QAQC : Thorie

Accurance= proximit de la valeur par rapport la vrai valeur. Prcision=proximit de la valeur par rapport aux autres valeurs. Formule de Gys=FE=erreur fondamentale

Fi2=variance (de lerreur fondamentale) Fi2 (FE)=(1/MS-1/ML)xfxgxcxlxd3 MS=masse sample ML=masse lot F=forme=0.5 G=taille de distribution=0.25 c=composition minralogique l=libration l=0 si trs htrogne et l=1 si trs homogne (entre 0 et 1)

D=plus grosse particule 95%=taille broyage Fxgxcxl=constante chantillon=C Plus ML est grand, plus il devient ngligable ! Donc : Fi2 (FE)=(1/MS-1/ML)xfxgxcxlxd3=Cd3/MS soit Fi2 diminue si MS augmente et d diminue. Donc il faut un grand chantillon et un broyage trs fin. Calcul de C :

C=fxgxc=0.5*0.25*l*c C=(1-a)*((1-a)dens a+ a dens g)/a ou a=teneur de la calcopyrite dans minerai (g=gangue). Si 34.5% de Cu dans calco, 0.8% cu dans minerai=quartz alors a=0.008/0.345=0.0232=2.32% Si a trs petit c=dens a/a 3 applications la formule de Guy : Fi2 (FE)=(1/MS-1/ML)*C*d3

-estimer variance Fi2 -estimer Ms=poid minimum de lchantillon -estimer d=taille maxi des particules

Ex : calcul de Fi avec 0.8% de Cu broy 12.5mm avec un ch de 50kg ? Fi2=Cd3/Ms (Ms=50000g/ d=1.25cm/dl=0.01cm/l=0.9) C=1.95 g/cm3 Fi2=76*10-6 et racine de Fi2=Fi=0.87% ou 2Fi*0.8%Cu=+/- 0.014 %Cu Exemple : On part de 2m de carotte=25kgjaw crusher 5mm puis roll crusher 1mm24kg reject et 1kg que on pulvrise 100microns700g de pulps stochage et 300g pour analyse type FA
Utilisation du nomogram pour tre sr quon est en dessous de la safety line (10% de Fi2). Pour lor, on utilise le fcateur de bongarcon car Guy est trop conservatif :

Fi2= c*f*g*dl^1,5*d^1,5/M Avec : -dl=25 micron f=0,5 -g=0,25 -c= si grade=5g/t-->5,10^-6 et c=19,3/5,10^-6

La premire tape de broyage fct de Msample, va jouer normment sur Fi2 !!! il faut broyer finement un gros chantillon ds le dbut. Ex : 2cm et 2 kg a donne une erreur de 30% ce qui est norme !!!

FORAGE RC : 3 types * rotary= injecte par le tube et ressort entre tube et encaissant=possible contamination *reverse=injection entre tube et roche, aspiration par le tube *reverse dual=comme RC mais avec un 2me tube qui colle la paroi ! pas de contamination possible. -Recovery mesur grace au poid linverse du core gace la longueur. -Besoin de spliter laide dun RSD ( rotary sampling dividers, chnager si trop vieux) ou riffle splitter. -Un cyclone permet de rcuprer les chantillons.

-Un tube de 5 pouces produit 36 kg/mtre de forage !!! -les ch : des gros morceaux de plus de 4kg mieux que plusieurs petits morceaux. Possible : cone et splitting, pelle, pattern sampling, RSD, riffles. Tj sassurer que le lot est homogne !!!

ECHANTILLONNAGE

Facteur qui affecte lchantillonnage : -mauvaise rcupration -mauvais quartage -perte dchantillon -contamination (attention poussire autour du rig, condition de stockage, manipulation des ouvriers, pas nettoyer entre 2 samples, abrasion des quipements qu ipartent avec les samples comme le fer, le cuivre, laluminium ou la cramique....) 3 tapes :

-schage (24h 100C) -broyage=crushing (jaw crusher) puis concassage=grinding et pulvrisation=pulverising (mixer mill)) -blending=homognisation et splitting

Lors de la rduction de taille, tj sassurer que plus de 95% des particules soit passes sur la maille indique.

Attention bien nettoyer le splitter et les mills entre chaque sample !!!! Surveiller le temps de broyage !!! On appelle rejet le reste de lchantillon soumis aprs retrait de lchantillon splitter analyser. Ils servent de duplicate. Il est important de prendre des duplicates plusieurs tapes de broyage DUP1,2,3 pour contrler lefficacit des broyeurs et du quartage. La pulpe, plus gnralement issue du mills ?

RIFFLE :

*attention aux biais produit si : -matriel est humide

-introduit pas au milieu et dans le bon sens -la taille de la particule est sup 3x lespacement des dents - plusieurs manips et en cascade Analyses OR :

-Aqua regia/AAS= lor est dissous dans une mixture nitrique et hydrochlorique puis analyser par AAS. Peut sous-estimer lor si silicate et sulfure ne sont pas bien dissous ou bruls !!! -Fire Assay= fusion de lor et lAg sur une coupelle en plomb. Le plomb est volatilis et lor analys par AAS. Cest le plus utilis pour lor. Besoin de 25g pour lanalyse finale ! FA que pour Or ou Ag. Analyse mtaux :

-ICP=dissolution multi acide puis excitation atomes par traitement HT. Les photons mis sont analys par spectromtre en analysant la longueur donde spcifique de chaque atome ! Il permet une large suite dlments ! -AAS=pareil mais les atomes sont excit par des par des rayons de longueur donde diffrentes en suite. Adsorption atomique spectromtre. Il permet une large suite dlments ! -XRF=mission de RX spcifique de chaque atome aprs soumission de lchantillon un flux dlectron. Non destructif et pas besoin de calibration linverse des 2 autres. Idal pour le fer, bauxite et luranium. QA/QC :

-std=mesure laccurance et la qualit des analyses (labo) -duplicate= mesure la qualit de lchantillonnage et la prcision -on utilise 3-5 std par projet -rapport cout/efficacit, 1/20 std cest ok STD

-on fait un plot avec +/- 2SD, fournis avec le sample. Les valeurs doivent tre entre la ligne moyenne et les 2SD. -si non : attention la drive temporelle (downward pattern, problme de calibration, labo drift), leffet ppite (clusters effect), il faut ranalyser les rejects et contacter le labo, problme de contamination ou de standart pas du labo RSD= relative standart deviation=SD/valeur moyenne concentration*100 (%)=mesure de la prcision !

3 2,5

OxJ64
OxJ64 Certified value

Au ppm

2 1,5 1

+3FE -3FE

Count
DUPLICATE a marche par paire !

-MAPD= mean absolute pecent diffrence in %=2*ABS(x1-y1/x1+y1)x100 Entre 2ech.=mesure de la prcision -Scatter plot -q-q plot

Au-Au Lab Replicates (0-50)

50 40 Au (g/t) 30 20 10 0 0 10 20 Au-Au Au (g/t) y=x y=0.9x y=1.1x

30

40

50

Cross plot

100% 90% 80% 70% 60% 50% 40% 30% 20% 10% 0% 0% 20%

Intertek Pulp duplicates Ranked Hard

Ranked Hard

HARD

40% Rank

60%

80%

100%

RANKED HARD

100,000 HAD (Half Abs. Diff. - ppm) 10,000 1,000 0,100 0,010 0,001 0,000 0,10 100% 50% 20% 10% 5% 1%

Intertek Pulp duplicates Pair Mean / HAD

1,00 Pair Mean - Au ppm Pair MEAN

10,00

Q-Q : Original / All Data

140 120 100 All Data 80 60 40 20 0 0 50 Original 100 150

Avec ces graph, on voit si il y a un biais -1/20 sample cest ok ! BLANKS

-mesure laccurancy ! -1/40 ok. DBD=dry bulk density=Mdry/Vbulk Vbulk=si core rgulier=diamtre par longueur. Vbulk=si core pas rgulier=M eau qui sature sample- M eau qui immerge sample (voir descriptif) dans ce cas il y a 3 mesure faire de poids !!! La reprsentativit dun chantillon peut tre affect par :

-mauvaise recovery -roche friable, argileuse ou en bloc -type de minralisation alatoire : veine, effet ppite, cisaillement, faille -technique de forage -mauvaise pratique, procdure et quipement TEST dHETEROGENEITE=Monogram Il faut que Fi2 soit tj infrieur 10%
Sampling Nomograph 1000 100 10 1 0,1
1 cm 0,2 cm 0,0125 cm 0,0075 cm Process 5%

s2FSE

0,01

Split 4

Split2 Split 33 Crush Crush 2

Lot Split 1 Crush 1

0,001

0,0001 0,00001 0,000001 0,0000001 1 10 100 Mass (g) 1000 10000 100000

Labo : en choisir au moins 2, voir 3 ! utiliser diffrente technique comme AAS, FA, Aqua regia. Si on utilise 0.1g dacide ou 0.5g (plus cher), on va sous-valu les teneurs !

Ne pas oublier que sur 100 Mt de ressource, seul 1-5 kg seront analys !!!! Lhtrognit est vrifie avec les duplicate ! Si les grains sont trop gros, mieux vaut utiliser le FA gravi que AAS ! Lor grossier est trs compliqu estimer. Pour un d= 1cm (crusher ?), il faudra un sample de d lib=200 micron, alors que pour un dlib=10 micron, il faudra 650 g ! -il faut mieux grinder 1mm ou 0.5mm ds le premier broyage ! en effet avec d=1mm, il faut 1.7 kg de sample dlib=200 micron. -lor est trs dense et se segregate trs facilement notamment avec leau en RC, durant le split, ech secou au labo ou pendant la prparationCela peut introduire des biais !!! -lor est mou et ductile et peut contaminer dautres sample pendant le broyage si il reste coll. Trs difficile broy de faon homogne ! -ne pas hsiter sur lhtrognit avec duplicate et le temps de broyage. -lor est visible 150 micron ! Il est grossier si sup 75 microns, sinon il est fin. Mais les 2 apparaissent dans un mme ch !

QAQC : PRATIQUE
Drillhole deviation measurements Drillhole deviation should be measured at 10m depth and then every 30m downhole. Take deviation readings as the hole is drilled for all diamond drill holes and monitor for any strong deviation. Hole deviation should be plotted to ensure that the hole will reach its designed target. If the hole deviates to much it may need to be stopped and re-drilled.

Core recovery Core recovery could possibly be a problem for the diamond drilling. Monitor this closely especially in the ore zone. If poor core recovery occurs make the driller aware of the situation. He can try and improve recovery by drilling shorter runs. Also notify the project geologist as changes to drilling techniques may be needed. Core orientation

For the drill core we want to orientate the core so that structural measurements can be made. This program will be a good opportunity to gain experience with core orientation geotechnical and structural logging Make sure that the drillers drop the spear tool down the hole to mark the bottom of the core every 6m and that they mark the orientation line on the end of the core. The completion of a spear orientation should be noted on the drillers log book. The core may often be very broken or very oxidised. If this is the case it is not suitable for taking orientation readings. The driller can generally determine this. Check to make sure that the driller does take measurements if the core is competent. Drill core is then orientated once the core has been taken to the core logging shed.

Sampling Diamond core: The sampling procedure generally follows SOP: CORE5 At the core facility: The drill core will be orientated if possible. Metre intervals to be marked on the core and drillers measurements checked. Diamond core will be technically, geologically and structurally logged by the geologist. Core will be checked after sampling and additional detailed geological logging carried out if the cut core surface improves geological observations. The intervals for analysis will be clearly marked by the logging geologist. Sample length should generally be between 0.5-1.5m, dictated by geology with most sampling by 1m intervals. If significant core loss (>20cm) has occurred the sample intervals should be between core blocks (i.e. samples should not cross core blocks). A list of the sample intervals should be provided to the core samplers so that core can be cut and sampled. And a copy of the list to the Project/Senior Geologist to prepare the QA/QC sampling list. The QA/QC to be used is specified by the Project/Senior Geologist based on the following guidelines. QA/QC procedure based on selective sampling of the mineralised zone; per 100 samples: 4 standards, 2 blanks and 5 duplicates. (Duplicates should be selected from the interpreted mineralised zone and be inserted after the primary number in the sampling sequence). Refer to Quality Assurance SOP Chapter 5. The left half of the core is to be retained in the core tray and the right half sampled. Each sampled interval is to be placed in a sample bag. Sample bags will be numbered using the usual convention: example hole id HAW_D001, 78-78.8m would be labelled HAN_R001-78.8 On completion of sampling samples are transferred to the sample preparation facility.

At the sample preparation facility: The entire sample is primary and secondary crushed. Twice through the jaw crusher and twice through the cone crusher.

The sample is then split to give a 500g sub sample. The residue is retained in labelled sample bags in the container. The entire 500g sub-sample is then pulverised in the ringmill. The pulverised 500g sample is split to produce a 125-250g sample to be packaged in a geochem envelope for sending to the laboratory for analysis. The remaining 250350g of sample is retained as a witness sample. Samples are packaged and sent for analysis at Intertek for Au by method FA50. Samples which show signs of base metal mineralisation (eg. Sulphides of oxidised Cu minerals should also be analysed for base metals)

RC drilling: Usual procedures for RC sampling will be employed (same as Kamoeb drilling in 2009). The sampling procedure generally follows SOP: RC3.

At drill rig: The samples from the cyclone will be weighed and split generating a ~5kg sample, with the splitter residue generally discarded (see below). When the ore zone is intersected (indicated by gossan or oxidised altered material) the geologist should instruct the sampling workers to retain the splitter residue in labelled plastic bags. These can be placed next to the drill site in rows for future use. The reason for this is that larger amounts of the ore zone will be required for future test work. Sample bags will be numbered using the usual convention: example hole id HAN_R001, 0-1m would be labelled HAN_R001-001 Samples are transported to sample preparation facility at the exploration hanger. Drill chips should be placed into chip boxes for each metre. With the boxes labelled with the depth intervals and hole id.

At sample preparation facility: The QA/QC to be used is specified by the geologist/exploration manager based on the following guidelines. QA/QC procedure per 100 samples: 4 standards, 2 blanks and 5 duplicates. Refer to Quality Assurance SOP Chapter 5. Duplicates should be selected from interpreted mineralised intervals and should follow in ticket number the primary sample. A sampling list detailing sample ticket numbers and QA/QC is provided by the Project/Senior Geologist to the Laboratory Manager. Samples are dried if required. The sample is split to give a 1kg sample and a bulk residue. The bulk residue is stored in container for later check analysis if required. The sample is put in a small plastic bag. A sample number is allocated to each sample interval from the ticket book as described in the sampling list. Samples are pulverised in the ring mill. The pulverised 1kg sample is then split to produce a 125-250g sample which is placed in a geochem envelope for shipment for assay. The remaining 750g sample is kept as a reference sample. Samples are packaged and sent to Intertek for analysis for Au by method FA50.

Responsibilities of the Rig geologist Make sure that the drillhole is drilled at the correct azimuth and dip Supervise the sampling and ensure that good practices occur, no contamination, samples correctly labelled, weighed, etc. Collect and check deviation information as the hole is drilled, pass this on to the Project/Senior Geologist to be checked. Logging geology (RC & Dia) and structure, geotech (Dia). Provide details of drilling, mineralised zones, geology to the Senior/Project geologist. Draw field sections to show drillhole as it is drilled Ensure that data is correctly entered into the daily drill reports on the computer. Review drill results and check that data is correct in the database.

1. AMC Duplicate Sampling The main aim of duplicate samples will be to test the reproducibility of our sampling and assaying procedures. This will determine if the results we receive for samples are repeatable and accurately representing the mineralisation of each sample interval. Matrix effects or contamination during the sample collection and preparation process should be identified. In contrast the aim of the Standards and Blanks dispatched to the assay lab is to test the precision and accuracy of the lab. Check samples or duplicates of the lab pulps can be submitted to an umpire laboratory to also test the quality of the primary laboratories precision and accuracy.

1.1

AMC Duplicate Procedure

Routine Duplicate sampling for AMC will involve a duplicate taken at the second division of a sample, (DUP2 see below). Everything in the sampling process should remain constant, same sample preparation procedure, same laboratory, etc. Duplicate samples will be selected by the Project/Senior Geologist according to samples most likely to contain mineralisation as interpreted from the drillhole logs. The duplicates are then inserted into the sampling sequence directly after the primary sample (this is to simplify the process for the sample preparation workers). The duplicate samples should be clearly identified on the sampling sheets provided to the Preparation Laboratory Manager. As the 500-1000g sub-samples for pulverising are split from the samples at the hanger a duplicate sample is also prepared in the same manor and inserted into the ticket numbering sequence after the primary sample as defined by the sampling sheet. This sample will then be treated in the same way as a normal sample during the sampling preparation procedure and assay.

Rate for duplicates should be 5 samples per 100 when the entire hole is sampled and 9 duplicates per 100 samples when mineralised intervals only are sampled.

1.2

AMC Check Sample Procedure

Check samples should be carried out at a rate of half that for routine duplicates. Samples should be selected once pulps have been returned from the primary laboratory and prepared with QA/QC samples inserted and sent to a selected umpire laboratory for analysis. Sampling lists should be prepared by the project/senior geologist to select a range or anomalous assay values. Samples should then be prepared under the supervision of the Preparation Laboratory Manager according to this list. Check samples should get new ticket numbers and have QA/QC samples included in the sampling sequence.

1.4

Database Management

The duplicate samples can be managed as outlined in the document Quality Assurance/Quality Control Hassai Camp Geology Manual: Sampling and sample management quality control data flow resources/reserves version 1.2, October 2009. The following (in italics) is taken from this document and modified slightly as indicated (blue text). Duplicate samples will be given the Hole ID, depth from and depth of the sample being duplicated. The Sample ID of the duplicate sample will be the same as the sample being duplicated followed by a D to indicate that it is a duplicate sample (eg; KAMS_R001-006D). If more then one duplicate of a sample is analysed a number is added after the D to indicate this (eg KAMS_R001-063D1). An example of the Sample ledger for Duplicates is shown below.

Hole_ID KAMS_R001 KAMS_R001 KAMS_R001 KAMS_R001 KAMS_R002

Depth_from 5 31 62 62 10

Depth_To 6 32 63 63 11

QA/QC Type DUP2 DUP2 CHECK DUP2_1 DUP2

Sample_ID KAM_R001-006D KAM_R001-032D KAM_R001-063D KAM_R001-063D1 KAM_R002-011D

The following identifier system is proposed for identifying duplicate samples taken at different stages of the sampling procedure. This can appear in the QA/QC Type column as shown above.

DUP1

First division of a sample -For diamond core sampling this would be a duplicate or core sample. -For RC sampling the duplicate would be taken as a second split of the original RC sample at the rig site.

DUP2

Second division of a sample -For diamond core this would be a duplicate of the 500-1000g subsample for pulverising split from the crushed original core sample. -For RC samples this would be a duplicate of the pulverised 1kg sample split from the sub-sample collected at the rig site.

DUP3

Third division of a sample -This would be a duplicate of the 125-250g sample sent for analysis at the lab which was split from the pulverised sample.

CHECK

Lab Check sample -This is an assay by an umpire laboratory of the remaining pulp sample returned from the primary laboratory.

ARIAB MINING COMPANY Ltd

Sample preparation Standard Operation Procedures

SOP: CORE5 Sample preparation 1/2 - Flow-Chart Rig site Geologist Supervision

Manipulate with great care, do not: - Rotate core in tray - Manipulate core without Geologists authorization - Walk on or above Core-box - Lift or move a core-box alone - Knock-down a box
Bottom: 92.7m

Technical log incl. RQD and Recovery Adjust geologist depth Core orientation

DH: DD_UMASHAR_002 PQ Box 13 From 88.3m to 92.7m

91.1 88.8

Cutting Line
88.8
Top: 88.3m

91.1

Top: 88.3m

Properly identify and label: -Top and bottom -Core Blocks -All depths Hole-ID, Depth from and to, Box no, on the corebox cover, and on the 4 sides

Form: Dispatch Field to Hangar

Properly identify the sample limits on the core and on the core-box
Bottom

2. Core Splitting with Diamond Saw Geological log Sample Log Photography Sample Number

91.1

4- 5 kg

89.2

Left half core kept as a reference in the corebox

Top

Form: Storage

3. Sample dispatch and CoreBox Storage

Exploration sample preparation facility See SOP Core5 Core Sample 2/2
Date: 10/10/2009 Version1.2

Storage in CoreBox Shelves

DH: DD_UMASHAR_002 Properly label every Core-Box PQ Box 13 From 88.3m to 92.7m Prepared by: R. Bosc, M.Bennett, M. Barbut
Executive Deputy Manager Chief Geologist Field Manager

Approved by:

Exploration Manager

Bottom: 92.7m

ARIAB MINING COMPANY Ltd

Sample preparation Standard Operation Procedures

SOP: CORE5 Sample preparation 2/2 - Flow-Chart

Left half core kept as a reference in the corebox Geologist Supervision

1. Core Sampling See Sample prep 1/2 1- 5 kg

Number

Hangar Manager Supervision

2. Crushing and splitting Primary Jaw Crusher 2 pass < 2cm Preferred procedure 1ry and 2ry crush then split 4-5kg Cone Crusher - Marcy 2 pass < 1 mm
Split

Bulk residue storage optional

Split

Splitter: 16 Riffles 1.4 cm

Split Split

Storage of reference split

3. Grinding

1/8 (~500g)

Form: Shipment Hangar to External Laboratory

Ring Mill < 125 m Form: Storage

Paper sample bag (125g) to Intertek Assay = FA and GA30 etc

Storage for further analysis (375g)

Date: 10/10/2009

Version1.2

Prepared by:

R. Bosc, M.Bennett, M. Barbut

Approved by:

Exploration Manager

Executive Deputy Manager

Chief Geologist

Field Manager

ARIAB MINING COMPANY Ltd

Sample preparation Standard Operation Procedures

SOP: RC3 Sample preparation - Flow-Chart

Geologist Supervision
Split

1. Drilling site Division Number

Wet weight

3X

Wet samples are sun dried in calico bags before splitting Waste

Geological Log Reference Chips box Panning

Form: Dispatch Field to Hangar 2. Drying Insertion of Standards and Blanks: - 1 tube - Label as usual - No grinding

7-10 kg

Ship to the Hangar Hangar Manager Supervision

Split

3-4X
5 kg Reference Storage Form: Storage

0.5 - 1kg

Total processing < 125 m

Storage of reference pulp (875g)

125g pulp
Form: Shipment Hangar to external laboratory External Laboratory Supervision

Assay: Au CN08, Au FA, GA30

Pulp storage at the lab. Rtn to Hassai after 3 months. (& Bulk residue discarded.)

Pulp storage

Form: Storage

Date: 10/10/2009

Version1.2

Prepared by:

R. Bosc, M.Bennett, M. Barbut

Approved by:

Exploration Manager

Executive Deputy Manager

Chief Geologist

Field Manager

ARIAB MINING COMPANY Ltd

Sample preparation Standard Operation Procedures

SOP: RC4 Sample preparation - Flow-Chart

Geologist Supervision
Split

1. Drilling site Division Number

Wet weight

3X

Wet samples are sun dried in calico bags before splitting Waste

Geological Log Reference Chips box Panning

Form: Dispatch Field to Hangar Composite sample: - collected by scoop or splitting - Number of meters to composite defined by geologist
Split

7-10 kg

Ship to the Hangar Hangar Manager Supervision 5 kg Reference Storage

3-4X
5 kg

2. Drying Insertion of Standards and Blanks: - 1 tube/sample envelope - Label as usual - No grinding 0.5 - 1kg

Form: Storage Bulk composite sample discarded

Total processing < 125 m

Storage of reference pulp (375-875g)

125g pulp
Form: Shipment Hangar to external laboratory External Laboratory Supervision

Assay: Au CN08, Au FA, GA30

Pulp storage at the lab. Rtn to Hassai after 3 months. (& Bulk residue discarded.)

Pulp storage

Form: Storage

Date: 10/10/2009

Version1.2

Prepared by:

R. Bosc, M.Bennett, M. Barbut

Approved by:

Exploration Manager

Executive Deputy Manager

Chief Geologist

Field Manager