By : Nabil Remila

H2O2 ( 1) .1
( 1) H2O2 2I 2H I2 2H2O I

I2 .2
(prlvement)
trempe ( 1)
S2O32 I2
( 2) I2 2S2O32 2I S4O62 ( 2) .3

.1
C1 0, 056mol.L1 H2O2 V1 50mL

C2 0, 2mol.L1 (K I ) V2 50mL

.2
C3 0, 04mol.L1 ( 2Na S2O32 )
S2O32 t 1min I2 .3

V0 10mL

Prof

:Nabil Remila

t 0
VT 100mL

t 1min

I2

123
VE
t .4

VE t
t(min) 1 3 4, 5 6 8, 5 12 15 18 24
VE (mL) 2, 2 4, 8 6, 3 7, 3 9, 0 10, 6 11, 7 12, 7 13, 7

By : Nabil Remila

.5
t [I2 ]
VE C3 V0


VE [I2 ]

(S O )

(I )

2
( 2) I2 2S2O3 2I S4O6
C3VE
[I2 ]V0 C3VE
n(I2 ) n( S2O32 )
[I2 ]

2V0
1
2
1
2

!!

:Nabil Remila

[I2 ]

C3VE
t [I2 ]
2V0

VE ( 1) x
( 1)
H2O2
2I
2H I2 2H2O
x n(I2 ) t

C
V

n1 C1V1
2
2 2
0
x [I2 ].VT

Prof

0
x n1 x n 2 2x
xf n1 xf n 2 2xf

x
xf

C3VE

2V0
(V V )
CV
x 1 2 C3VE x 3 E .VT
2V0
2V0
( 50 50)
x 0, 2VE x
0, 04VE
2 10

[I2 ]

x f (t )

t(min) 1 3 4, 5 6 8, 5 12 15 18 24








x(mmol)
m mol x mL VE x 0, 2VE

t(min) 1 3 4, 5 6 8, 5 12 15 18 24
VE (mL) 2, 2 4, 8 6, 3 7, 3 9, 0 10, 6 11, 7 12, 7 13, 7
0, 2
x(mmol) 0, 44 0, 96 1, 26 1, 46 1, 8 2,12 2, 34
2, 54
2, 74

X f (t ) .6