October1998, pp 568-574
RI~SU
A B S T R A C T
MI ~
This paper describes a test rig to measure the uni-directional water absorption of mortar and concrete. The test
data acquisition is controlled by purpose written software
installed on a PC and the results are utilised directly to
obtain the sorptivity measured in g/mm2/minl/2 . As an
example the apparatus was used to obtain the sorptivity of
mortar in which the ordinary Portland cement was partially replaced by ground waste brick obtained from different sources. The results presented demonstrate the validity
of the test, and the apparatus and the methodology are
shown to be of sufficient sensitivity in detecting the differences between the sorptivities of the various mortars
tested. The variation in the sorptivity with curing time and
mixture composition was determined. The paper also gives
the results of total water absorption tests conducted on the
sorptivity test specimens, after being reconditioned, and
the results of compressive strength tests for all the mortars
investigated.
Cet article d&rit uu appareil d'essai pour mesurer l'absorption unidiwctionnelle de l' eau par le mortier et le bdton. Les donn&s r&ultant des essais sont contr31&s au moyen d'un logiciel
sp&ialement confu installd sur PC, et ces r&ultats sont directement utilis& pour obtenir la sorptivitd mesur& en
g/mm2/minJ/2. A titre d'exemple, on a utilisd l'appareil pour
ddterminer la sorptivitd d'un mortier dans lequel le ciment
Portland ordinaire avait dtd partialement remplacd par les briques
de r&up&ation partialement concass&s. Les r&ultats pre'sent& ici
ddmoutwnt la validitd de l'essai, et le fait que l'appareil et la
mdthodologie ont une sensibilitd suffisante pour ddtecter les diffdfences entre les sorptivit& des diff&ents mortiers dtudi&. Les
variations de la sorptivitd en fonction du temps de cuw et de la
composition du mglange ont dtd ddtermin&s. L'article prdsente
@lement les r&ultats d'essais d'absorption totale de l'eau mene's
sur les @ouvettes utih's&s pour les essais de sorptivitd, apt& leur
reconditiormement, ainsi que les r&ultats d'essais de r&istance a
la compression pour tousles mortiers dtudie's.
1. I N T R O D U C T I O N
568
Sabir,Wild,O'Farrell
ised drying procedure for all specimens. Furthermore, as
water absorption and capillary suction depend on porosity,
any non-uniformities in the latter could lead to different
sorptivities in samples obtained from what is supposed to
be the same material. It is, therefore, essential that materials
under test be consistent and homogeneous. In practice the
point of origin, and frequently the very early readings, are
omitted when determining the slope of the graph. This is
because there is an increase in the mass of the specimen
caused by the filling of the open surface pores on the
inflow face and the sides of the specimen when it is submerged. In order to reduce these effects to a minimum, it
is essential that the specimen be submerged in water to no
more than 2-5 m m [1l].
3. TEST APPARATUS
i : S~/7
S is the sorptivity measured in g per m m 2 (of wetted
area) per mini/2. It is easily determined from the slope of
the linear part of the i versus ~t curve. Some materials
with extremely coarse pore structure experience little capillary suction and may show significant deviation from linearity after prolonged wetting. Capillary suction can only
be measured in partially dry mortar or concrete. Sorption
does not take place in saturated materials, and in totally dry
materials substantial absorption of water by the gel will distort the results. The sorptivity will depend on the initial
water content and its uniformity throughout the specimen
under test. It is important, therefore, to keep this in mind
both when relating laboratory measurements to field
behaviour and also in ensuring a consistent and standard-
569
Raw Materials
FiringTemperature
BaO
P205
Cr203
SrO
SO3
L.O.I.
1.77
1.39
8.86
1.02
2.61
0.05
0.11
0.01
0.03
0.04
0.25
9.39
0.50
3.15
0.04
0.20
.03
.05
2.90
1.48
2.02
1.79
0.26
3.71
0.04
0.07
0.02
0.01
0.13
0.19
1.20
0.87
0.27
2.17
0.05
0.10
0.02
0.01
0.07
0.36
Mineral (%)
B10 - B30
D10 - D30
L10 - L30
P10 - P30
Quartz
Feldspar
Haematite
Cristobalite
49
5
10
12
60
23
6
12
43
24
20
13
88
3
5
4
Spinel
Gypsum
Anhydrite
17
6
+ denotes a trace
- denotes absence.
4-
570
5.0
4.5
4.0
o
X
7 days
3.5
/
3.0
2.5
2.0
~
~ _ . ~ e
s
SOda s
~'
1.5
1.0
0.5
0.0
material to ball milling to the required particle size. The final material had a specific
surface in the range 320-350 m2/kg, see
[10], which is approximately the same as
that of OPC.
From each mixture, four 100 m m
cubes were prepared for each curing time.
The cubes were cured in water at 20~ at
each of the curing times of 7, 28 and 90
days. Three cubes were used for compression strength tests and the fourth was used
to produce a cylindrical core from which
four discs were cut for the sorptivity and
absorption measurements.
6. RESULTS A N D D I S C U S S I O N
6.1 Sorptivity
Typical plots of cumulative water
absorption against the square root of time
are shown in Fig. 2. These plots give the
water absorption for the B30 mixtures cured
at 7, 28 and 90 days. Each set of three plots
shown refers to the three samples tested
from each of the mixtures. The tests conducted on the three samples at each of the
three curing times give practically identical
slopes, particularly during the early part of
the test. This demonstrates the reproducibility of the behaviour as obtained from different samples of the same mortar. The results
also clearly show the influence of curing
time on the sorptivity of the mortar.
For the majority of samples tested, the
relationship between cumulative water
absorption and the square root of time of
exposure begins to deviate from linearity
after about 20-30 minutes. In adopting a
systematic methodology for determining
t.8
1.6
..
,o,
1.4
1.2
1.0
o.~
0.6
9--"
0.4
0.2
t'
0.0
,e*a
9 '~*X*
:W
(a)
I
2.0
1.6/r,
x
t.,
t.2 41 9 e2o
":'~
1.0
,E~
0.8
,~
0.6
0,
o . o~
a 7~'*~&.*
,o
j[~
.,
="
: *
.de*
.x" *
9 _,~,/~ .=:.
;:-:.::,:::*"
0.2
0.0
(b)
,,X* ~ ~,,~
..,.-
,~.
,,4.*
i'i:'"
0.0
0.5
1.0
1.5
(c)
2.0
2.5
3.0
3.5
4.0
4.5
571
Curingtime (days)
Mixture
28
90
Control
3.58
3.58
3.58
BIO
B20
B30
4.51
4.71
6.21
4.29
4.32
4.58
4.22
4.08
3.48
DIO
D20
D30
4.97
5.67
5.85
4,5 7
5.11
5.32
3,84
4.10
4.85
LIO
1.20
L30
3.81
4.56
4.84
3.42
3,96
4.54
3.21
3,80
4.33
PIO
P20
P30
4.47
4.73
5.38
4.22
3.91
4.95
3.99
3.69
3,45
4,~
3-
2 i..~_LlO
_
ii
i
Or
(a)
7 - -
[-~L$0
i ~
i~P1o
i+
(c) I
(d)
(b)
,(1~
lOO
Curing tim
P20
lO
,oo
Fig. 4 - Variation ofsorptivity with curing time for mortars with ground brick from: (a) Britain, (b) Denmark., (c) Lithuania and (d) Poland.
572
Curingtime (days)
Mixture
28
90
Control
7.21
7.03
6.61
BIO
B20
B30
7.93
8.36
8.91
7.57
8.09
8.65
7.25
8.09
8.28
DIO
D20
D30
7.98
8.39
8.51
7.79
8.23
8.44
LIO
L20
L30
7.68
8.23
8.61
PIO
P20
P30
8.03
8.43
8.68
Mixture
28
90
Control
52.2
65.3
67.0
BIO
B20
B30
43.8
39.4
31.2
61.2
55.4
45.2
74.0
66.2
55.7
7.58
8.01
8.12
DIO
D20
D30
40.3
30.1
28.9
55.0
45.0
35.6
65.2
55.0
49.1
7.39
7.96
8.45
7.06
7.69
8.05
LIO
L20
L30
44.7
33.5
27.8
59.4
48.5
40.5
69.1
61.5
55.1
7.52
7.74
8.26
7.62
7.62
8.34
PIO
P20
P30
39.8
34.5
28.3
55.6
50.1
39.8
65.5
62.7
57.5
8-
!--Con,ro,!
i
i
I " ~ LIO
L---L~O ~
1~83~ j
Curingtime (days)
7
:"
="
(a)
s (c)
10
10
I , C-~ontrol~
=~
-.-oto
9 ~ i-~Plo
- ~ - D20
| ~- a - P 2 0
<
, (b)
s/(d)
Curing time Idays)
,0o
,oo
Fig. 5 - Variation of absorption with curing time for mortars with ground brick from: (a) Britain, (b) Denmark, (c) Lithuania and (d) Poland.
573
ACKNOWLEDGEMENTS
7. CONCLUSIONS
The paper introduced a novel test rig and testing
methodology for the measurement of sorptivity of mortar and concrete. The arrangements have been shown to
yield reproducible values of sorptivity obtained from different samples prepared from the same mixture. The
tests have shown that at short curing periods, ground
brick increases the sorptivity of mortar relative to that of
the control. The greater the replacement level of OPC
by ground brick, the greater the sorptivity. However, the
sorptivity of ground brick mortar decreases with curing
time and for certain replacement levels some mortars
exhibited sorptivities below that of the control. The
above observations serve to demonstrate that the test has
a high degree of sensitivity and enables the changes in
capillary porosity to be detected.
From the material behaviour point of view, the increase
in sorptivity at the early ages is attributed, in part, to the
residual porosity in the ground brick. At this stage very little, if any, pozzolanic activity has taken place. Similar
effects, due to ground brick, were also obtained on the
measured absorption. This suggests that ground brick
574
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