TP : Thermodynamique et Cinétique chimique L 2 Chimie

Groupe : Nom et prénom :

1 ° ------------------------------------------------------------------------------------------------------------
------
2 ° ------------------------------------------------------------------------------------------------------------

Compte rendu TP 3 : Mesure du volume molaire de mélange

On donne :

W (%) 0 10 20 30 40 50 60 70 80 90 100
ρ
0,9971 0,9804 0,9664 0,9507 0,9315 0,9098 0,8870 0,8634 0,8391 0,8135 0,7890
(g/ml)

1 ° / compléter le tableau suivant :

Exemple de calcule pour le premier et le deuxième point :

------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------

X1
Vm
(ml/mol)

2 ° / déduire à partir du tableau précédant le volume molaire de l'eau pur et le volume molaire d’éthanol pur

------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------

L’année Universitaire : 1
2020 / 2021
TP : Thermodynamique et Cinétique chimique L 2 Chimie

3 ° / compléter le tableau suivant :

------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------

X1
∆Vm
(ml/mol)

4 ° / représenter en fonction de x1 les variations de ∆Vm , donc : tracer la courbe ∆Vm = f(x1)

5° / tracer la tangente à la courbe pour la composition 56% (pourcentage massique) et déduire les volumes molaires
partielles d’éthanol et l’eau.

------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------
------------------------------------------------------------------------------------------------------------------------------------------------------------

L’année Universitaire : 2
2020 / 2021