01
Volume NaOH, mL

Page 15
 4

2
Differentiate
0
0.00E+00 1.00E+01 2.00E+01 3.00E+01 4.00E+01 5.00E+01 6.00E+01 7.00E+01 8.00E+01
Volume NaOH, mL

Page 16
 Differentiate

First Derivative
1.60E+00

1.40E+00

1.20E+00

1.00E+00
DpH/ DV

8.00E-01

6.00E-01

4.00E-01

2.00E-01

0.00E+00
0 10 20 30 40 50 60 70 80 90 100
Volume NaOH, mL

Second Derivative
2

1.5

1
D(DpH)/ DV^2

0.5

0
0 10 20 30 40 50 60 70 80 90 100
-0.5

-1

-1.5

-2
Volume NaOH, mL

Page 17
 Ka's & pKa's

Carbonic Ka1= 4.45E-07 pKa1= 6.35

Ka2= 4.69E-11 pKa2= 10.33
Fumaric Ka1= 8.85E-04 pKa1= 3.05
Ka2= 3.21E-05 pKa2= 4.49
Maleic Ka1= 1.30E-02 pKa1= 1.89
Ka2= 5.90E-07 pKa2= 6.23
Malic Ka1= 3.48E-04 pKa1= 3.46
Ka2= 8.00E-06 pKa2= 5.10
Malonic Ka1= 1.42E-03 pKa1= 2.85
Ka2= 2.01E-06 pKa2= 5.70
Oxalic Ka1= 5.60E-02 pKa1= 1.25
Ka2= 5.42E-05 pKa2= 4.27
o-Phthalic Ka1= 1.12E-03 pKa1= 2.95
Ka2= 3.91E-06 pKa2= 5.41
Succinic Ka1= 6.21E-05 pKa1= 4.21
Ka2= 2.31E-06 pKa2= 5.64
Tartaric Ka1= 9.20E-04 pKa1= 3.04
Ka2= 4.31E-05 pKa2= 4.37

Page 18