3ème année licence « chimie fondamentale » Faculté des Sciences Exactes.

Module « Cristallographie » Département de chimie.

Travaux Dirigés N° 2 : Corrigés.
Corrigé Exercice 1 :
A) Cubique centré (I) : z

c
c’
b’
c’
α’
y β’ βγ b’
a b ’
a’ a’ γ’
x

Fig.1 : Maille élémentaire primitive d’un c.c (I).

1°) Maille multiple : c’est la maille conventionnelle du réseau cubique corps centré (I).
r r
a = a ⋅ i
r 1
Vecteurs de translation : b = a ⋅ j .
r
Volume : Vm = a 3 Multiplicité : m = 8 ⋅ + 1 = 2 .
r r 8
c = a ⋅ k
r r r
Maille primitive : Le rhomboèdre obtenu à l’aide du système (a ' , b ' , c ' ) .
r a r r r 1 r 1 r 1 r r r
a ' = 2 ⋅ (i + j − k ) = 2 ⋅ a + 2 ⋅ b − 2 ⋅ c  a'  a
r r  r  1 +1 −1 
 r r r 1 r 1 r 1 r 1  
a  b '  = ( P) ⋅  b  (P) = ⋅  − 1 + 1 + 1
b ' = ⋅ (−i + j + k ) = − ⋅ a + ⋅ b + ⋅ c
 2 2 2 2  r   r  2  
r a r r r 1 r 1 r 1 r
c
  ' c   + 1 − 1 − 1
c ' = 2 ⋅ (i − j + k ) = 2 ⋅ a − 2 ⋅ b + 2 ⋅ c

r r r r r r
(P) est la matrice qui permet le passage du système (a , b , c ) au système (a ' , b ' , c ' ) .
r r v r r v a a⋅ 3
2°) On a a = b = c = a ce qui implique a ' = b ' = c ' = ⋅ 1 + 1 + 1 =
2 2
3°) Pour des raisons de symétrie α ' = β ' = γ ' , calculons par exemple γ ' :
r r
a '⋅b ' r r a2 r r r r r r a2
On a cos γ ' = r r a '⋅b ' = ⋅ (i + j − k ) ⋅ (−i + j + k ) = − , par ailleurs :
a'.b ' 4 4

r r a 3 2 r r 3⋅ a2 r r a2
a '⋅b ' = ( ) ⋅ cos(a ' , b ' ) = ⋅ cos(a ' , b ' ) = − .
2 4 4
r r 1 r r
cos(a ' , b ' ) = − γ ' = (a ' , b ' ) = 109,47° donc α ' = β ' = γ ' = 109,47° = 109° 28'16' ' .
3
+1 +1 −1
r r r a3 a3 a3
4°) Le volume de la maille primitive est : (a '∧b ' ) ⋅ c ' = ⋅ −1 +1 +1 = ⋅ (2 + 2) =
8 8 2
+1 −1 +1
a3
Le volume de la maille conventionnelle est Vm = a 3 . Le volume de la maille primitive est : Ve = .
2
Nous vérifions bien la relation Ve = Vm = Vm pour un c.c
m 2
1
B) Cubique à faces centrées (F) :
z

c
c’

α’
b’ β’ βγ b’
c’
’
b a’ γ’
a y
a’

x
Fig.2 : Maille élémentaire primitive d’un cfc (F).
1°) Maille multiple : c’est la maille conventionnelle du réseau cubique à faces centrées (F).
r r
a = a ⋅ i
r 1 1
Vecteurs de translation : b = a ⋅ j .
r
Volume : Vm = a 3 Multiplicité : m = 8 ⋅ + 6 ⋅ = 4
r r 8 2
c = a ⋅ k
r r r
Maille primitive : Le rhomboèdre obtenu à l’aide du système (a ' , b ' , c ' ) .
r r r r r r
La maille conventionnelle est construite à l’aide de (a , b , c ) dans le système orthonormé (O, i , j , k ) .
Les vecteurs de translation de la maille élémentaire rhomboédrique sont donc :
r a r r 1 r 1 r
a ' = 2 ⋅ ( i + j ) = 2 ⋅ a + 2 ⋅ b 
r
a'  
r
a
r r  r  +1 +1 0
 a r r 1 r 1 r 1  
b ' = ⋅ ( j + k ) = ⋅ b + ⋅ c  b '  = ( Ρ) ⋅  b  (P) = ⋅  0 + 1 + 1
 2 2 2  r   r  2  
r a r r 1 r 1 r
c
  ' c
   + 1 0 + 1
c ' = 2 ⋅ (k + i ) = 2 ⋅ c + 2 ⋅ a

r r v r r v a a⋅ 2
2°) On a a = b = c = a , ce qui implique a ' = b ' = c ' = ⋅ 1 + 1 + 0 =
2 2
3°) Pour des raisons de symétrie α ' = β ' = γ ' , calculons par exemple γ ' :
r r a2 r r r r a2
a '⋅b ' = ⋅ (i + j ) ⋅ ( j + k ) =
4 4
r r a 2 2 r r 2 ⋅ a2 r r a2
a '⋅b ' = ( ) ⋅ cos(a ' , b ' ) = ⋅ cos(a ' , b ' ) =
2 4 4
r r 1 r r π
Ce qui donne : cos(a ' , b ' ) = ou γ ' = (a ' , b ' ) = = 60° Donc : α ' = β ' = γ ' = 60°
2 3
1 1
4°) La multiplicité d’une maille cfc est m = 8 ⋅ + 6 ⋅ = 4
8 2
+1 +1 0
r r r a3 a3 a3
Le volume de la maille primitive est : (a '∧b ' ) ⋅ c ' = ⋅ 0 +1 +1 = ⋅ (1 + 1) =
8 8 4
+1 0 +1
a3
Le volume de la maille conventionnelle est Vm = a 3 . Le volume de la maille primitive est Ve = .
4
V m Vm
Nous vérifions bien la relation Ve = = avec m = 4 pour un cfc.
m 4
2
Corrigé Exercice 2 :
r 1 r r
a ' = 2 ⋅ ( a − b ) r r r
a = a '+b '
r  r
 1 r r r r
1°) b ' = ⋅ (a + b ) donc b = − a '+b '
 r r2 cr = cr '
c ' = c 


 1 −1 0   1 1 0
1    
(Ρ ) = ⋅  1 1 0  (Ρ −1 ) =  − 1 1 0 
R→R ' 2   R '→ R  0 0 1
 0 0 2  
 h'   h
   
2°) D’après le cours :  k '  = ( P) ⋅  k 
 l'  l
  R'  R
 h'  1 −1 0  1   2 1
  1 
 k ' = ⋅  1
2 
   1    
1 0  ⋅  − 1 = ⋅  0  =  0 
2  
(111)
R → (101)R '
 l'  0 2   1  R  
  R' 0  2  R'  1  R'
 h'  1 −1 0   0   − 1
  1     1  
 k ' = ⋅  1
2 
1 0 ⋅1 = ⋅ 1 
2  
(012 ) R ( )
→ 114 R'
 l'  0 2   2  R
 R' 0  4 R'

 h'   1 −1 0   1   − 1
  1     1  
 k ' = ⋅  1 1 0  ⋅  2 = ⋅  3  (121)R → (132)R '
 l'  2     2  
  R'  0 0 2  1 R  2  R'

h  h' 
  −1
 
3°) D’après le cours :  k  = ( P) ⋅  k ' 
l  l' 
 R   R'

h  1 1 0  1  2
       
 k  =  −1 1 0  ⋅ 1 =  0  (111)R ' → (201)R
l  0 0 1  1 R '  1  R
 R 
h  1 1 0 0 1
       
 k  =  −1 1 0 ⋅1 = 1 (012)R ' → (112 )R
l  0 0 1   2  R '  2  R
 R 
 h   1 1 0  2  4
       
 k  =  −1 1 0  ⋅  2 =  0  (223)R ' → (403)R
 l   0 0 1   3  
 R     R'  3  R
 u'  u
  t −1  
4°) D’après le cours :  v'  = ( P ) ⋅  v 
 w'   w
 R'  R
 u'   1 −1 0  0  − 1
       
 v'  =  1 1 0  ⋅  1  =  1  [010 ]R → [11 0 ]R '
 w'       
  R'  0 0 1   0  R  0  R'

3
 u'   1 −1 0  2 1
       
 v'  =  1 1 0  ⋅  1  =  3  [213 ]R → [1 3 3]R '
 w'       
  R'  0 0 1   3  R  3 R'
 u'   1 − 1 0   3  2 
       
 v'  =  1 1 0  ⋅  1  =  4  [313 ]R → [2 4 3]R '
 w'       
  R '  0 0 1   3 R  3  R'
u   u' 
  t  
5°) D’après le cours :  v  = ( P) ⋅  v' 
 w  w' 
 R   R'

u 1 1 0  0  2 1
  1     1    
 v  = ⋅  −1 1 0  ⋅  2  = ⋅  2  = 1 [021]R ' → [111]R
 w 2  2  
 R 0 0 2   1  R '  
 2  R ' 1 R '
u 1 1 0   1  2 1
  1     1    
 v  = ⋅  −1 1 0  ⋅  1 = ⋅  0  =  0  [113 ]R ' → [1 0 3]R
 w 2  2  
 R 0 0 2   3  R '  
 6  R '  3  R'

u  1 1 0  2  4  2
  1     1    
 v  = ⋅  −1 1 0 ⋅  2 = ⋅  0 =  0 [223 ]R ' → [2 0 3]R
 w 2     2    
 R  0 0 2   3  R'  6  R '  3  R'

Corrigé Exercice 3 : Transformation hexagonal↔ trigonal :

r 2r 1r 1v
a R = 3 a H + 3 bH + 3 cH
(Ρ)
r r
r  aR  2 1 1  a H 
 1r 1r 1v r  1   r 
bR = − a H + bH + cH ou sous forme matricielle :  bR  = ⋅  − 1 1 1 ⋅  bH 
 3 3 3  cv  3  − 1 − 2 1  cv 
v 1r 2 r 1v  R    H
cR = − 3 a H − 3 bH + 3 cH
H →R


r
 arR = bR = cvR
1°) On doit montrer que : 
α R = β R = γ R
r 2r 1r 1v
a R = a H + bH + c H
3 3 3
r 2 r r 2r 1r 1v 2r 1r 1v
a R = a R ⋅ a R = ( a H + bH + cH ) ⋅ ( a H + bH + c H )
3 3 3 3 3 3

4
 5 2 2 2 1 2 1 2 1 2 1
= ⋅ a H − ⋅ a H + ⋅ cH = ⋅ a H + ⋅ cH = ⋅ (3 ⋅ a H2 + cH2 )
9 9 9 3 9 9
r 1 r 1 r 1
a R = ⋅ 3 ⋅ a H2 + c H2 de même on a par symétrie : bR = ⋅ 3 ⋅ a H2 + cH2 et cR = ⋅ 3 ⋅ a H2 + cH2
3 3 3
r r r r v r
a ⋅b b ⋅c c ⋅a
On a également cos γ R = r R rR ; cos α R = r R rR et cos β R = v R rR
a R ⋅ bR bR ⋅ c R cR ⋅ a R cR
r r r r r r
On doit montrer que a R ⋅ bR = bR ⋅ c R ⋅ = cR ⋅ a R
r r 2 r 1 r 1v   1 r 1 r 1 v  βR αR
a R ⋅ bR =  ⋅ a H + ⋅ bH + cH  ⋅  − ⋅ a H + ⋅ bH + ⋅ cH  RR bR
3 3 3   3 3 3  R
2 2 1 1 1 1 1 1 1 γR
= − ⋅ a H2 − ( ) ⋅ ( ) ⋅ a H2 +   ⋅ ( ) ⋅ a H2 + ⋅ a H2 + c H2 = − ⋅ a H2 + ⋅ cH2 ’
9 9 2 9 2 9 9 6 9 aR
r r  1r 1r 1v   1r 2r 1v 
bR ⋅ c R =  − a H + bH + cH  ⋅  − a H − bH + c H 
 3 3 3   3 3 3 
1 1 1 2 1 1 1
= ⋅ a H2 − ⋅ a H2 + ⋅ a H2 − ⋅ a H2 + ⋅ c H2 = − ⋅ a H2 + ⋅ cH2
9 9 18 9 9 6 9
v r  1r 2 r 1 v  2 r 1 r 1v 
cR ⋅ a R =  − a H − bH + cH  ⋅  a H + bH + cH 
 3 3 3  3 3 3 
2 1 4 2 1 1 1
= − ⋅ aH2 + ⋅ aH2 + ⋅ aH2 − ⋅ aH2 + ⋅ cH2 = − ⋅ aH2 + ⋅ cH2
9 18 18 9 9 6 9
r r r r r r
a R ⋅ bR = bR ⋅ c R ⋅ = cR ⋅ a R donc cos α R = cos β R = cos γ R et α R = β R = γ R , le réseau est rhomboédrique.

2°) Calculons ( P) −1 la matrice de passage du réseau R vers le réseau H :

 2 1 1
1  
( P) = ⋅  − 1 1 1
3  
 − 1 − 2 1 H →R
1 1
-) ∆ = ( ) 3 ⋅ (6 + 3) =
3 3
 3 0 3 1 0 1
1 2   1  
-) Cofact. = ( ) ⋅  − 3 3 3  = ⋅  − 1 1 1
3   3  0 − 1 1
 0 − 3 3  
r r r
1 −1 0  1 −1 0  a H = a R − bR
1   −1
   r r v
t
Cofact. = ⋅  0 1 − 1 donc ( P) =  0 1 − 1 donc bH = bR − c R
3     v r r v
1 1 1  1 1 1  R→ H c H = a R + bR + c R

r (Ρ) r r (Ρ) −1 r
 aR  2 1 1  a H   aH   1 − 1 0   aR 
r  1   r  r    r 
 bR  = ⋅  − 1 1 1 ⋅  bH   bH  =  0 1 − 1 ⋅  bR 
 cv  3  − 1 − 2 1  cv   cv   1 1 1   cv 
 R    H  H    R
H →R R→H

3°) Comparaison de VR et VH :
r r r
VR = (aR ∧ bR ) ⋅ cR
142 r
43
S

5
 r r r 2 r 1 r 1 r 1 r 1 r 1 r
S = (aR ∧ bR ) = ( ⋅ aH + ⋅ bH + ⋅ cH ) ∧ (− ⋅ aH + ⋅ bH + ⋅ cH )
3 3 3 3 3 3
2 r r 1 r r 2 r r 1 r r 1 r r 1 r r
= ( a H ∧ b H ) + ⋅ ( a H ∧ b H ) + ( a H ∧ c H ) + (b H ∧ c H ) + ( a H ∧ c H ) − (b H ∧ c H )
9 9 9 9 9 9
1 r
[ r r r
]
= ⋅ ( a H ∧ bH ) + ( a H ∧ c H )
3
1 r
3
[ r r r
] 1 r
3
2 r
3
1 r
VR = ⋅ ( a H ∧ bH ) + ( a H ∧ c H ) ⋅ ( − ⋅ a H − ⋅ bH + ⋅ cH )
3
1 1 r r r 2 r r r  1 1 2  1
= ⋅  ⋅ (aH ∧ bH ) ⋅ cH + ⋅ (cH ∧ aH ) ⋅ bH  = ⋅  ⋅ VH + ⋅ VH  = ⋅ VH
3 3 3  3 3 3  3
r r r
Remarque : VH = a H ∧ bH ⋅ cH = a 2H ⋅ c H ⋅ ( 3 / 2) .
 x'   x  x  x' 
  t −1     t  
4°) D’après le cours :  y'  = ( P ) ⋅  y  et  y  = ( P) ⋅  y ' 
 z'  z z  z' 
 R  H  H  R
 x'   x  1 0 1 1 / 2   1/ 2 
  t −1         1 1  1 1
 x'  = ( P ) ⋅  y  =  − 1 1 1 ⋅ 1 / 2  =  0  M :  , ,0  → M :  ,0,− 
 z'  z        2 2 H 2 2 R
 R   H  0 − 1 1  0  H  − 1 / 2  R

 x  x'   2 − 1 − 1   1/ 3   − 1/ 9
  t   1       1 2 1  1 1 4
 y  = ( P) ⋅  y '  = ⋅  1 1 − 2  ⋅  2 / 3  =  1 / 9  N :  , ,  → N : − , , 
z  z'  3   3 3 3 R  9 9 9 H
 H  R 1 1 1   1 / 3  R  4 / 9  H
Question supplémentaire : Déterminer les indices des rangées suivantes dans le réseau R :
[001]H → [u ' v ' w']R et [ ] 111 H → [u ' v ' w ']R
 u'  u 1 0 1  0  1
  t −1        
 v'  = ( P ) ⋅  v  =  − 1 1 1 ⋅  0  = 1 [001]H → [111]R
 w'   w      
 R   H  0 − 1 1  1  H 1 R
r
L’axe cH du système hexagonal coincide avec la diagonale principale du rhomboèdre.

 u'  u 1 0 1  − 1 0

  t −1        
 v'  = ( P ) ⋅  v  =  − 1 1 1 ⋅  1  =  3  [ ]
111 H → [0 1 0 ]R
 w'   w  0 − 1 1  1  0
 R  H    H  R
r
La diagonale principale du prisme héxagonal qui passe par le motif est parallèle à l’axe bR du
rhomboèdre. Ce qui se vérifie bien géométrique.
[001]H = [111]R 111 H [ ]
[010]R

6
Corrigé Exercice 4 : Transformation CFC↔ Rhomboédrique↔Hexagonal.
CFC 
→ R
→ H
(P ) 1
( P2 )

(P )
r r r r r r
Réseau CFC : Caractérisé par les vecteurs de translation cubiques : a c = a ⋅ i ; bc = a ⋅ j ; cc = a ⋅ k
r r v
a c = bc = c c = a . α c = β c = γ c = 90°
( P1 )
Transformation : CFC  → R (voir exo. 1 TD2)
Les vecteurs de translation de la maille élémentaire rhomboédrique sont donc :
r a r r 1 r r
a
 R 2 = ⋅ ( i + j ) = ⋅ (a c + bc ) r r
r
2  aR   ac  1 1 0
a r r 1 r r r  r   
  bR  = (Ρ1 ) ⋅  bc  1
bR = ⋅ ( j + k ) = ⋅ (bc + c c ) ( P1 ) = ⋅  0 1 1
 2 2  r   r  2 
r c
  c
  1 0 1 
r a r 1 r r R c
c
 R 2 = ⋅ ( k + i ) = ⋅ ( c c + a c ) C→R
 2
r r v a a⋅ 2 r r a2 r r r r a2
a R = bR = c R = ⋅ 1 + 1 + 0 = a R ⋅ bR = ⋅ (i + j ) ⋅ ( j + k ) =
2 2 4 4
r r a 2 2 r r 2 ⋅ a2 r r a2 r r 1
a R ⋅ bR = ( ) ⋅ cos(a R , bR ) = ⋅ cos(a R , bR ) = cos(a R , bR ) =
2 4 4 2
π
Ce qui donne : γ R = = 60° et donc : α R = β R = γ R = 60° .
3
Le réseau est bien rhomboédrique.
Transformation : CFC  →
(P )
H

Les vecteurs de translation de la maille élémentaire hexagonale sont :

r a r r 1 r r
 a H = ⋅ ( − i + j ) = ⋅ ( − a c + bc ) r r
r
2 2  aR   ac   −1 1 0
r r r r r  r  1  
 a 1   = Ρ ⋅  bc 
bH = ⋅ (− j + k ) = ⋅ (−bc + cc ) bR ( ) ( P) = ⋅  0 − 1 1 
 2 2  r 
 cR   r  2  
r r r r 1 r r r    cc   2 2 2
c H = a ⋅ (i + j + k ) = 2 ⋅ (a c + bc + cc ) CFC → R


r r a a⋅ 2 v a
a H = bH = ⋅ 1 + 1 + 0 = cH = ⋅ 1+1+1 = a ⋅ 3
2 2 2
r r 1 r r r r a2 r r r r r a2
cos(a H , bH ) = − (a H , bH ) = 120° aH ⋅ cH = ⋅ ( −i + j ) ⋅ ( i + j + k ) = ⋅ (−1 + 1) = 0
2 2 2
r r a 2 r r r r r a2
bH ⋅ c H = ⋅ ( − j + k ) ⋅ (i + j + k ) = ⋅ (−1 + 1) = 0 donc α H = β H = 90° .
2 2
Le réseau est bien hexagonal.

7
 1 1 0  − 1 1 0
1   1  
Selon le cours : ( P) = ( P2 ) ⊗ ( P1 ) avec ( P1 ) = ⋅  0 1 1  et ( P) = ⋅  0 − 1 1 
2   2 
1 0 1  2 2 2 
( P ) ⊗ ( P1 ) −1 = ( P2 ) ⊗ (( P1 ) ⊗ ( P1 ) −1 ) or ( P1 ) ⊗ ( P1 ) −1 = I Donc : ( P2 ) = ( P ) ⊗ ( P1 ) −1
1 1 0
1   3 2
1 1
∆ =   ⋅ [1 + 1] =   =
−1 1
Calculons ( P1 ) : ( P1 ) = ⋅  0 1 1 
2   2 2 4
1 0 1
2  1 1 − 1 2  1 −1 1   1 −1 0 
1   1   −1
 
Cofact.( P1 ) =   ⋅  − 1 1 1  ; Cofact.( P1 ) =   ⋅  1 1 − 1 ; ( P1 ) =  1 1 − 1
t

2   2   −1 1

 1 −1 1  −1 1 1   1 
 −1 1 0  1 −1 0   0 2 − 2   0 1 − 1
1 
−1
   1    
( P2 ) = ( P) ⊗ ( P1 ) = ⋅  0 − 1 1  ⋅  1 1 − 1 = ⋅  − 2 0 2  = ⋅ − 1 0 1 
2     2  2
 2 2 2  −1 1 1   2 2   1 1 1 
R→H
 1 1 0   0 1 − 1  1 0 0
−1 1      
Vérification : ( P1 ) ⊗ ( P1 ) = ⋅  0 1 1  ⋅  − 1 0 1 ⋅ =  0 1 0  = (I )
2     
1 0 1  1 1 1  0 0 1 
 0 1 − 1
−1
 
Calculons ( P2 ) : ( P2 ) =  − 1 0 1  ∆ = 2 +1 = 3
1 1 1
 
 − 1 2 − 1  − 1 − 1 1  − 1 − 2 1
    −1 1  
Cofact.( P2 ) =  − 2 1 1  ; Cofact.( P2 ) =  2 1 1 ; ( P2 ) = ⋅  2
t
1 1
 1 1 1  − 1 1 1 3  
     − 1 1 1
 − 1 − 2 1  0 1 − 1  1 0 0 
−1 1      
Vérification : ( P2 ) ⊗ ( P2 ) = ⋅  2 1 1 ⋅  − 1 0 1  =  0 1 0  = ( I )
3      
 − 1 1 1  1 1 1   0 0 1 
Remarque : ( P ) −1 = ( P1 ) −1 ⊗ ( P2 ) −1
2°) (h k l ) c (→
P1 )
(h' k ' l ' ) R (→

P2 )
(h' ' k ' ' l ' ' ) H
 h'  1 1 0  1 1  2
  1       1  
 k ' = ⋅  0 1 1  ⋅ 1 =  1  = ⋅  1  (111) c 
→(211) R
 l'  2  2  
 R 1 0 1  1C  0 C  1 R
 h' '  0 1 − 1  2  0
       
 k ' ' =  − 1 0 1  ⋅  1  =  − 1 (211) R 
→(01 4) H
 l' '   1 1   1  R  4  H
 H  1
(111) c 
→(211) R 
→(014) H

 h' '   2  −1 1 0 1 0

    1     1  
Vérification :  k ' '  = ( P) ⋅  1  = ⋅  0 − 1 1  ⋅  1  = ⋅  − 1
 l' '  1 2     2  
 H  R  2 2 2   0 C  4 H
(111) c 
→(01 4) H

8
3°) [u v w]c  →[u ' v' w']R  →[u ' ' v' ' w' ']H
t −1 t −1
( P1 ) ( P2 )

 u'   1 1 − 1 1 1  u' '   − 1 2 − 1 1 0 0

          1     1    
 v'  =  − 1 1 1  ⋅ 1 = 1  v' '  = ⋅  − 2 1 1  ⋅ 1 = ⋅  0  =  0 
 w'         w' '  3     3    
  R  1 − 1 1  1 C 1 R  H  1 1 1  1 C  3 R 1R
[111]c →[111]R →[0 01]H
Vérification : [u v w]c  →[u ' ' v' ' w' ']H
t −1
(P )

 1 − 1 0   − 1 − 2 1  − 4 − 2 1
−1 −1 1  −1
   1  
( P) = ( P1 ) ⊗ ( P2 ) = ⋅  1 1 − 1 ⋅  2 1 1 = ⋅  2 − 2 1
3     3  2
 − 1 1 1   − 1 1 1  4 1
 u' '   − 4 2 2  1  0  0
  1     1    
 v' '  = ⋅  − 2 − 2 4  ⋅ 1 = ⋅  0  =  0 
 w' '  3  3  
 H  1 1 1  1 C  
 3H  1 H
On retrouve ainsi le même résultat.

Corrigé Exercice 5 :
1°) Plans réticulaires : (100), (110), (111); (011), (321) .

2°) Famille de plan 111 : { }

(001)

(010)
(100)

Les plans équivalents sont : { (111);(1 1 1); (1 1 1), (1 11), (11 1 ), (1 1 1 ), (1 1 1 ), (1 1 1 )}

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