( ρΎΑήϟ΍ ) ΔϟΪϴμϟ΍ϭ ΐτϟ΍ ΔϴϠϜϟ ϰϟϭϷ΍ ΔϨδϟ΍ ΝϮϟϭ Γ΍έΎΒϣ ΢ϴΤμΗ

2014/2013
ΕΎϴοΎϳήϟ΍ ΓΩΎϣ

:1 ϦϳήϤΘϟ΍
2S
1 i i
.t ϭ z 2e 3
ϦϴϴϟΎΘϟ΍ ϦϴϳΪϘόϟ΍ ϦϳΩΪόϟ΍ ήΒΘόϧ
2
:ΎϨϳΪϟ ˬ Ϧϣ ΍ήμϨϋ n ϦϜϴϟ-(1
tn  œ Im
I tn 0
§§ 1 i ·
n
·
œ Im ¨ ¨  ¸ ¸ 0
¨© 2 2¹ ¸
© ¹
§  i nS ·
œ Im ¨ e 4 ¸ 0
© ¹
§ nS ·
œ  sin ¨ ¸ 0
© 4 ¹
nS
œ { 0 >S @
4
œ 4|n
:ΎϨϳΪϟ -(2
§ z2 ·
arg ¨ 3 ¸ { 2 arg z  3arg t > 2S @
©t ¹
4S 3S
{  > 2S @
3 4
7S
{ > 2S @
12
:ΎϨϳΪϟ -(3
§ 2S ·
z u cos ¨10 u
10
Re z10 ¸
© 3 ¹
§ 2S ·
210 u cos ¨ 6S  ¸
© 3 ¹
1
210 u
2
2 9

512
 4
:ΎϨϳΪϟ -(4
1 t9
1 t  t2   t8
1 t
9S

1 e 4

S

1 e 4

S

1 e 4

S

1 e 4

1
:2 ϦϳήϤΘϟ΍
­ 1 § 1  x2 ·
°f x ln ¨ ¸ ;x z 0
® x © 1  x2 ¹ :ΚϴΤΑ @1;1> ϰϠϋ Δϓήόϣ f ΔϳΩΪόϟ΍ Δϟ΍Ϊϟ΍
°f 0 0
¯
:ΎϨϳΪϟ -(1
1 § 1  x2 ·
lim f x lim ln ¨ 2 ¸
x o0 x o0 x
© 1 x ¹
1 1
lim ln 1  x 2  ln 1  x 2
x o0 x x
ln 1  x 2
ln 1  x 2
lim  x u  xu
x o0  x2 x2
§ ln 1  x 2 ln 1  x 2 ·
lim  x u ¨  ¸
x o0 ¨  x2 x2 ¸
© ¹
0
. 0 ϲϓ ΔϠμΘϣ f Δϟ΍Ϊϟ΍ ϥΈϓ lim f x f 0 ϥ΃ ΎϤΑ
x o0

:ΎϨϳΪϟ -(2
f x 1 § 1 x 2 ·
lim lim u ln ¨ 2 ¸
x o0 x x o0 x 2
© 1 x ¹
ln 1  x 2 ln 1  x 2
lim  
x o0 x 2 x2
1  1
2

f x f 0 f x
. fc 0 2 ϭ 0 ϲϓ ϕΎϘΘηϺϟ ΔϠΑΎϗ f Δϟ΍Ϊϟ΍ ϥΈϓ lim lim 2 ϥ΃ ΎϤΑ-(3
x o0 x x o0 x
:ΎϨϳΪϟ x z 0 ϭ x  @1;1> ϞΟ΃ Ϧϣ -(4
 § § 1 ·2 ·
¨ 1 ¨ ¸ ¸
§1·
f ¨ ¸ xln ¨ © ¹ 2 ¸
x
©x¹ ¨ §1· ¸
¨ 1 ¨ ¸ ¸
© ©x¹ ¹
§ x2 1 ·
¨ 2 ¸
xln ¨ 2x ¸
¨ x 1 ¸
¨ 2 ¸
© x ¹
§ x2 1 ·
xln ¨ 2 ¸
© x 1¹
:3ϦϳήϤΘϟ΍
:ΎϨϳΪϟ. Ϧϣ ΍ήμϨϋ n ϦϜϴϟ -(1
3
1
un 1  1 4  un
vn 1
un 1  3 3
3
4  un
1  u n
9  3un
1 un  1
u
3 un  3
1
vn
3
n
§1· 1 1
vn ¨ ¸ v0 n 1
:ϥΫ· . ΎϬγΎγ΃ ΔϴγΪϨϫ vn ΔϴϟΎΘΘϤϟ΍ ϪϨϣϭ
©3¹ 3 3

. Ϧϣ ΍ήμϨϋ n ϦϜϴϟ-(2
:ΔϴϟΎΘΘϤϟ΍ ΎϨϳΪϟ
wn 1  wn ln vn 1  ln vn
§ u 1 · § un  1 ·
ln ¨ n 1 ¸  ln ¨ ¸
© un 1  3 ¹ © un  3 ¹
§ 3 ·
¨ 4  u 1 ¸ § u 1 ·
ln ¨ n
¸  ln ¨ n ¸
¨ 3 3¸ © un  3 ¹
¨ 4u ¸
© n ¹
§ 1  un · § un  1 ·
ln ¨ ¸  ln ¨ ¸
© 9  3un ¹ © un  3 ¹
§ 1 u  1 un  3 ·
ln ¨ u n u ¸
© 3 un  3 un  1 ¹
 ln 3

.  ln 3 ΎϬγΎγ΃ ΔϴΑΎδΣ wn ΔϴϟΎΘΘϤϟ΍ ϪϨϣϭ

 :ΎϨϳΪϟ-(3
§ 1 §1·
n
·
ln v0 u v1 u u vn l ¨ v0 u v0 u u ¨ ¸ v0 ¸
ln
¨ 3 ©3¹ ¸
© ¹
§ §1·
1 2   n
·
ln ¨ v0n 1 u ¨ ¸ ¸
¨ ©3¹ ¸
© ¹
§ n 1
n n 1
·
¨ §1· §1· 2 ¸
ln ¨ ¸ u ¨ ¸
¨¨ © 3 ¹ © 3¹ ¸¸
© ¹
§ n 1 n  2
·
¨ §1· 2 ¸
ln ¨ ¸
¨¨ © 3 ¹ ¸¸
© ¹
§ 1 ·
n  1 n  2 ln ¨ ¸
© 3¹
 n  1 n  2 ln 3

:ΎϨϳΪϟ Ϧϣ ΍ήμϨϋ n ϦϜϴϟ -(4

un  1 3vn  1
vn Ÿ un
un  3 vn  1

.ΔΑέΎϘΘϣ un ΔϴϟΎΘΘϤϟ΍ ϲϟΎΘϟΎΑϭ ˬ lim un 1 ϥΈϓ lim vn 0 ϥ΃ ΎϤΑϭ

:4 ϦϳήϤΘϟ΍
ϭ p A‰ B 0,8 ϭ p B 0,3 ϭ p A 0, 4 ϭ ϥϼϘΘδϣ C ϭ A ΚϴΤΑ C ϭ B ϭ A Ι΍ΪΣϷ΍ ήΒΘόϧ ϲϟΎϤΘΣ΍ ˯Ύπϓ ϲϓ
. p AˆC 0, 2

:ΎϨϳΪϟ B ϭ A ϦϴΛΪΣ ϞϜϟ ϪϧϷ ˬΔϨϜϤϣ ήϴϏ p A ‰ B 0,8 ϭ p B 0,3 ϭ p A 0, 4 ϢϴϘϟ΍ -(1

p A‰ B d p A  p B

:ΎϨϳΪϟ
p A ˆB p A  p B  p A ‰B
0, 4  0,3  0,5
0, 2
. p AˆC p A u p C :ϥΈϓ ϦϴϠϘΘδϣ B ϭ A ϦϴΛΪΤϟ΍ ϥ΃ ΎϤΑ-(2

p A ˆC 0, 2
p C 0,5 : ϥΫ·
p A 0, 4
.ΊρΎΧ (2Ώ΍ϮΠϟ΍ ϪϨϣϭ
:ΎϨϳΪϟ -(3
p A‰C p A  p C  p AˆC
0, 4  0,5  0, 2
0, 7
 p A ˆB 0, 2
(ϖϘΤΗ A ϥ΃ ΎϤϠϋ B ϝΎϤΘΣ΍) p A B 0,5 -(4
p A 0, 4

˯Ύϳΰϴϔϟ΍ ΓΩΎϣ
1 ϦϳήϤΘϟ΍
.έΎδϜϧϹ΍ ΓήϫΎυ ΙΪΤΗ ήΧϵ ςγϭ Ϧϣ Ύϫέϭήϣ ΪϨϋϭ ΔϴϜϴϧΎϜϴϣ ΔΟϮϣ έΎθΘϧ΍ ˯ΎϨΛ΃ .1
: Ȝ2 ΏΎδΣ .2
Ȝ= మ
1 = ˜ଵ .T1 ΎϨϳΪϟ

Ȝ1 =  ల
ϱΩΪϋ ϖϴΒτΗ

Ȝ1= 750 —m
: ΏΎδΣ
˜ =Ȝ2 . ˜ଵ ΎϨϳΪϟ
= 250 x 10-6 x6.10-6 ϱΩΪϋ ϖϴΒτΗ
= 1500 m/s

2 ϦϳήϤΘϟ΍
: ΐΘϜϧ ϲϋΎόηϹ΍ κϗΎϨΘϟ΍ ϥϮϧΎϗ ΐδΣ .1
a(t) = a0‡
a0(t) – ȜN0e-Ȝt = 0

a(t) + N0 =0

a(t) + = 0
భȀమ
a(t) + =0 ϥΫ·

: ϞϜθϟ΍ ϰϠϋ ΐΘϜϳ ΔϘΑΎδϟ΍ ΔϴϠοΎϔΘϟ΍ ΔϟΩΎόϤϟ΍ ϞΣ .2

N= ϊϣ a(t) =ƒ

a(t) = ƒ଴ ‡ ౪భȀమ
ϥ΃ ΞΘϨΘδϧ ϪϨϣϭ

: t= 3t1/2 ΔψΤϠϟ΍ ΪϨϋ ΔΒδϨϟ΍ ΏΎδΣ .3

ϥ΃ ϖΒγ ΎϤϣ ΞΘϨΘδϧ

ϥΫ·
 : ȕ+ ί΍ήρ Ϧϣ ΖΘϔΘϟ΍ .4
ΖΘϔΘϟ΍ ΔϟΩΎόϣ
ସ଴
= ଵ଼ + ‡
ϥϮϏέϷ΍ X = Ar ϥΫ·

3 ϦϳήϤΘϟ΍
: Γέ΍Ϊϟ΍ ϲϓ ΓέΎϤϟ΍ ΔϳϮμϘϟ΍ έΎϴΘϟ΍ ΓΪη ΏΎδΣ .1
Pth(R) = RIm2
౪౞ሺ౎ሻ
Im = ට = ට = 0.1A : ϱΩΪϋ ϖϴΒτΗ
I(IJ) = 0,63 . Im ΎϨϳΪϟ t = 0,25 ms ΔψΤϠϟ΍ ΪϨϋ
I(IJ) = 0,63 x 0,1 = 0.063 mA
: R ΔϴϠΧ΍Ϊϟ΍ ΔϣϭΎϘϤϟ΍ ΔϤϴϗ ΏΎδΣ .2
Pth(l) = r Im2 ΎϨϳΪϟ

r= Pth(R) = RIm2
r= = 10ȍ
: L ξϳήΤΘϟ΍ ϞϣΎόϣ ΔϤϴϗ .3

IJ = : ΔϗϼόϟΎΑ IJ Ϧϣΰϟ΍ ΔΜΑΎΛ ϦϋήΒόϳ(RLC) Γέ΍ΪϠϟ ΔΒδϨϟΎΑ

L = IJ ( R + r)
L = 0,25 x 10-3 (80+10) ϱΩΪϋ ϖϴΒτΗ
L = 22.5 mH ϥΫ·
: E ΔϛήΤϣήϬϜϟ΍ ΓϮϘϟ΍ ΔϤϴϗ .4
E = (r + R) Im ϡϭ΃ ϥϮϧΎϗ ΐδΣ
E = (80 + 10).0,1 ϱΩΪϋ ϖϴΒτΗ
E = 9v ϥΫ·
: ΔόϴηϮϟ΍ ϲϓ ΔϧϭΰΨϤϟ΍ ΔϴδϴρΎϨϐϤϟ΍ ΔϗΎτϟ΍ .5
L=1/2.Im2Em
Em = ½ x 22.5 x 10-3 x (0.1)2 ϱΩΪϋ ϖϴΒτΗ
Em = 112.5ȝJ ϥΫ·
 4 ϦϳήϤΘϟ΍

: P ϭA ϦϴΑ ΔϴϛήΤϟ΍ ΔϗΎτϟ΍ ΔϨϫήΒϣ ΐδΣ .1

Ec(P) – Ec(A)= w(’ ሬ
= mgyF
బ
Ec(A) = Ec(P) – mg( h + )

Ec(A) = 130-0.2 x10 x (15+ ) ϱΩΪϋ ϖϴΒτΗ

Ec(A) = 90J ϥΫ·

:ΎϨϳΪϟ F ΔτϘϨϟ΍ ΪϨϋ .2
VxF = V0 cos Į
tan(ɲ) =
VF = -gt + V0 sinĮ = 0

tan(Į) = =

tan (Į) = = 1/3 ϱΩΪϋ ϖϴΒτΗ

: h ωΎϔΗέϹ΍ ΔϤϴϗ . 3
: ΐΘϜϧ F ϭ P ϦϴΑ ΔϴϛήΤϟ΍ ΔϗΎτϟ΍ ΔϨϫήΒϣ ϖϴΒτΘΑ
ሬ
Ec (P) – Ec(F) = w(’

Ec(P) – Ec(F) = mg(

h=

- h= ϱΩΪϋ ϖϴΒτΗ

h= 5m ϥΫ·

:νέϷ΍ ΢τγ ϰϟ· ΔϳήϜϟ΍ ϝϮλϭ ΔψΤϟ ΦϳέΎΗ .4

 x V p 0
cos(D )t p

x p
t p
cos(D )
V 0
2
v 0
sin(2D )
t p
gV cos(D )
0

t p
2V 0 sin(D )
g

2Ec
m sin(D )
t p
2
g

2u90
0, 2
t p
2
10
sin(18, 43)

t p
1,89s

˯ΎϴϤϴϛ ΓΩΎϣ
1 ϦϳήϤΘϟ΍

2 ϦϳήϤΘϟ΍
ΐΘϜΗ ϞϋΎϔΘϟ΍ ΔϟΩΎόϣ ΔϣΎϋ ΔϔμΑ -1
B + H2O ļ BH+ + HO-
pH = pKA + log ([B])/(BH+]) ϝϮϠΤϤϟ΍ pHήϴΒόΗ
log ([B])/(BH+])> 0 ϥΈϓ ϪϨϣϭ [B] >>[BH+] t=0 ΔψΤϠϟ΍ ΪϨϋ
 pH > pKA ϲϟΎΘϟΎΑϭ
NH3OH+/NH2OH ϝϮϠΤϤϠϟ ΔΒδϨϟΎΑ pH1 = 9
NH4+/NH3ϝϮϠΤϤϠϟ ΔΒδϨϟΎΑ pH2 = 10,6
(CH3)2NH2+/(CH3)2NH ϝϮϠΤϤϠϟ ΔΒδϨϟΎΑ pH3 = 11,4
.ΓήϴΒϛ pKA ΖϧΎϛ ΎϤϠϛ ϱ΃ ΔόϔΗήϣ IJ ϡΪϘΘϟ΍ ΔΒδϧ ΖϧΎϛ ΎϤϠϛ ΔϳϮϗ ΓΪϋΎϘϟ΍ ΖϧΎϛ ΎϤϠϛ -2
(CH3)2NH2+/(CH3)2NH IJ1 = 0,25
NH4+/NH3 IJ2= 0,4
NH3OH+/NH2OH IJ3= 1x10-3
: ϞϋΎϔΘϟ΍ Δϋήγ ΓΪΣϭ -3
mol/ m3.s ϭ΃ mol/ l.min

3 ϦϳήϤΘϟ΍
AH/A- = C2H4O2/C2H3O2- ϊπϧ -1
AH + H2O ļ A- + H3O+ :Ώ ϞϋΎϔΘϟ΍ ΔϟΩΎόϣ Ϧϋ ήΒόϳ

KA= ΔϴπϤΤϟ΍ ΔΘΑΎΜϟ΍ ήϴΒόΗ ϭ

pKA = pH + log ([AH])/( A-]) (1) ϥ΃ ΞΘϨΘδϧ ϪϨϣϭ

[AH] = CA – [A-] ϭ [A ] = [H3O ] = 10
- + -pH
ΐΘϜϧ ϲϔλϮϟ΍ ϝϭΪΠϟ΍ Ϧϣ Ύϗϼτϧ΍
pKA = pH + log ([CA- 10-pH])/([10-pH]) ΢ΒμΗ (1) ϥ΃ ϲϟΎΘϟΎΑϭ
pKA = 3,3 + log(1,5x10-2 x 103,3 -1) ϱΩΪόϟ΍ ϖϴΒτΘϟ΍ -2
pkA = 4.76 ϥΫ·
-3
K= ϲϟΎΘϟΎϛ ΐΘϜΗ ϥί΍ϮΘϟ΍ ΔΘΑΎΛ ήΒΘόϧ (a

K= ϪϨϣϭ

K= ϥΫ·

έϮτΘϟ΍ ϝϭΪΟ (b
C2H4O2 + NH3 ļ C2H3O2 -
+ NH4+
t=0 n0 n0 0
0
t0 n0-x n0-x x
x

IJ= ϞϜθϟ΍ ϰϠϋ ΐΘϜϳ ϞϋΎϔΘϟ΍ ϡΪϘΗ

K= ϞϋΎϔΘϟ΍ ΔΘΑΎΛϭ

K = మ
:ϥ΃ ΞΘϨΘδϧ ϲϔλϮϟ΍ ϝϭΪΠϟ΍ ϰϠϋ ΩΎϤΘϋϻΎΑ ϭ

K= మ
బ
మ = మ ϱ΃
 IJ= ϥΫ·

4 ϦϳήϤΘϟ΍
-1
pKA Ώ pH ςΑήΗ ϲΘϟ΍ Δϗϼόϟ΍ -1-1
pH = pKA + log
- pk
= 10-pH A

ΔΒδϨϟ΍ ΏΎδΣ -2-1

ϦϤϴϬϤϟ΍ ωϮϨϟ΍

AH 10-2
ΓΪόϤϟ΍
- 2.5
A 10
ήθϋΎϨΛϹ΍ ϲόϤϟ΍
- 3.9
A 10
ϡΪϟ΍
-2
: ϞϋΎϔΘϟ΍ ϲϓ ΔϠΧΪΘϤϟ΍ ΕΎΟϭΩΰϤϟ΍ -1-2
-2-2
O2/H2O ϭ SO2/HSO2
SO2 + H+ + 1e- ļ HSO2 -3-2
2H2O ļ 4H+ +4e- + O2
4SO2 + 2H2O ĺ 4HSO2 + O2 :ΔϠϴμΤϟ΍ ΔϟΩΎόϤϟ΍ ϥΫ·